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41. 发明申请

US20110053036A1 Polyelectrolyte Membranes Made Of Poly(Perfluorocyclobutanes) With Pendant Perfluorosulfonic Acid Groups and Blends With Poly(Vinylidene Fluoride) 有权
标题翻译：由聚（亚乙烯基氟）与全氟磺酸基团和共混物制成的聚（全氟环丁烷）聚电解质膜
公开(公告)号：US20110053036A1
公开(公告)日：2011-03-03
申请号：US12548350
申请日：2009-08-26
申请人： Timothy J. Fuller , Sean M. Mackinnon , Michael R. Schoeneweiss
发明人： Timothy J. Fuller , Sean M. Mackinnon , Michael R. Schoeneweiss
IPC分类号： H01M8/10 , C08G61/12 , C08L63/00
CPC分类号： H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1044
摘要： A polymer useful as an ion conductor in fuel cells includes a perfluorocyclobutyl moiety and pendant PFSA side groups. The polymer is made by a variation of the Ullmann reaction. Ion conducting membranes incorporating the polymer are provided.
摘要翻译：在燃料电池中用作离子导体的聚合物包括全氟环丁基部分和PFSA侧基侧基。聚合物通过Ullmann反应的变化来制备。提供了结合聚合物的离子导电膜。

42. 发明申请

US20110049746A1 Method of manufacturing reinforced electrolyte membrane and membrane electrode assembly 审中-公开
标题翻译：制造增强电解质膜和膜电极组件的方法
公开(公告)号：US20110049746A1
公开(公告)日：2011-03-03
申请号：US12926249
申请日：2010-11-04
申请人： Hiroshi Suzuki
发明人： Hiroshi Suzuki
IPC分类号： H01M8/10 , B29C47/06
CPC分类号： H01M8/0295 , B01D67/002 , B01D69/10 , B01D2323/08 , B01D2323/46 , B01D2325/42 , B29C48/08 , B29C48/15 , B29L2031/755 , B32B37/153 , B32B38/08 , B32B2457/18 , H01M8/1039 , H01M8/1044 , H01M8/106 , H01M8/1083 , H01M8/1088 , H01M2250/20 , H01M2300/0082 , H01M2300/0085 , H01M2300/0091 , Y02E60/521 , Y02P70/56 , Y02T90/32
摘要： To manufacture by a simple method a reinforced electrolyte membrane obtained by directly impregnating a molten electrolyte resin into a porous reinforced membrane. Further, to easily manufacture a membrane electrode assembly including the reinforced electrolyte membrane by slightly changing the method of manufacturing a reinforced electrolyte membrane. A heated and molten electrolyte resin p is extruded from a resin discharge port 3 of a die 2, and the extruded molten electrolyte resin p is supplied into a porous reinforced membrane 6. The porous reinforced membrane 6 supplied by two heated rotating rolls 4 arranged opposite to each other is embedded into the molten electrolyte resin p, and the molten electrolyte resin p is impregnated into the porous reinforced membrane 6, so that a reinforced electrolyte membrane 20 is formed. It is also possible to manufacture a membrane electrode assembly 40 including the reinforced electrolyte membrane 20 by applying electrode catalyst particles 31 to the surface of the rotating rolls 4.
摘要翻译：通过简单的方法制造通过将熔融的电解质树脂直接浸渍到多孔增强膜中获得的增强电解质膜。此外，通过稍微改变制造增强电解质膜的方法，容易制造包括增强电解质膜的膜电极组件。从模具2的树脂排出口3挤出加热熔融的电解质树脂p，将挤出的熔融电解质树脂p供给到多孔增强膜6中。多孔增强膜6由相对配置的两个加热的旋转辊4供给彼此嵌入熔融电解质树脂p中，并且将熔融的电解质树脂p浸渍到多孔增强膜6中，从而形成增强的电解质膜20。通过将电极催化剂粒子31施加到旋转辊4的表面，也可以制造包括增强电解质膜20的膜电极组件40。

