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41. 发明授权

US4055586A Process for the manufacture of bis-(2-cyanoethyl)-amine 失效
标题翻译：制备双（2-氰基乙基） - 胺的方法
公开(公告)号：US4055586A
公开(公告)日：1977-10-25
申请号：US733999
申请日：1976-10-20
申请人： Hans Feichtinger , Wolfgang Payer , Boy Cornils , Jurgen Weber
发明人： Hans Feichtinger , Wolfgang Payer , Boy Cornils , Jurgen Weber
IPC分类号： C07C20060101 , C07C255/24 , C07C120/00 , C07C121/43
CPC分类号： C07C253/30
摘要： A process for the manufacture of bis-(2-cyanoethyl)-amine wherein gaseous ammonia is reacted with acrylonitrile having a 5-15% by weight water content in a bubble column reactor. The reaction is carried out at a temperature of about 20.degree.-80.degree. C.
摘要翻译：一种制备双（2-氰基乙基） - 胺的方法，其中气泡氨与在气泡塔反应器中具有5-15重量％水含量的丙烯腈反应。反应在约20-80℃的温度下进行。

42. 发明授权

US4048211A Modification of methadone synthesis process step 失效
标题翻译：美沙酮合成工艺步骤的修改
公开(公告)号：US4048211A
公开(公告)日：1977-09-13
申请号：US685034
申请日：1976-05-10
申请人： Charles J. Barnett
发明人： Charles J. Barnett
IPC分类号： C07C255/32 , C07C120/00 , C07C121/78
CPC分类号： C07C255/00
摘要： Alkylation of diphenylacetonitrile in methadone synthesis is carried out in presence of sodium hydroxide and DMF.
摘要翻译：美沙酮合成中二苯基乙腈的烷基化在氢氧化钠和DMF存在下进行。

43. 发明授权

US3988360A Process for preparing iminodiacetonitrile 失效
标题翻译：亚氨基乙腈的制备方法
公开(公告)号：US3988360A
公开(公告)日：1976-10-26
申请号：US611369
申请日：1975-09-08
申请人： Roger Robert Gaudette , James Edward Philbrook , Jon Carl Thunberg
发明人： Roger Robert Gaudette , James Edward Philbrook , Jon Carl Thunberg
IPC分类号： C07C255/24 , C07C120/00
CPC分类号： C07C255/00
摘要： Iminodiacetonitrile is prepared by a process comprising: (a) forming an aqueous reaction mixture by admixing water, hexamethylenetetramine, formaldehyde, and HCN; and (b) forming iminodiacetonitrile by passing the aqueous reaction mixture through a continuous reaction zone while maintaining the temperature within the continuous reaction zone at 50.degree.-250.degree. C. The resulting iminodiacetonitrile can be recovered or it can be hydrolyzed to form an alkali metal salt of iminodiacetic acid which can be recovered or converted to iminodiacetic acid which can be recovered.In other embodiments: (a) the hexamethylenetetramine solution and the formaldehyde solution can be combined before being admixed with the HCN; or (b) the formaldehyde solution and the HCN can be admixed with a stabilizing acid to form an acid stabilized aqueous solution of formaldehyde and HCN before being admixed with the hexamethylenetetramine solution in the reaction zone in which iminodiacetonitrile is formed.
摘要翻译：亚氨基二乙腈通过以下方法制备，该方法包括：（a）通过混合水，六亚甲基四胺，甲醛和HCN形成水性反应混合物; 和（b）通过使含水反应混合物通过连续反应区而形成亚氨基乙腈，同时将连续反应区内的温度保持在50-250℃。所得亚氨基二乙腈可以回收，或者可以水解形成碱金属可以回收或转化为可回收的亚氨基二乙酸的亚氨基二乙酸盐。

44. 发明授权

US3966791A Preparation of dialkyl amino acrylonitrile 失效
标题翻译：二烷基氨基丙烯腈的制备
公开(公告)号：US3966791A
公开(公告)日：1976-06-29
申请号：US574164
申请日：1975-05-02
申请人： Willy Leimgruber , Manfred Weigele
发明人： Willy Leimgruber , Manfred Weigele
IPC分类号： C07C255/30 , C07C120/00
CPC分类号： C07C255/00
摘要： A process for preparing dialkyl amino acrylonitrile by condensing acetonitrile and an acetal of dimethyl formamide. The dialkyl amino acrylonitrile is an intermediate for aminomethylene malononitrile, a valuable intermediate for thiamine.
摘要翻译：通过缩合乙腈和二甲基甲酰胺的缩醛制备二烷基氨基丙烯腈的方法。二烷基氨基丙烯腈是氨基亚甲基丙二腈的中间体，是硫胺素的有价值的中间体。

