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    • 52. 发明授权
    • Ethylene polymer, catalyst for producing thereof and method for producing thereof
    • 乙烯聚合物,其制造用催化剂及其制造方法
    • US07388059B2
    • 2008-06-17
    • US10876717
    • 2004-06-28
    • Takashi MonoiHidenobu Torigoe
    • Takashi MonoiHidenobu Torigoe
    • C08F4/24C08F110/02
    • C08F10/02C07F7/1804C08F210/16C08F2/001C08F210/14C08F2500/04C08F2500/12
    • A method for producing an ethylene polymer which comprises continuously polymerizing ethylene alone or copolymerizing ethylene and a C3-C8 α-olefin by multistage polymerization in a plurality of polymerization reactors connected in series in the presence of a chromium catalyst having at least a part of chromium atoms converted to hexavalent chromium carried on an inorganic oxide carrier by calcination-activating in a non-reducing atmosphere, wherein an organoaluminum compound of the formula (1): (R1)xAl(OR2)y(OSiR3R4R5)z  (1) (in the above formula, R1 and R2 may be the same or different, each represents a C1-C18 alkyl group or a C6-C18 aryl group, R3, R4 and R5 may be the same or different, each represents a C1-C18 alkyl group or a C6-C18 aryl group, R1, OR2 and OSiR3R4R5 respectively may be the same or different when each has a plurality of kinds, and x, y and z are respectively 0≦x≦3, 0≦y
    • 一种制备乙烯聚合物的方法,其包括在多个连接的聚合反应器中通过多级聚合连续聚合乙烯或共聚乙烯和C 3 -C 8 -C 8α-烯烃 在具有通过在非还原性气氛中煅烧活化的无机氧化物载体上载有至少一部分转化为六价铬的铬原子的铬催化剂存在下,其中式(1)的有机铝化合物: (在线公式)end =“lead”?(R&lt; 1&gt;)xAl(OR 2)y(OSiR&lt; 3(1)<?in-line-formula description =“In-line Formulas”end =“tail”?> (在上式中,R 1和R 2可以相同或不同,各自表示C 1 -C 18 C 1 -C 6烷基或C 6 -C 18芳基,R 3,R 4和R 4, R 5可以相同或不同 t各自表示C 1 -C 18烷基或C 6 -C 18芳基, 分别为R 1,S 2,O 2和OS i R 3 R 4 R 5 5 相同或不同,每个都有多种,x,y和z分别为0 <= x <= 3,0 <= y <3,0 <= z <3,x + y + z = 3 )引入至少一个或所有聚合反应器。
    • 54. 发明申请
    • Ethylene polymer, catalyst for producing thereof and method for producing thereof
    • 乙烯聚合物,其制造用催化剂及其制造方法
    • US20050288459A1
    • 2005-12-29
    • US10876717
    • 2004-06-28
    • Takashi MonoiHidenobu Torigoe
    • Takashi MonoiHidenobu Torigoe
    • B01J31/00C07F7/02C07F7/18C08F2/00C08F10/02C08F210/16
    • C08F10/02C07F7/1804C08F210/16C08F2/001C08F210/14C08F2500/04C08F2500/12
    • A method for producing an ethylene polymer which comprises continuously polymerizing ethylene alone or copolymerizing ethylene and a C3-C8 α-olefin by multistage polymerization in a plurality of polymerization reactors connected in series in the presence of a chromium catalyst having at least a part of chromium atoms converted to hexavalent chromium carried on an inorganic oxide carrier by calcination-activating in a non-reducing atmosphere, wherein an organoaluminum compound of the formula (1): (R1)xAl(OR2)y(OSiR3R4R5)z  (1) (in the above formula, R1 and R2 may be the same or different, each represents a C1-C18 alkyl group or a C6-C18 aryl group, R3, R4 and R5 may be the same or different, each represents a C1-C18 alkyl group or a C6-C18 aryl group, R1, OR2 and OSiR3R4R5 respectively may be the same or different when each has a plurality of kinds, and x, y and z are respectively 0≦x≦3, 0≦y
    • 一种制备乙烯聚合物的方法,其包括在多个连接的聚合反应器中通过多级聚合连续聚合乙烯或共聚乙烯和C 3 -C 8 -C 8α-烯烃 在具有通过在非还原性气氛中煅烧活化的无机氧化物载体上载有至少一部分转化为六价铬的铬原子的铬催化剂存在下,其中式(1)的有机铝化合物: (在线公式)end =“lead”?(R&lt; 1&gt;)xAl(OR 2)y(OSiR&lt; 3(1)<?in-line-formula description =“In-line Formulas”end =“tail”?> (在上式中,R 1和R 2可以相同或不同,各自表示C 1 -C 18 C 1 -C 6烷基或C 6 -C 18芳基,R 3,R 4和R 4, R 5可以相同或不同 nt表示C 1 -C 18烷基或C 6 -C 18芳基, 分别为R 1,S 2,O 2和OS i R 3 R 4 R 5 5 相同或不同,每个都有多种,x,y和z分别为0 <= x <= 3,0 <= y <3,0 <= z <3,x + y + z = 3 )引入至少一个或所有聚合反应器。