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51. 发明授权

US10211413B2 Organic electroluminescent materials and devices 有权
公开(公告)号：US10211413B2
公开(公告)日：2019-02-19
申请号：US13351972
申请日：2012-01-17
申请人： Bin Ma , Zeinab M. Elshenawy , Chuanjun Xia
发明人： Bin Ma , Zeinab M. Elshenawy , Chuanjun Xia
IPC分类号： H01L51/50 , H01L51/00 , C07F15/00 , C09K11/06
摘要： Novel heteroleptic iridium complexes are disclosed. The complexes contain a phenyl pyridine ligand and another ligand containing a dibenzofuran, dibenzothiophene, dibenzoselenophene, or carbazole linked to an imidazole or benzimidazole fragment. These complexes are useful materials when incorporated into OLED devices.

52. 发明授权

US09670404B2 Organic electroluminescent materials and devices 有权
公开(公告)号：US09670404B2
公开(公告)日：2017-06-06
申请号：US13542868
申请日：2012-07-06
申请人： Chuanjun Xia , Bin Ma , Alan DeAngelis
发明人： Chuanjun Xia , Bin Ma , Alan DeAngelis
IPC分类号： H01L51/54 , C09K11/06 , C07F15/00 , H01L51/00 , H05B33/14 , H01L51/50
CPC分类号： C09K11/06 , C07F15/0033 , C09K2211/1029 , C09K2211/1044 , C09K2211/185 , H01L51/0085 , H01L51/0087 , H01L51/5016 , H05B33/14
摘要： Compounds comprising the formula L1L2MX wherein L1, L2, and X are distinct bidentate ligands that form an octahedral complex on the metal M, wherein M is a metal with an atomic weight greater than 40. Compounds of this formula are sublimated more facilely than octahedral metal complexes where L1, L2, and X are not distinct bidentate ligands. Organic light emitting devices are also described wherein the emissive layer may comprise a host material containing an emissive molecule of formula L1L2MX, which molecule is adapted to luminesce when a voltage is applied across the heterostructure, and the emissive molecule is selected from the group of phosphorescent organometallic complexes, including iridium complexes of the formula L1L2IrX wherein L1, L2, and X are distinct bidentate ligands.

53. 发明申请

US20140103305A1 5-SUBSTITUTED 2-PHENYLQUINOLINE COMPLEXES MATERIALS FOR LIGHT EMITTING DIODE 有权
标题翻译： 5-取代的2-苯基喹啉复合材料用于发光二极管
公开(公告)号：US20140103305A1
公开(公告)日：2014-04-17
申请号：US13872840
申请日：2013-04-29
申请人： Bin MA , Alan DeAngelis , Chuanjun Xia , Vadim Adamovich
发明人： Bin MA , Alan DeAngelis , Chuanjun Xia , Vadim Adamovich
IPC分类号： H01L51/00
CPC分类号： H01L51/0085 , C07F15/0033 , C09K11/06 , C09K2211/1029 , C09K2211/185 , H01L51/5016
摘要： Compounds are provided that comprise a ligand having a 5-substituted 2-phenylquinoline. In particular, the 2-phenylquinoline may be substituted with a bulky alkyl at the 5-position. These compounds may be used in organic light emitting devices, in particular as red emitters in the emissive layer of such devices, to provide devices having improved properties.
摘要翻译：提供了包含具有5-取代的2-苯基喹啉的配体的化合物。特别地，2-苯基喹啉可以在5位被大体积烷基取代。这些化合物可以用于有机发光器件，特别是在这种器件的发射层中的红色发射体，以提供具有改进性能的器件。

54. 发明申请

US20130146848A1 Novel Organic Light Emitting Materials 有权
标题翻译：新型有机发光材料
公开(公告)号：US20130146848A1
公开(公告)日：2013-06-13
申请号：US13316162
申请日：2011-12-09
申请人： Bin Ma , Alan DeAngelis , Chuanjun Xia
发明人： Bin Ma , Alan DeAngelis , Chuanjun Xia
IPC分类号： H01L51/50 , C07F15/00
CPC分类号： H01L51/0085 , C07F15/0033 , C09K11/025 , C09K11/06 , C09K2211/1029 , C09K2211/185 , H01L51/0072 , H01L51/5016 , H01L51/5024 , H01L51/5056 , H01L51/5072 , H01L51/5088 , H01L51/5092 , H01L51/5096 , H05B33/14
摘要： Novel phosphorescent metal complexes containing 2-phenylisoquinoline ligands with at least two substituents on the isoquinoline ring are provided. The disclosed compounds have low sublimation temperatures that allow for ease of purification and fabrication into a variety of OLED devices.
摘要翻译：提供了含有在异喹啉环上具有至少两个取代基的2-苯基异喹啉配体的新型磷光金属络合物。所公开的化合物具有低升华温度，其允许易于纯化和制造成各种OLED器件。