45. 发明授权

US3963769A Substituted trimethylene cyclopropanes, salts thereof, intermediates and methods of making the same 失效
标题翻译：取代的三亚甲基环丙烷，其盐，中间体及其制备方法
公开(公告)号：US3963769A
公开(公告)日：1976-06-15
申请号：US535138
申请日：1974-12-20
申请人： Tadamichi Fukunaga
发明人： Tadamichi Fukunaga
IPC分类号： C07D213/20 , G03C1/73 , C07C120/00 , C07C121/46 , C07C121/48
CPC分类号： G03C1/73 , C07C45/68 , C07C49/21 , C07D213/20
摘要： Trimethylenecyclopropane wherein all six hydrogen atoms are symmetrically substituted with cyano, alkoxycarbonyl or carbacyl groups and which are salt-forming can be made by reacting tetrachlorocyclopropene with the appropriate active methylene compound such as malononitrile, acetyl acetone or ethyl cyanoacetate. Using limited amounts of malononitrile and a tertiary amine, a tetracyanodimethylenecyclopropene substituted with a quaternary ammonium group is obtained, which reacts with other active methylene compounds including the above, nitroalkanes, benzoylacetonitrile, benzenesulfonylacetonitrile, and dialkyl sulfones to form unsymmetrical substituted trimethylenecyclopropane. The neutral compounds are useful as organic oxidants. Their radical anion salts are useful as organic conductors and as dyes, and the dianion salts are useful as image formers on transparent films or on opaque substrates.
摘要翻译：三甲基环丙烷，其中所有六个氢原子被氰基，烷氧基羰基或碳酰基对称取代，并且其形成盐可以通过使四氯环丙烯与适当的活性亚甲基化合物如丙二腈，乙酰丙酮或氰基乙酸乙酯反应来制备。使用有限量的丙二腈和叔胺，得到被季铵基取代的四氰基二甲基环己烯丙基，其与包括上述的其它活性亚甲基化合物，硝基烷烃，苯甲酰基乙腈，苯磺酰基乙腈和二烷基砜反应形成不对称取代的三甲基环丙烷。中性化合物可用作有机氧化剂。它们的自由基阴离子盐可用作有机导体和染料，并且二价阴离子盐可用作透明膜上或不透明基底上的成像剂。

46. 发明授权

US3956358A Dimerization method 失效
标题翻译：二聚法
公开(公告)号：US3956358A
公开(公告)日：1976-05-11
申请号：US537297
申请日：1974-12-30
申请人： Olav Torgeir Onsager
发明人： Olav Torgeir Onsager
IPC分类号： C07C253/00 , B01J21/00 , B01J23/06 , B01J27/00 , B01J27/08 , B01J31/00 , B01J31/02 , B01J31/12 , C07B20060101 , C07B61/00 , C07C51/00 , C07C51/353 , C07C57/00 , C07C67/00 , C07C69/52 , C07C255/09 , C07C120/00
CPC分类号： C07C255/00
摘要： Derivatives of the .alpha.,.beta.-unsaturated carboxylic acids are dimerized by reaction in the presence of a catalyst consisting essentially of (a) at least one metal compound of the formula M(X).sub.n wherein M is zinc, aluminum, titanium, vanadium, iron, or cobalt, X is a halide and n is a number equal to the valence of the metal M and (b) at least one nitrogen-containing Lewis Base which is (1) a tertiary monoaryl amine of the formula, ##EQU1## wherein R.sup.1 and R.sup.2 are the same or different and each is an alkyl group or a cycloalkyl group with at least one of R.sup.1 and R.sup.2 containing at least two carbon atoms; or (2) a tertiary monobenzyl amine of the formula, ##EQU2## wherein R.sup.3 and R.sup.4 are the same or different and each is an alkyl or cycloalkyl radical; or (3) a tertiary di- or poly-functional amine which contains at least two Lewis Base nitrogen groups which are separated from each other by at least one carbon atom, and are (a) N-disubstituted amino groups wherein each N-substituent is the same or different and is an alkyl, cycloalkyl, benzyl, aryl radical or (b) N-heterocyclic groups containing 3 to 20 carbon atoms; or (4) an N-substituted heterocyclic amine wherein the N-substituent is an alkyl, benzyl, cycloalkyl or aryl radical.
摘要翻译： α，β-不饱和羧酸的衍生物在催化剂存在下通过反应进行二聚，所述催化剂基本上由（a）至少一种式M（X）n的金属化合物，其中M是锌，铝，钛，钒，铁或钴，X是卤化物，n是等于金属M的化合价的数，和（b）至少一种含氮的路易斯碱，其是（1）下式的叔二芳基胺R1 ANGLE N 其中R 1和R 2相同或不同，并且各自是具有至少一个含有至少两个碳原子的R 1和R 2的烷基或环烷基; 或（2）下式的叔单苄基胺，其中R 3和R 4相同或不同，并且各自为烷基或环烷基; 或（3）含有至少两个通过至少一个碳原子彼此分离的路易斯碱氮基团的叔二 - 或多官能胺，并且是（a）N-二取代的氨基，其中每个N-取代基是相同或不同的，是烷基，环烷基，苄基，芳基或（b）含有3-20个碳原子的N-杂环基; 或（4）N-取代的杂环胺，其中N-取代基是烷基，苄基，环烷基或芳基。

