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    • 57. 发明申请
    • PNEUMATIC TIRE
    • 气动轮胎
    • US20110124771A1
    • 2011-05-26
    • US12622800
    • 2009-11-20
    • Paul Harry SandstromBrad Stephen GulasDavid Mark FrantzSteven Wayne CroninTang Hong WongMichael Joseph Rachita
    • Paul Harry SandstromBrad Stephen GulasDavid Mark FrantzSteven Wayne CroninTang Hong WongMichael Joseph Rachita
    • C08J5/14
    • C08L9/00B29B7/7495B60C1/00C08C19/44C08K3/36C08L9/06C08L15/00Y02T10/862C08L2666/08
    • The present invention is directed to a pneumatic tire having a component comprising a vulcanizable rubber composition comprising, based on 100 parts by weight of elastomer (phr),(A) from about 60 to about 90 phr of a polymer comprising (1) a terminating group provided from a terminating compound XnSi(OR)mR′4-m-n wherein X is a chlorine atom, a bromine atom or an iodine atom, R is an alkyl group with from about 1 carbon to about 7 carbons, R′ is a alkyl group with from about 1 carbon to about 20 carbons, an aryl group, a vinyl group or a halogenated alkyl group, m is an integer from about 1 to about 4, n is an integer from about 0 to about 2, and a sum of n and m is from 1 to 4; (2) repeat units comprising: (a) a repeat unit provided from a conjugated diolefin monomer, and (b) a repeat unit provided from an amine monomer; (B) from about 40 to about 10 phr of polybutadiene having a microstructure comprised of about 96 to about 99 percent cis 1,4-isomeric units, about 0.1 to about 1 percent trans 1,4-isomeric units and from about 1 to about 3 percent vinyl 1,2-isomeric units; a number average molecular weight (Mn) in a range of from about 75,000 to about 150,000 and a heterogeneity index (Mw/Mn) in a range of from about 3/1 to about 5/1; and(C) from about 50 to about 150 phr of silica.
    • 本发明涉及具有包含可硫化橡胶组合物的组分的充气轮胎,该组合物包含基于100重量份的弹性体(phr),(A)约60至约90phr的聚合物,其包含(1)终止 由末端化合物XnSi(OR)mR'4-mn提供的基团,其中X是氯原子,溴原子或碘原子,R是具有约1碳至约7个碳的烷基,R'是烷基 具有约1个碳至约20个碳的烷基,芳基,乙烯基或卤代烷基,m为约1至约4的整数,n为约0至约2的整数,以及 n和m为1至4; (2)重复单元,包括:(a)由共轭二烯单体提供的重复单元,和(b)由胺单体提供的重复单元; (B)约40至约10phr的具有约96至约99%的顺式1,4-异构体单元,约0.1至约1%的反式1,4-异构体单元和约1至约1%的微结构的聚丁二烯 3%乙烯基1,2-异构体单元; 在约75,000至约150,000范围内的数均分子量(Mn)和约3/1至约5/1范围内的异质指数(Mw / Mn); 和(C)约50至约150phr的二氧化硅。
    • 58. 发明申请
    • RUBBER COMPOSITION WITH MOISTURE EXPOSED SURFACE CONTAINING COMBINATION OF SILICA AND SPECIALIZED TACKIFYING RESIN AND TIRE WITH COMPONENT THEREOF
    • 具有含有二氧化硅和特殊结合树脂与轮胎组合的水分暴露表面的橡胶组合物与其组分
    • US20100317793A1
    • 2010-12-16
    • US12483346
    • 2009-06-12
    • Paul Harry Sandstrom
    • Paul Harry Sandstrom
    • B60C1/00B29C43/24B29C47/00C08L9/00
    • C08L9/00B60C1/0025C08K3/013C08K3/04C08K3/36C08L7/00C08L21/00C08L61/04C08L2666/02C08L2666/16
    • An uncured silica-containing rubber composition having a moisture exposed surface wherein the rubber surface contains a combination of silica and a specialized tackifying resin. The moisture exposed silica degrades necessary building tack for the rubber composition. The specialized tackifying resin counteracts and significantly reduces said reduction of building tack caused by the silica/moisture interaction. Accordingly, a method of preparation of silica-containing uncured rubber is provided by processing the rubber under high shear, internal heat generation to cause the rubber composition to reach an elevated temperature followed by treating the surface of the heated rubber composition with moisture to cool the processed rubber composition where the surface of the rubber composition contains said silica together with a specialized tackifying resin. The invention further relates to building an assembly of uncured rubber components of which at east one of such components is a silica-containing moisture exposed rubber composition which contains said specialized tackifying resin. Such assembly is sulfur cured in a suitable mold at an elevated temperature to form a tire with said component, particularly where said component is an atmospherically exposed tire sidewall. Said specialized tackifying resin is a reaction product of t-butyl phenol and formaldehyde or vinyl modified product of t-butyl phenol and formaldehyde to the exclusion of sorbitan monostearate.
    • 一种具有水分暴露表面的未固化的含二氧化硅的橡胶组合物,其中橡胶表面含有二氧化硅和专用增粘树脂的组合。 水分暴露的二氧化硅降低橡胶组合物所需的建筑粘性。 专门的增粘树脂抵消并显着降低了由二氧化硅/水分相互作用引起的建筑粘性的降低。 因此,通过在高剪切,内部发热下处理橡胶来提供含二氧化硅的未固化橡胶的方法,以使橡胶组合物达到高温,然后用水分处理加热的橡胶组合物的表面以冷却 加工橡胶组合物,其中橡胶组合物的表面与专用增粘树脂一起含有所述二氧化硅。 本发明还涉及建立未固化的橡胶组分的组件,其中在这些组分的东侧是包含所述专用增粘树脂的二氧化硅水分暴露的橡胶组合物。 这种组件在合适的模具中在升高的温度下硫化固化,以形成具有所述部件的轮胎,特别是在所述部件是大气暴露的轮胎侧壁的情况下。 所述专用增粘树脂是叔丁基苯酚与甲醛的反应产物或叔丁基苯酚和甲醛的乙烯基改性产物,排除失水山梨糖醇单硬脂酸酯。