55. 发明申请

US20130126831A1 ORGANIC LIGHT EMITTING MATERIALS 有权
标题翻译：有机发光材料
公开(公告)号：US20130126831A1
公开(公告)日：2013-05-23
申请号：US13301179
申请日：2011-11-21
申请人： Bin Ma , Alan DeAngelis , Chuanjun Xia
发明人： Bin Ma , Alan DeAngelis , Chuanjun Xia
IPC分类号： H01L51/54 , C07F15/00
CPC分类号： C07F15/0033 , C09K11/06 , C09K2211/1029 , C09K2211/185 , H01L51/001 , H01L51/0081 , H01L51/0085 , H01L51/5016
摘要： Novel phosphorescent metal complexes containing 2-phenylquinoline ligands with at least two substituents on the quinoline ring are provided. The disclosed compounds have low sublimation temperatures that allow for ease of purification and fabrication into a variety of OLED devices.
摘要翻译：提供了含有在喹啉环上具有至少两个取代基的2-苯基喹啉配体的新型磷光金属络合物。所公开的化合物具有低升华温度，其允许易于纯化和制造成各种OLED器件。

56. 发明授权

US08431243B2 Phosphorescent materials containing iridium complexes 有权
标题翻译：含铱络合物的磷光体
公开(公告)号：US08431243B2
公开(公告)日：2013-04-30
申请号：US12044234
申请日：2008-03-07
申请人： Raymond Kwong , Bin Ma , Chuanjun Xia , Bert Alleyne , Jason Brooks
发明人： Raymond Kwong , Bin Ma , Chuanjun Xia , Bert Alleyne , Jason Brooks
IPC分类号： H01L51/54 , C09K11/06
CPC分类号： H01L51/0085 , C07F15/0033 , C09K11/06 , C09K2211/1007 , C09K2211/1029 , C09K2211/1037 , C09K2211/185 , C09K2211/188 , H01L51/0081 , H01L51/0092 , H01L51/5016 , H01L51/5056 , H01L51/5072 , H01L51/5092 , H05B33/14
摘要： Phosphorescent materials comprising iridium complexes of Formula I are provided. Compounds of Formula I are red emitters, and OLED devices incorporating these compounds have improved properties such as higher efficiency and stability.
摘要翻译：提供包含式I的铱络合物的磷光材料。式I化合物是红色发射体，并且掺入这些化合物的OLED器件具有改进的性能，例如更高的效率和稳定性。

57. 发明申请

US20130181190A1 NOVEL HETEROLEPTIC IRIDIUM COMPLEXE 审中-公开
标题翻译：新型异丁二烯复合物
公开(公告)号：US20130181190A1
公开(公告)日：2013-07-18
申请号：US13351972
申请日：2012-01-17
申请人： Bin Ma , Zeinab M. Elshenawy , Chuanjun Xia
发明人： Bin Ma , Zeinab M. Elshenawy , Chuanjun Xia
IPC分类号： H01L51/54 , C07F15/00
CPC分类号： H01L51/0085 , C07F15/0033 , C09K11/06 , C09K2211/185 , H01L51/5016
摘要： Novel heteroleptic iridium complexes are disclosed. The complexes contain a phenyl pyridine ligand and another ligand containing a dibenzofuran, dibenzothiophene, dibenzoselenophene, or carbazole linked to an imidazole or benzimidazole fragment. These complexes are useful materials when incorporated into OLED devices.
摘要翻译：公开了新的杂多铱络合物。络合物含有苯基吡啶配体，另一配体含有与咪唑或苯并咪唑片段连接的二苯并呋喃，二苯并噻吩，二苯并硒吩或咔唑。这些复合物在掺入OLED器件时是有用的材料。

58. 发明申请

US20120181511A1 5-Substituted 2 Phenylquinoline Complexes Materials for Light Emitting Diode 有权
标题翻译： 5-取代的2苯基喹啉配合物用于发光二极管的材料
公开(公告)号：US20120181511A1
公开(公告)日：2012-07-19
申请号：US13006016
申请日：2011-01-13
申请人： Bin Ma , Alan DeAngelis , Chuanjun Xia , Vadim Adamovich
发明人： Bin Ma , Alan DeAngelis , Chuanjun Xia , Vadim Adamovich
IPC分类号： H01L51/54 , C07F15/00
CPC分类号： H01L51/0085 , C07F15/0033 , C09K11/06 , C09K2211/1029 , C09K2211/185 , H01L51/5016
摘要： Compounds are provided that comprise a ligand having a 5-substituted 2-phenylquinoline. In particular, the 2-phenylquinoline may be substituted with a bulky alkyl at the 5-position. These compounds may be used in organic light emitting devices, in particular as red emitters in the emissive layer of such devices, to provide devices having improved properties.
摘要翻译：提供了包含具有5-取代的2-苯基喹啉的配体的化合物。特别地，2-苯基喹啉可以在5位被大体积烷基取代。这些化合物可以用于有机发光器件，特别是在这种器件的发射层中的红色发射体，以提供具有改进性能的器件。

