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    • 53. 发明授权
    • Magnetic material
    • 磁性材料
    • US07076958B2
    • 2006-07-18
    • US10718518
    • 2003-11-24
    • Akiko SaitoTadahiko KobayashiTakao SawaMasashi Sahashi
    • Akiko SaitoTadahiko KobayashiTakao SawaMasashi Sahashi
    • F25B21/00C09K5/00H01F1/04
    • H01F1/015F25B21/00Y02B30/66
    • The magnetic material for magnetic refrigeration of the present invention is characterized by exhibiting, in a certain temperature region, preferably, only in part of a temperature region from 200 K to 350 K, an inflection point at which a second order differential coefficient of a magnetization curve changes from positive to negative with respect to a magnetic field, within the range of this magnetic field formed using a permanent magnet unit. This magnetic material of the present invention can generate a low temperature by using a relatively low magnetic field, by transferring the entropy between the electron spin system and the lattice system near the temperature at which an inflection point appears on the magnetization curve. Examples of the magnetic material meeting this condition are La(Fe,Si)13, (Hf,Ta)Fe2, (Ti,Sc)Fe2, and (Nb,Mo)Fe2, each containing 50 to 60 atomic % of transition metals such as Fe.
    • 本发明的磁性制冷用磁性材料的特征在于,在一定的温度范围内优选仅显示200K〜350K的温度区域的一部分,其中磁化强度的二阶微分系数 在使用永久磁铁单元形成的该磁场的范围内,曲线相对于磁场从正向变化为负。 本发明的这种磁性材料可以通过在电磁自旋系统和晶格系统之间传递熵在靠近磁化曲线上出现拐点的温度下,通过使用较低的磁场而产生低温。 满足该条件的磁性材料的实例是La(Fe,Si)13,(Hf,Ta)Fe 2 N,(Ti,Sc)Fe 2 /(Nb,Mo)Fe 2 N 2,各自含有50〜60原子%的过渡金属如Fe。
    • 57. 发明授权
    • Fe-based soft magnetic alloy, method of producing same and magnetic core
made of same
    • 铁基软磁合金,其制造方法和由其制成的磁芯
    • US5522948A
    • 1996-06-04
    • US217219
    • 1994-03-24
    • Takao SawaYumiko Takahashi
    • Takao SawaYumiko Takahashi
    • C22C45/02H01F1/153H01F1/147
    • C22C45/02H01F1/15308
    • An Fe-based soft magnetic alloy is consisted essentially of fine crystal grains constituting 50% or more of the alloy structure by area %. The Fe-based soft magnetic alloy has the composition substantially represented by the general formula: Fe.sub.100-a-b-c-d-e-f X.sub.a M.sub.b M'.sub.c A.sub.d Si.sub.e Z.sub.f (wherein X is at least one compound selected from the ceramic materials fusible when the composition is fused and rapidly quenched to form a rapidly cooled alloy, M is at least one element selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo and W, M' is at least one element selected from the group consisting of Mn, elements in the platinum group, Ag, Au, Zn, Al, Ga, In, Sn, Cu and rare each elements, A is at least one element selected from among Co and Ni, Z is at least one element selected from the group consisting of B, C, P and Ge. Said a, b, c, d, e and f respectively satisfy 0.1.ltoreq.a.ltoreq.5, 0.1.ltoreq.b.ltoreq.10, 0.ltoreq.c.ltoreq.10, 0.ltoreq.d.ltoreq.40, 5.ltoreq.e.ltoreq.25, 2.ltoreq.f.ltoreq.20, 12.ltoreq.e+f.ltoreq.30, provided that all the numerals in the said formulae are in terms of atomic %). The inorganic compound represented by X of the above general formula makes the precipitating crystal grains super fine, thereby reducing dependence of the soft magnetic properties on the heat treatment temperature.
    • Fe基软磁性合金基本上由构成合金结构的50%以上的细晶粒占面积%构成。 Fe基软磁性合金的组成基本上由以下通式表示:Fe100-abcde-fXaMbM'cAdSieZf(其中X是选自当组合物熔融并迅速淬火形成快速淬火的陶瓷材料中的至少一种化合物 M是选自Ti,Zr,Hf,V,Nb,Ta,Cr,Mo和W中的至少一种元素,M'是选自Mn中的至少一种元素,Mn, 铂,Ag,Au,Zn,Al,Ga,In,Sn,Cu和稀有元素中的至少一种元素,A为选自Co和Ni中的至少一种元素,Z为选自B ,C,P和Ge,所述a,b,c,d,e和f分别满足0.1≤i≤5,0.1≤b≤10,0≤c≤10 ,0