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    • 51. 发明授权
    • Alkali metal, copper phosphate glasses
    • 碱金属,磷酸铜眼镜
    • US5286683A
    • 1994-02-15
    • US972416
    • 1992-11-05
    • Bruce G. Aitken
    • Bruce G. Aitken
    • C03C3/16
    • C03C3/16
    • This invention is directed to the production of glasses exhibiting transition temperatures below 375.degree. C., preferably below 350.degree. C., and superior resistance to attack by boiling water. The glasses contain at least 10% copper, as expressed in terms of CuO, the predominant proportion of the copper being present in the Cu.sup.+2 oxidation state. The glasses consist essentially, in mole percent, of______________________________________ Li.sub.2 O 0-15 MgO 0-15 B.sub.2 O.sub.3 0-5 Na.sub.2 O 0-20 CaO 0-20 ZnO 0-37 K.sub.2 O 0-10 SrO 0-20 Sb.sub.2 O.sub.3 0-36 Tl.sub.2 O 0-15 BaO 0-20 CeO.sub.2 0-3 Li.sub.2 O + Na.sub.2 O + 12-30 MgO + 0-25 MoO.sub.3 0-7 K.sub.2 O + Tl.sub.2 O CaO + SrO + BaO CuO 10-50 Al.sub.2 O.sub.3 + B.sub.2 O.sub.3 0-5 RE.sub.2 O.sub.3 0-2 P.sub.2 O.sub.5 28-36 Al.sub.2 O.sub.3 0-5 WO.sub.3 0-7 MnO 0-20 ______________________________________ wherein at least two alkali metal oxides are present and up to 12% by weight fluoride may optionally be present.
    • 本发明涉及显示出转变温度低于375摄氏度,优选低于350摄氏度的玻璃以及优异的耐受沸水侵蚀的玻璃的制备。 该玻璃含有至少10%的铜,以CuO表示,铜以Cu + 2氧化态存在的主要比例。 玻璃基本上以摩尔百分比计的-Li2O 0-15MgO0-15B2O30-5-Na2O 0-20CaO0-20ZnO0-37-K2O 0-10SrO0-20Sb2O30-36-T10-2 0-15BaO0-20CeO20-3-Li2O + Na2O + 12-30MgO + 0-25MoO30-7-K2O + T10CaO + SrO + -BaO-CuO10-50Al2O3 + B2O30-5RE2O30-2-P2O528-36Al2O30-5WO30-7-MnO0-20-,其中至少两种碱金属氧化物 并且可以任选地存在至多12重量%的氟化物。
    • 54. 发明授权
    • Blue transparent glass-ceramic articles
    • 蓝色透明玻璃陶瓷制品
    • US5064460A
    • 1991-11-12
    • US604177
    • 1990-10-29
    • Bruce G. Aitken
    • Bruce G. Aitken
    • C03C3/097C03C10/00C03C10/14C03C10/16
    • C03C10/0045C03C10/16
    • This invention is directed to the formation of blue-to-black transparent glass-ceramic articles containing .beta.-quartz solid solution as essentially the sole crystal phase present therein. The articles are prepared by heat treating reduced precursor glass articles consisting essentially, in weight percent, of 2.5-5% Li.sub.2 O, 1-2% MgO, 18-30% Al.sub.2 O.sub.3, 2-4% TiO.sub.2, 1-4% ZrO.sub.2, 48-70% SiO.sub.2, 1-12% P.sub.2 O.sub.5, and 0-2% ZnO. The precursor glass articles are placed in a reduced state through the inclusion of a sufficient amount of a hydrogen-containing phosphate and/or chloride and/or Ti.sub.2 O.sub.3 to obtain about 0.2-6% of the total titanium content in the form of Ti.sup.+3 ions.
    • 本发明涉及形成基本上存在于其中的唯一晶相的含有β-石英固溶体的蓝 - 黑透明玻璃 - 陶瓷制品。 制品通过热处理基本上重量百分比为2.5-5%Li 2 O,1-2%MgO,18-30%Al 2 O 3,2-4%TiO 2,1-4%ZrO 2,48 -70%SiO 2,1-12%P 2 O 5和0-2%ZnO。 前体玻璃制品通过包含足够量的含氢磷酸盐和/或氯化物和/或Ti 2 O 3以降低的状态放置,以获得Ti + 3形式的总钛含量的约0.2-6% 离子。