43. 发明申请

US20110039185A1 ELECTROLYTE MEMBRANE FOR POLYMER ELECTROLYTE FUEL CELL AND METHOD OF MANUFACTURING THE SAME 失效
标题翻译：聚合物电解质燃料电池用电解质膜及其制造方法
公开(公告)号：US20110039185A1
公开(公告)日：2011-02-17
申请号：US12988572
申请日：2009-04-22
申请人： Hiroyuki Nishii , Tooru Sugitani , Otoo Yamada , Sakura Toshikawa
发明人： Hiroyuki Nishii , Tooru Sugitani , Otoo Yamada , Sakura Toshikawa
IPC分类号： H01M8/10 , B05D5/12
CPC分类号： H01B1/122 , C08G73/1042 , C08G73/1046 , C08G73/105 , C08G73/1067 , C08G73/1071 , C08J5/20 , C08J5/2275 , C08J2379/08 , C08L79/08 , H01M8/1004 , H01M8/1011 , H01M8/1023 , H01M8/103 , H01M8/1044 , H01M8/1053 , H01M2300/0082 , H01M2300/0094 , Y02E60/523 , Y02P70/56
摘要： An electrolyte membrane (1) includes a base material layer (1) containing a hydrocarbon-based electrolyte as a main component, and a surface layer (5) laminated with the base material layer (1). The surface layer (5) is a layer containing, as a main component, a polymeric material having a hydroxyl group and a proton conductive group. The polymeric material that constitutes the surface layer (5) contains, for example, a first polymer having a hydroxyl group, and a second polymer having a proton conductive group. A matrix is formed by cross-linking the first polymer, and the second polymer can be held in the matrix.
摘要翻译：电解质膜（1）包括以烃系电解液为主要成分的基材层（1）和层叠有基材层（1）的表层（5）。表面层（5）是含有具有羟基和质子传导性基团的聚合物材料作为主要成分的层。构成表面层（5）的聚合物材料包含例如具有羟基的第一聚合物和具有质子传导性基团的第二聚合物。通过交联第一聚合物形成基质，第二聚合物可以保持在基质中。

44. 发明授权

US07875392B2 Polymer electrolyte membrane having high durability and method for producing the same 有权
公开(公告)号：US07875392B2
公开(公告)日：2011-01-25
申请号：US10874246
申请日：2004-06-24
申请人： Naoto Miyake , Masanobu Wakizoe , Eiji Honda
发明人： Naoto Miyake , Masanobu Wakizoe , Eiji Honda
IPC分类号： H01M6/18 , H01M8/10
CPC分类号： H01B1/122 , C08J5/2281 , C08J2327/18 , H01M4/921 , H01M4/926 , H01M8/0289 , H01M8/1004 , H01M8/1023 , H01M8/103 , H01M8/1039 , H01M8/1044
摘要： A polymer electrolyte membrane comprising: (a) a fluorinated polymer electrolyte having an ion exchange group, and (b) a basic polymer, wherein, optionally, at least a part of component (a) and at least a part of component (b) are chemically bonded to each other. A method for producing the above-mentioned polymer electrolyte membrane. A membrane/electrode assembly comprising the above-mentioned polymer electrolyte membrane which is securely sandwiched between an anode and a cathode. A polymer electrolyte fuel cell comprising the membrane/electrode assembly.

45. 发明授权

US07816052B2 Portion conductive electrolyte, method of preparing the same, electrode for fuel cell, method of manufacturing the electrode, and fuel cell including the same 有权
标题翻译：部分导电电解质，其制备方法，燃料电池用电极，电极的制造方法以及包含该电极的燃料电池
公开(公告)号：US07816052B2
公开(公告)日：2010-10-19
申请号：US11441000
申请日：2006-05-26
申请人： Myung-dong Cho , Jung-ock Park
发明人： Myung-dong Cho , Jung-ock Park
IPC分类号： H01M6/14
CPC分类号： H01M8/1081 , C08J5/2268 , C08J2375/04 , C08J2387/00 , H01B1/122 , H01M4/8605 , H01M4/8803 , H01M8/1023 , H01M8/1027 , H01M8/103 , H01M8/1039 , H01M8/1044 , H01M2008/1095 , H01M2300/0082 , Y02P70/56
摘要： A proton conductive electrolyte including a polymerized polyurethane, polyethylene(metha)acrylic acid (PEAA), and a cross-linking agent mixture; a method of preparing the same; an electrode including a support and a catalyst layer, the catalyst layer including a supported catalyst and a polymerized mixture of a polyurethane based compound and a polyethylene(metha)acrylic acid; a method of preparing the electrode; and a fuel cell including the proton conductive electrolyte and/or the electrode. The proton conductive electrolyte can be prepared at lower costs than conventionally used polybenzimidazole and NAFION and can be easily formed into a membrane with a controlled thickness by casting. The polymer electrolyte membrane has high mechanical strength, flexibility, and excellent ionic conductivity. The electrode remains stable under high temperature operation, a strong binding force is maintained between the support and the catalyst layer, and the electrode has excellent ionic conductivity. The fuel cell produced using the proton conductive electrolyte and/or the electrode can operate at 100° C. or higher under non-humidified conditions and exhibits an improved performance.
摘要翻译：包含聚合的聚氨酯，聚乙烯（甲基）丙烯酸（PEAA）和交联剂混合物的质子传导电解质; 其制备方法; 包括载体和催化剂层的电极，所述催化剂层包括负载型催化剂和聚氨酯基化合物与聚乙烯（甲基）丙烯酸的聚合混合物; 制备电极的方法; 以及包括质子传导性电解质和/或电极的燃料电池。质子传导电解质可以以比常规使用的聚苯并咪唑和NAFION更低的成本制备，并且可以通过铸造容易地形成具有受控厚度的膜。聚合物电解质膜具有高机械强度，柔韧性和优异的离子导电性。电极在高温操作下保持稳定，在支撑体和催化剂层之间保持牢固的结合力，电极具有优异的离子导电性。使用质子传导电解质和/或电极制造的燃料电池可在非加湿条件下在100℃或更高温度下工作，并且表现出改进的性能。

