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    • 54. 发明授权
    • Secondary battery
    • 二次电池
    • US06884546B1
    • 2005-04-26
    • US09856431
    • 2000-09-11
    • Shigeru FujitaHiroyuki AkashiMomoe Adachi
    • Shigeru FujitaHiroyuki AkashiMomoe Adachi
    • H01M10/05H01M4/13H01M4/131H01M4/133H01M4/40H01M4/52H01M4/525H01M4/58H01M4/587H01M6/16H01M10/0525H01M10/0565H01M10/0568H01M10/0569H01M10/36H01M4/02H01M10/40
    • H01M10/052H01M4/131H01M4/133H01M4/525H01M4/587H01M10/0525H01M10/0565H01M10/0567H01M10/0568H01M10/0569H01M2300/0042
    • Provided is a secondary battery in which high energy density can be obtained and charging/discharging cycle characteristic can be improved. A positive electrode (13) and a negative electrode (15) are stacked with a separator (16) interposed therebetween, and are enclosed inside an exterior can (11) to which an electrolyte is injected. The negative electrode (15) contains a negative electrode material capable of occluding/releasing lithium in an ionic state. Thereby, lithium metal precipitates in the negative electrode (15) in a state where the open circuit voltage is lower than the overcharge voltage. In other words, lithium is occluded in an ionic state in a negative electrode material capable of occluding/releasing lithium in the beginning of charging, and then lithium metal precipitates on the surface of the negative electrode material thereafter during charging. The amount of precipitation of lithium metal is preferable to be from 0.05 to 3.0 times, both inclusive, the ability of charging capacity of the negative electrode material capable of occluding/releasing lithium. Thereby, a high energy density and an excellent cycle characteristic can be obtained.
    • 提供了能够获得高能量密度并且可以提高充放电循环特性的二次电池。 正极(13)和负极(15)之间分隔有隔板(16)堆叠,并被封入设置有电解液的外部罐(11)内。 负极(15)含有能够在离子状态下吸留或释放锂的负极材料。 由此,在开路电压低于过充电电压的状态下,锂金属在负极(15)中析出析出物。 换句话说,在充电开始时,锂能够在能够吸留/释放锂的负极材料中以离子状态封闭,然后在充电期间锂金属在负极材料的表面上析出。 锂金属的析出量优选为能够吸留/释放锂的负极材料的充电能力的0.05〜3.0倍。 因此,可以获得高能量密度和优异的循环特性。