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    • 52. 发明授权
    • Silver halide photographic light-sensitive material
    • 卤化银照相感光材料
    • US4692399A
    • 1987-09-08
    • US880781
    • 1986-07-01
    • Masao SasakiTakashi KadowakiKaoru Onodera
    • Masao SasakiTakashi KadowakiKaoru Onodera
    • G03C1/76C09K3/00G03C1/83G03C1/95G03C7/392G03C1/46
    • G03C7/39208G03C1/95Y10S430/132
    • A silver halide photographic light-sensitive material is disclosed, which is excellent in light discoloration resistance and is more particularly capable of keeping its color balance and reproducing long life color images. The photographic material comprises a support, at least three light-sensitive silver halide emulsion layers containing a yellow, magenta, and cyan coupler, respectively, and at least one non-light-sensitive layer being provided at a further side of the emulsion layer being provided at the furthest position from the support. The non-light-sensitive layer contains at least three kinds of UV absorbers represented by the general formula [UV-I], provided that at least one of the UV absorbers is in a liquid state at 30.degree. C. and at least two UV absorbers are in a solid state at the same temperature. ##STR1## And the emulsion layer containing the yellow coupler contains a compound represented by the general formula [A]: ##STR2##
    • 公开了一种卤化银照相感光材料,其耐光变色性优异,并且更特别地能够保持其颜色平衡和再现长寿命的彩色图像。 照相材料包括支持体,分别含有黄色,品红色和青色成色剂的至少三种感光卤化银乳剂层,以及在乳剂层的另一侧提供的至少一种非感光层为 距离支架最远的位置。 非感光层含有由通式[UV-I]表示的至少三种UV吸收剂,条件是至少一种UV吸收剂在30℃下处于液态,并且至少两个UV 吸收体在相同的温度下处于固态。 < IMAGE>式[UV-1]和含有黄色成色剂的乳剂层含有通式[A]表示的化合物:[A]
    • 53. 发明授权
    • Light-sensitive silver halide color photographic material
    • 感光卤化银彩色照相材料
    • US4684603A
    • 1987-08-04
    • US805120
    • 1985-12-04
    • Toyoki NishijimaKaoru Onodera
    • Toyoki NishijimaKaoru Onodera
    • G03C7/30G03C7/392G03C7/40G03C7/26
    • G03C7/39284G03C7/301
    • There is disclosed a light-sensitive silver halide photographic material which comprises containing at least one coupler represented by the formula (I) shown below and at least one of the compounds represented by the formulae (XI) and (XII) shown below: ##STR1## wherein Z represents a group of non-metallic atoms necessary for forming a nitrogen-containing heterocyclic ring which may have a substituent; X represents a hydrogen atom or a substituent eliminatable through the reaction with the oxidized product of a color developing agent; and R represents a hydrogen atom or a substituent, ##STR2## wherein X.sup.1, X.sup.2 and X.sup.4 each represents an oxygen atom, a sulfur atom or --NR.sup.10 --(R.sup.10 represents a hydrogen atom, an alkyl group, an aryl group or a hydroxyl group); X.sup.3 represents a hydroxyl group or a mercapto group; Y represents an oxygen atom or a sulfur atom; R.sup.1, R.sup.2 and R.sup.3 each represents a hydrogen atom, an alkyl group or an aryl group, provided that at least two of R.sup.1, R.sup.2 and R.sup.3 represent alkyl groups or aryl groups; R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8 and R.sup.9 each represents an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkoxycarbonyl group, an aryloxycarbonyl group, and acyl group, an acylamino group, an arylamino group, an alkylamino group, a carbamoyl group, a sulfamoyl group, a sulfonamide group, a sulfonyl group or a cycloalkyl group, or they can be linked to each other to form a 5- or 6-membered ring; M represents a metal atom; a, b, c, d, e and f each represent an integer of 0 to 4.