47. 发明授权

US3950370A Process of dimerization 失效
标题翻译：二维过程
公开(公告)号：US3950370A
公开(公告)日：1976-04-13
申请号：US537296
申请日：1974-12-30
申请人： Olav Torgeir Onsager
发明人： Olav Torgeir Onsager
IPC分类号： C07B61/00 , B01J21/10 , B01J23/16 , B01J27/00 , B01J27/08 , B01J31/00 , B01J31/12 , B01J31/32 , B01J31/34 , C07C67/00 , C07C253/00 , C07C255/09 , C07C120/00
CPC分类号： C07C255/00
摘要： Acrylonitrile is dimerized by reaction in the presence of a catalyst consisting essentially of (a) at least one metal compound of the formula M(X).sub.n wherein M is magnesium, chromium or manganese, X is a halide and n is a number equal to the valence of the metal M and (b) at least one nitrogen-containing Lewis Base which is (1) a tertiary monoamine of the formula ##EQU1## wherein R.sup.1, R.sup.2, and R.sup.3 are the same or different and each is an alkyl, cycloalkyl, benzyl or aryl radical; or (2) a tertiary di- or poly-functional amine which contains at least two Lewis Base nitrogen groups separated from each other by at least one carbon atom, and which are (a) N-disubstituted amino groups wherein each N-substituent is the same or different and is an alkyl, cycloalkyl, benzyl or aryl radical, or (b) N-heterocyclic groups containing three to 20 carbon atoms; or (3) an N-substituted heterocyclic amine containing three to 20 carbon atoms in the heterocyclic ring wherein the N-substituent is an alkyl, cycloalkyl, benzyl or aryl radical.

48. 发明授权

US3946066A Dimerisation process and catalyst 失效
标题翻译：二聚过程和催化剂
公开(公告)号：US3946066A
公开(公告)日：1976-03-23
申请号：US501605
申请日：1974-08-29
申请人： Peter Frank Todd
发明人： Peter Frank Todd
IPC分类号： B01J23/46 , B01J23/56 , C07B61/00 , C07C67/00 , C07C253/00 , C07C255/04 , C07C120/00
CPC分类号： B01J23/56 , B01J23/462
摘要： A ruthenium catalyst of improved performance for the dimerisation and hydrodimerisation of olefinically unsaturated compounds, especially acrylonitrile, is obtained by co-precipitating a ruthenium compound with an aluminium oxide and/or hydroxide.
摘要翻译：通过使钌化合物与氧化铝和/或氢氧化物共沉淀，得到烯属不饱和化合物，特别是丙烯腈的二聚和加氢二聚化改进性能的钌催化剂。

49. 发明授权

US3914280A Process for producing {62 -aminopropionitrile 失效
标题翻译：生产{62-氨基丙腈的方法
公开(公告)号：US3914280A
公开(公告)日：1975-10-21
申请号：US47502774
申请日：1974-05-31
申请人： DAIICHI SEIYAKU CO
发明人： YAMAKAMI KIYOSHI , AKAZAWA OSAMU , SHIBATA YOSHIYUKI , FUJIMOTO NICHIO
IPC分类号： C07C237/06 , C07C67/00 , C07C227/00 , C07C227/26 , C07C229/08 , C07C253/00 , C07C255/24 , C07C120/00
CPC分类号： C07C253/30 , C07C255/24
摘要： Beta -Aminopropionitrile is produced by introducing acylonitrile into an equilibrium reaction mixture of imino- Beta - Beta ''-propionitrile and excess ammonia.
摘要翻译：通过将酰基腈引入到亚氨基-β-β'-丙腈和过量氨的平衡反应混合物中来制备β-氨基丙腈。

50. 发明授权

US3897318A Single-compartment electrolytic hydrodimerization process 失效
标题翻译：单室电解加氢二聚工艺
公开(公告)号：US3897318A
公开(公告)日：1975-07-29
申请号：US49780074
申请日：1974-08-15
申请人： MONSANTO CO
发明人： HECKLE WILLIAM A , SADLER DONALD L
IPC分类号： C25B3/10 , C07C103/14 , C07C120/00 , C25B11/04
CPC分类号： C25B3/105
摘要： In a process for hydrodimerizing an olefinic nitrile, amide or ester by electrolyzing an aqueous solution of the olefinic compound, quaternary ammonium or phosphonium ions and an alkali metal phosphate, borate or carbonate in a single-compartment cell, anode corrosion is substantially lessened by use of a cell having an anode consisting essentially of carbon steel. Even at relatively high temperatures and current densities, corrosion of such an anode is surprisingly slow. Even lower rates of corrosion of such an anode are achieved when the electrolyzed solution contains an alkali metal phosphate and an alkali metal borate.
摘要翻译：在通过在单室电池中电解烯烃化合物的水溶液，季铵或鏻离子和碱金属磷酸盐，硼酸盐或碳酸盐的烯烃腈，酰胺或酯进行氢化二聚的方法中，通过使用基本上减轻了阳极腐蚀的具有主要由碳钢组成的阳极的电池。即使在较高的温度和电流密度下，这种阳极的腐蚀也令人惊讶地缓慢。当电解溶液含有碱金属磷酸盐和碱金属硼酸盐时，这种阳极的腐蚀速率甚至更低。

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