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    • 44. 发明授权
    • Chromium-cobalt fine alloy powder and process for producing same
    • 铬钴合金粉及其制造方法
    • US4684401A
    • 1987-08-04
    • US861884
    • 1986-05-12
    • Judith A. LaddClarence D. Vanderpool
    • Judith A. LaddClarence D. Vanderpool
    • B22F1/00B22F9/22C22B5/12C22B23/02C22B34/32
    • C22B5/12B22F1/0048B22F9/22C22B23/021C22B34/32Y10S75/953
    • A chromium-cobalt alloy fine powder is disclosed which consists essentially of spheres with the chromium and cobalt being relatively uniformly distributed throughout the particles of the powder. The process for producing the powder is disclosed. The process involves firing a relatively uniform admixture consisting essentially of anhydrous cobalt (II) chloride and chromium (III) chloride in a furnace in a hydrogen atmosphere at a first temperature of at least about 400.degree. C. and below the sublimation temperature of chromium (III) chloride for a time sufficient to reduce essentially all of the cobalt (II) chloride to cobalt metal and to reduce essentially all of the chromium (III) chloride to chromium (II) chloride. The temperature is elevated to a second temperature of at least about 750.degree. C. and below the sublimation temperature of chromium (II) chloride. The elevation is done by raising the temperature in increments of about 100.degree. C. and holding at the elevated temperature until the evolution of HCl gas ceases. The first reduced mixture is fired at the second temperature for a time sufficient to to reduce essentially all of the chromium (II) chloride to chromium metal without causing appreciable melting of the cobalt metal, to form the alloy powder which is then cooled in a non-oxidizing atmosphere.
    • 公开了一种铬钴合金细粉末,其基本上由具有相对均匀分布在粉末颗粒中的铬和钴的球体组成。 公开了制造粉末的方法。 该方法包括在氢气氛中的炉中,在至少约400℃的第一温度和低于铬的升华温度(1)的温度下,在熔炉中焙烧基本上由无水氯化钴(II)和氯化铬(III)组成的相对均匀的混合物 III)氯化物的时间足以将氯化钴(II)基本上全部还原成钴金属,并将氯化物基本上全部还原成氯化铬(II)。 将温度升高至至少约750℃并低于氯化铬(II)的升华温度的第二温度。 升高通过以约100℃的增量升高温度并保持在升高的温度直到HCl气体的释放停止。 将第一种还原的混合物在第二温度下烧制足以将氯化铬(II)全部还原成铬金属的时间,而不引起钴金属明显的熔化,形成合金粉末,然后将其冷却成非金属 氧化气氛。