    • 公开了一种感光卤化银照相材料,其包含至少一种由下式(I)表示的成色剂和至少一种由下式(XI)和(XII)表示的化合物之一:
    • 54. 发明授权
    • Silver halide color photographic material of improved reproducibility
    • 卤化银彩色照相材料具有改进的再现性
    • US4675275A
    • 1987-06-23
    • US812236
    • 1985-12-23
    • Toyoki NishijimaKaoru Onodera
    • Toyoki NishijimaKaoru Onodera
    • G03C7/26G03C7/30G03C7/38G03C7/392G03C7/40
    • G03C7/301G03C7/39284G03C7/32
    • There is disclosed a light-sensitive silver halide photographic material which comprises at least one coupler represented by the formula (I) shown below, at least one of the compounds represented by the formulae (XI), (XII) and (XIII) shown below and at least one of the compounds represented by the formulae (XXI), (XXII) and (XXIII) shown below: ##STR1## wherein Z, X and R have the same meanings as defined in the specification, ##STR2## wherein M, X.sup.3, Y, R.sup.1, R.sup.2, R.sup.3, R.sup.4 and Z.sup.0 have the same meanings as defined in the specification, ##STR3## wherein R.sub.1), J, R.sub.2), R.sub.3), R.sub.4), R.sub.5), R.sub.6), R.sub.7), R.sub.8), R.sub.9) and R.sub.10) have the same meanings as defined in the specification.
    • 公开了一种感光卤化银照相材料,其包含至少一种由下式(I)表示的成色剂,由式(XI),(XII)和(XIII)表示的化合物中的至少一种如下所示 和由下式表示的式(XXI),(XXII)和(XXIII)表示的化合物中的至少一种:其中Z,X和R与说明书中定义的含义相同, (XI)其中M,X3,Y,R1,R2,R3,R4和Z0具有与说明书中定义的相同的含义,其中M,X3,Y,R1,R2, (XXII)其中R1),J,R2),R3),R4),R5),R6),R7),R8),R9)和R10)与本说明书中定义的含义相同 。
    • 56. 发明授权
    • Silver halide photographic material
    • 卤化银照相材料
    • US4614710A
    • 1986-09-30
    • US724628
    • 1985-04-18
    • Shun TakadaTakashi KadowakiKaoru Onodera
    • Shun TakadaTakashi KadowakiKaoru Onodera
    • G03C7/34G03C7/32
    • G03C7/342
    • A silver halide photographic material having one or more silver halide emulsion layers formed on a support is disclosed, wherein at least one of said silver halide emulsion layers contains a cyan coupler of formula (I) in combination with a cyan coupler of formula (II): ##STR1## (wherein R.sub.1 is an alkyl group, an aryl group, a cycloalkyl group or a heterocyclic group; R.sub.2 is a halogen atom or a monovalent organic group; m is an integer of 0 to 4, provided that when m is 2 or more, R.sub.2 may be the same or different; R.sub.3 is a hydrogen atom, a halogen atom, an alkyl group or an alkoxy group; W is an alkylsulfonamido group, an arylsulfonamido group, an alkylsulfamoyl group or an arylsulfamoyl group; R.sub.4 is an alkylene group; X is a divalent group; l is 0 or a positive integer; Z.sub.1 is a hydrogen atom or a group capable of leaving upon reaction with the oxidized product of an aromatic primary amine color developing agent); ##STR2## (wherein R.sub.5 is an alkyl or alkoxy group; n is an integer of 0 to 5, provided that when n is 2 or more, R.sub.5 may be the same or different; R.sub.6 is an alkylene group; R.sub.7 is an alkyl group; R.sub.8 is a hydrogen atom, a halogen atom or an alkyl group; and Z.sub.2 is a hydrogen atom or a group capable of leaving upon reaction with the oxidized product of an aromatic primary amine color developing agent).
    • 公开了一种在载体上形成有一个或多个卤化银乳剂层的卤化银照相材料,其中至少一种所述卤化银乳剂层含有式(I)的青色成色剂与式(II)的青色成色剂组合, :其中R 1为烷基,芳基,环烷基或杂环基; R 2为卤素原子或一价有机基团; m为0〜4的整数,条件是当 m为2以上,R2可以相同或不同,R3为氢原子,卤素原子,烷基或烷氧基; W为烷基亚磺酰氨基,芳基磺酰氨基,烷基氨磺酰基或芳基氨磺酰基; R4是亚烷基; X是二价基团; l是0或正整数; Z1是氢原子或与芳族伯胺显色剂的氧化产物反应时能够离去的基团); (II)(其中R5为烷基或烷氧基; n为0〜5的整数,条件是当n为2以上时,R 5可以相同或不同,R6为亚烷基,R7为 烷基; R 8为氢原子,卤素原子或烷基; Z 2为氢原子或与芳族伯胺显色剂的氧化物反应时能够离去的基团)。
    • 57. 发明授权
    • Silver halide photographic material
    • 卤化银照相材料
    • US4613565A
    • 1986-09-23
    • US724576
    • 1985-04-18
    • Shun TakadaTakashi KadowakiKaoru Onodera
    • Shun TakadaTakashi KadowakiKaoru Onodera
    • G03C1/34G03C7/34G03C7/32
    • G03C7/342G03C1/34
    • A silver halide photographic material having one or more silver halide emulsion layers formed on a support is disclosed, wherein at least one of said silver halide emulsion layers contains a cyan coupler of formula (I) in combination with a cyan coupler of formula (II): ##STR1## (wherein R.sub.1 is a ballast group; R.sub.2 is a halogen atom or a monovalent organic group; R.sub.3 is a hydrogen atom, a halogen atom, an alkyl group or an alkoxy group; W is an alkyl-sulfonamido group, an arylsulfonamido group, an alkylsulfamoyl group or an arylsulfamoyl group; m is an integer of 0 to 4, provided that when m is 2 or more, R.sub.2 may be the same or different; and Z.sub.1 is a hydrogen atom or a group capable of leaving upon reaction with the oxidized product of an aromatic primary amine color developing agent); ##STR2## (wherein R.sub.4 is an alkyl or alkoxy group; n is an integer of 0 to 5, provided that when n is 2 or more, R.sub.4 may be the same or different; R.sub.5 is an alkylene group; R.sub.6 is an alkyl group; R.sub.7 is a hydrogen atom, a halogen atom or an alkyl group; and Z.sub.2 is a hydrogen atom or a group capable of leaving upon reaction with the oxidized product of an aromatic primary amine color developing agent).