59. 发明授权

US09978958B2 Phosphorescent emitters with phenylimidazole ligands 有权
公开(公告)号：US09978958B2
公开(公告)日：2018-05-22
申请号：US13798668
申请日：2013-03-13
申请人： Chuanjun Xia , Chun Lin , Gregg Kottas , Zeinab Elshenawy
发明人： Chuanjun Xia , Chun Lin , Gregg Kottas , Zeinab Elshenawy
IPC分类号： H01L51/50 , H01L51/00 , C09K11/06 , H05B33/14 , C07F15/00
CPC分类号： H01L51/0085 , C07F15/0033 , C09K11/06 , C09K2211/1007 , C09K2211/1029 , C09K2211/1044 , C09K2211/1088 , C09K2211/1092 , C09K2211/185 , H01L51/5016 , H05B33/14
摘要： Phosphorescent materials are provided, where the materials comprise a coordination compound having at least one ligand L3 having Formula (I): wherein A and B are each independently a 5-membered or 6-membered carbocyclic or heterocyclic ring; wherein RA, RB, RC, and RD each represent mono, di, tri, tetra substitutions, or no substitution; wherein Z1, Z2, Z3, Z4, Z5, Z6, Z7, and Z8 are each selected from N or C; wherein at least one of Z1, Z2, Z3, Z4, Z5, Z6, Z7, and Z8 is N; wherein one of Z1, Z2, Z3, and Z4 is C that is bonded to N of A; wherein Z is selected from the group consisting of BR, NR, PR, O, S, Se, C═O, S═O, SO2, CRR′, SiRR′, and GeRR′; wherein R, R′, RA, RB, RC, and RD are described herein; wherein L3 is coordinated to a metal M1; and wherein L3 may be linked with other ligands to comprise a tridentate, tetradentate, pentadentate, or hexadentate ligand. Devices, such as organic light emitting devices, comprising such compounds are also provided.

60. 发明申请

US20140054563A1 PHOSPHORESCENT EMITTERS WITH PHENYLIMIDAZOLE LIGANDS 有权
标题翻译：具有苯并咪唑配位体的荧光发射体
公开(公告)号：US20140054563A1
公开(公告)日：2014-02-27
申请号：US13798668
申请日：2013-03-13
申请人： Chuanjun Xia , Chun Lin , Gregg Kottas , Zeinab Elshenawy
发明人： Chuanjun Xia , Chun Lin , Gregg Kottas , Zeinab Elshenawy
IPC分类号： H01L51/00
CPC分类号： H01L51/0085 , C07F15/0033 , C09K11/06 , C09K2211/1007 , C09K2211/1029 , C09K2211/1044 , C09K2211/1088 , C09K2211/1092 , C09K2211/185 , H01L51/5016 , H05B33/14
摘要： Phosphorescent materials are provided, where the materials comprise a coordination compound having at least one ligand L3 having Formula (I): wherein A and B are each independently a 5-membered or 6-membered carbocyclic or heterocyclic ring; wherein RA, RB, RC, and RD each represent mono, di, tri, tetra substitutions, or no substitution; wherein Z1, Z2, Z3, Z4, Z5, Z6, Z7, and Z8 are each selected from N or C; wherein at least one of Z1, Z2, Z3, Z4, Z5, Z6, Z7, and Z8 is N; wherein one of Z1, Z2, Z3, and Z4 is C that is bonded to N of A; wherein Z is selected from the group consisting of BR, NR, PR, O, S, Se, C═O, S═O, SO2, CRR′, SiRR′, and GeRR′; wherein R, R′, RA, RB, RC, and RD are described herein; wherein L3 is coordinated to a metal M1; and wherein L3 may be linked with other ligands to comprise a tridentate, tetradentate, pentadentate, or hexadentate ligand. Devices, such as organic light emitting devices, comprising such compounds are also provided.
摘要翻译：提供磷光材料，其中材料包含具有至少一个具有式（I）的配体L3的配位化合物：其中A和B各自独立地为5元或6元碳环或杂环; 其中RA，RB，RC和RD各自表示单，二，三，四取代或不取代; 其中Z 1，Z 2，Z 3，Z 4，Z 5，Z 6，Z 7和Z 8各自选自N或C; 其中Z 1，Z 2，Z 3，Z 4，Z 5，Z 6，Z 7和Z 8中的至少一个为N; 其中Z1，Z2，Z3和Z4中的一个为与N的N键合的C; 其中Z选自由BR，NR，PR，O，S，Se，C = O，S = O，SO 2，CRR'，SiRR'和GeRR'组成的组。其中R，R'，RA，RB，RC和RD在本文中描述; 其中L3与金属M1配位; 并且其中L3可以与其它配体连接以包含三齿，四齿，五齿戊酸或六齿配体。还提供了包含这些化合物的装置，例如有机发光装置。

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