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    • 55. 发明授权
    • Method for making alloyed catalysts
    • 制备合金化催化剂的方法
    • US5294580A
    • 1994-03-15
    • US743331
    • 1991-08-08
    • Bryan F. Dufner
    • Bryan F. Dufner
    • B01J23/40B01J23/56B01J23/648B01J23/652B01J23/89B01J37/03H01M4/86H01M4/92H01M4/88
    • H01M4/925B01J23/56H01M4/92H01M4/926H01M2004/8689
    • Adjustment of the noble metal catalytic activity in the production of noble metal alloyed catalyst preparation using alloying metals capable of multiple valence states improves the alloying metal loading. A noble metal is precipitated from a liquid onto a support. Prior to the addition of an alloying metal which is capable of a low valence state having low solubility and a high valence state having high solubility, the catalytic activity of the noble metal precipitate is reduced. Reduction is accomplished by adjusting the temperature and/or pH of the liquid such that a minimal amount of the alloying metal will be converted from the lower to the higher valence state. By maintaining the alloying metal in the lower valence state, a greater amount of the alloying metal which has been dissolved into the liquid is precipitated onto the support, thereby attaining high loadings, reducing waste of the alloying metal, making the loadings predictable, and making the waste liquid more environmentally sound.
    • PCT No.PCT / US91 / 04398 Sec。 371日期1991年8月8日 102(e)日期1991年8月8日PCT 1991年6月21日PCT。1991年6月21日,贵金属合金催化剂制备中贵金属催化剂活性的调节使用能够具有多价态的合金化金属改善合金化金属负载。 贵金属从液体沉淀到载体上。 在添加能够具有低溶解度且具有高溶解度的高价态的低价态的合金金属之前,贵金属沉淀物的催化活性降低。 通过调节液体的温度和/或pH来实现还原,使得最小量的合金金属将从较低价态转化为较高价态。 通过保持合金化金属处于较低价态,已经溶解在液体中的更多量的合金金属沉淀到载体上,从而获得高负荷,减少合金金属的浪费,使得装载可预测,并使 废液更环保。
    • 56. 发明授权
    • Proton exchange membrane fuel cell support plate and an assembly
including the same
    • 质子交换膜燃料电池支撑板和包括其的组件
    • US5264299A
    • 1993-11-23
    • US813472
    • 1991-12-26
    • Myron KrasijPaul R. Watson
    • Myron KrasijPaul R. Watson
    • H01M8/02H01M8/10
    • H01M8/0271H01M8/1007H01M2300/0082
    • A support plate for a proton exchange membrane fuel cell includes a porous support body that has a central portion and a peripheral portion integral with and circumferentially completely surrounding the central portion, and a sealing body of elastomeric sealing material that completely fills the pores of the peripheral portion to make it impermeable to fluids. The support plate may be assembled with another one and with a proton exchange membrane interposed between the two support plates to form an assembly, and the sealing body then peripherally joins and seals the assembly and fills any gaps that may be present between the peripheral portions due to the absence of the membrane from such regions and thus to peripherally encapsulate the membrane.
    • 用于质子交换膜燃料电池的支撑板包括多孔支撑体,其具有与中心部分整体并且周向完全围绕中心部分的中心部分和周边部分,以及完全填充周边孔隙的弹性体密封材料的密封体 部分使其不透液体。 支撑板可以与另一个组装,并且置于两个支撑板之间的质子交换膜以形成组件,并且密封体然后周边连接并密封组件,并填充可能存在于外围部分之间的任何间隙 从而不存在来自这些区域的膜,从而周边地包封膜。
    • 57. 发明授权
    • Internally cooled proton exchange membrane fuel cell device
    • 内部冷却质子交换膜燃料电池装置
    • US5262249A
    • 1993-11-16
    • US813463
    • 1991-12-26
    • Daniel W. BealRichard D. Breault
    • Daniel W. BealRichard D. Breault
    • H01M8/02H01M8/04H01M8/10
    • H01M8/04007H01M8/1007H01M2300/0082H01M8/04029H01M8/04074H01M8/04119H01M8/04156H01M8/04291
    • An internally cooled proton exchange membrane fuel cell device includes a fuel cell including a pair of substantially coextensive electrode components each of which includes a porous central region and a fluid-impermeable peripheral region circumferentially completely surrounding the central region, and a proton exchange membrane component interposed between at least the central regions of the electrode components. The fuel cell device further includes an arrangement for cooling the fuel cell, including at least one enclosed cooling channel situated at the peripheral region of one of the electrode components and supplied with fresh cooling medium, with the spent cooling medium being discharged from the cooling channel. There is further provided a heat transfer device that is operative to transfer heat from the central region to the peripheral region of the one electrode component. This heat transfer device advantageously includes a hermetically sealed casing and, within the casing, a quantity of a heat transfer substance of the type that evaporates at temperatures below those reached by a central zone of the casing during the operation of the fuel cell and condenses at temperatures above those prevailing at a peripheral zone of the casing during the operation of the cooling arrangement.
    • 内部冷却的质子交换膜燃料电池装置包括燃料电池,其包括一对基本上共同延伸的电极部件,每个电极部件包括多孔中心区域和周向完全围绕中心区域的流体不可渗透的周边区域,以及插入 至少在电极组件的中心区域之间。 燃料电池装置还包括用于冷却燃料电池的装置,包括至少一个封闭的冷却通道,该冷却通道位于电极组件之一的周边区域并被供给新鲜的冷却介质,而废冷却介质从冷却通道 。 还提供了一种传热装置,其可操作以将热量从中心区域传递到一个电极部件的周边区域。 该传热装置有利地包括密封的壳体,并且在壳体内部具有一定量的传热物质,该传热物质在燃料电池运行期间在壳体的中心区域达到的温度以下而蒸发,并在 在冷却装置的操作期间,高于外壳周边区域的温度。