    • 公开了一种在载体上形成有一个或多个卤化银乳剂层的卤化银照相材料,其中至少一种所述卤化银乳剂层含有式(I)的青色成色剂与式(II)的青色成色剂组合, (Ⅰ)(Ⅰ)(其中R1是镇流基; R2是卤素原子或一价有机基团; R3是氢原子,卤原子,烷基或烷氧基; W是烷基 - 亚磺酰氨基 基团,芳基磺酰胺基,烷基氨磺酰基或芳基氨磺酰基; m为0〜4的整数,条件是当m为2以上时,R2可以相同或不同,Z1为氢原子或能够 与芳族伯胺显色剂的氧化产物反应留下); (II)(其中R 4为烷基或烷氧基; n为0〜5的整数,条件是当n为2以上时,R 4可以相同或不同,R 5为亚烷基,R 6为 烷基; R 7为氢原子,卤素原子或烷基; Z 2为氢原子或与芳族伯胺显色剂的氧化物反应时能够离去的基团)。
    • 58. 发明授权
    • Light-sensitive silver halide photographic material
    • 感光卤化银照相材料
    • US4517284A
    • 1985-05-14
    • US442768
    • 1982-11-18
    • Nobuaki KagawaNoboru FujimoriShigeo TanakaKaoru Onodera
    • Nobuaki KagawaNoboru FujimoriShigeo TanakaKaoru Onodera
    • C09B23/10G03C1/40G03C1/02
    • C09B23/102G03C1/40
    • A light-sensitive silver halide photographic material having at least one silver halide emulsion layer on a support, characterized in that the said silver halide comprises silver halide grains containing at least 80 molar % of silver chloride and at least one of merocyanine dyes having the formula ##STR1## wherein R.sub.1 and R.sub.2 individually represent an alkyl group, an alkenyl group or an aryl group provided that at least one of R.sub.1 and R.sub.2 is an alkyl or aryl group having a sulfo group; R.sub.3, R.sub.4, R.sub.5 and R.sub.6 individually represent a hydrogen atom, a halogen atom, a lower alkyl group, a lower alkoxy group or a phenyl group and any one pair of R.sub.3 and R.sub.4, R.sub.5 and R.sub.6, R.sub.1 and R.sub.6 or R.sub.4 and R.sub.5 may joint each other to form a ring; X is an oxygen atom, a sulfur atom or a selenium atom; and Y is an oxygen atom, a sulfur atom or a selenium atom provided that at least one of X and Y represents a selenium atom.
    • 一种感光卤化银照相材料,其在载体上具有至少一个卤化银乳剂层,其特征在于所述卤化银包含卤化银颗粒,其含有至少80摩尔%的氯化银和至少一种具有式 其中R 1和R 2各自表示烷基,烯基或芳基,条件是R 1和R 2中的至少一个是具有磺基的烷基或芳基; R3,R4,R5和R6分别表示氢原子,卤素原子,低级烷基,低级烷氧基或苯基,任何一对R 3和R 4,R 5和R 6,R 1和R 6或R 4和R 5 可以相互联系形成戒指; X是氧原子,硫原子或硒原子; 并且Y是氧原子,硫原子或硒原子,条件是X和Y中的至少一个表示硒原子。