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    • 55. 发明授权
    • Process for producing rubbery polymer particle and process for producing resin composition containing the same
    • 制备橡胶状聚合物颗粒的方法和用于制备含有它的树脂组合物的方法
    • US07485680B2
    • 2009-02-03
    • US10571068
    • 2004-09-01
    • Ryuji FurukawaMasakuni UenoKatsumi YamaguchiChiho YoshimiYoshihiro Ikeda
    • Ryuji FurukawaMasakuni UenoKatsumi YamaguchiChiho YoshimiYoshihiro Ikeda
    • C08F271/00C08F279/00C08L51/00C08L51/02
    • C08C1/14C08C1/15C08J3/14C08J3/16C08J9/16C08J2321/02C08J2351/00
    • A process for efficiently producing an agglomerate resulting from removal of impurities from a water-base latex of rubbery polymer particles or dry Powder thereof and producing a dispersion having rubbery polymer particles dispersed in an organic solvent, and a process for efficiently producing a resin composition of low impurity content, in which the state of dispersion of rubbery polymer particles is excellent, from the above dispersion. In particular, a rubbery polymer particle agglomerate of low impurity content is obtained by first mixing a water-base latex of rubbery polymer particles with an organic solvent exhibiting partial solubility in water, bringing the resultant mixture into contact with water to thereby form a rubbery polymer particle agglomerate, and thereafter separating the water phase from the agglomerate/water phase mixture. Further, a resin composition of low impurity content having rubbe, polymer particles favorably dispersed is obtained by first adding an organic solvent to the above agglomerate, mixing the obtained dispersion with a polymerizable organic compound having a reactive group, such as an epoxy resin, and thereafter distilling off volatile components.
    • 一种有效地生产由橡胶状聚合物颗粒或其干粉末的水性胶乳除去杂质而产生的附聚物的方法,并且制备分散在有机溶剂中的具有橡胶状聚合物颗粒的分散体,以及有效地制备树脂组合物的方法 由于上述分散体,橡胶状聚合物粒子的分散状态优异的杂质含量低。 特别地,通过首先将橡胶状聚合物颗粒的水性胶乳与在水中显示部分溶解性的有机溶剂混合,使得到的混合物与水接触,从而形成橡胶状聚合物,得到低杂质含量的橡胶状聚合物颗粒聚集体 颗粒附聚物,然后从附聚物/水相混合物中分离出水相。 此外,通过首先向上述附聚物中加入有机溶剂,将得到的分散体与具有反应性基团的可聚合有机化合物如环氧树脂和 然后蒸发挥发性成分。