46. 发明申请

US20100173222A1 SOLID POLYMER FUEL CELL-PURPOSE ELECTROLYTE MEMBRANE, PRODUCTION METHOD THEREFOR, AND MEMBRANE-ELECTRODE ASSEMBLY 有权
标题翻译：固体聚合物燃料电池用电解质膜，其制造方法和膜电极组件
公开(公告)号：US20100173222A1
公开(公告)日：2010-07-08
申请号：US12438012
申请日：2007-08-29
申请人： Hiroshi Suzuki , Yoshitaka Kino
发明人： Hiroshi Suzuki , Yoshitaka Kino
IPC分类号： H01M8/10
CPC分类号： B05D1/12 , H01M8/0258 , H01M8/0271 , H01M8/0276 , H01M8/0284 , H01M8/0286 , H01M8/0289 , H01M8/1007 , H01M8/1044 , H01M8/1053 , H01M8/1058 , H01M8/1065 , H01M8/1067 , H01M8/1083 , H01M8/109 , H01M8/1093 , Y02P70/56
摘要： In an electrolyte membrane (10) for a solid polymer fuel cell, sealing ribs (12) of a predetermined height made of an electrolyte resin is formed integrally with the electrolyte membrane (10). Using the electrolyte membrane, a membrane-electrode assembly (20) is formed, which is further processed into a fuel cell (30). Thus, an electrolyte membrane and a membrane-electrode assembly which are capable of improving the sealing characteristic when incorporated into a fuel cell are obtained. Besides, a fuel cell improved in the sealing characteristic is obtained.
摘要翻译：在用于固体聚合物燃料电池的电解质膜（10）中，与电解质膜（10）一体地形成由电解质树脂制成的预定高度的密封肋（12）。使用电解质膜形成膜 - 电极组件（20），其进一步加工成燃料电池（30）。因此，获得当结合到燃料电池中时能够改善密封特性的电解质膜和膜 - 电极组件。此外，获得了密封特性提高的燃料电池。

47. 发明授权

US07695843B2 Microfibrous fuel cell assemblies comprising fiber-supported electrocatalyst layers, and methods of making same 失效
标题翻译：包含纤维支撑的电催化剂层的微纤维燃料电池组件及其制造方法
公开(公告)号：US07695843B2
公开(公告)日：2010-04-13
申请号：US11030703
申请日：2005-01-06
申请人： Ray R. Eshraghi , Changquig Lin , Jung-Chou Lin , Martin E. Ketterer
发明人： Ray R. Eshraghi , Changquig Lin , Jung-Chou Lin , Martin E. Ketterer
IPC分类号： H01M2/00 , H01M4/00 , B05D5/12 , B01J49/00
CPC分类号： H01M4/8807 , H01M4/8605 , H01M4/8626 , H01M4/8817 , H01M4/8846 , H01M4/92 , H01M4/921 , H01M4/928 , H01M8/004 , H01M8/0234 , H01M8/0247 , H01M8/0252 , H01M8/0278 , H01M8/04089 , H01M8/1004 , H01M8/1023 , H01M8/1027 , H01M8/1032 , H01M8/1039 , H01M8/1044 , H01M8/106 , H01M8/1062 , H01M8/241 , H01M8/2418 , H01M8/243 , H01M2250/30 , Y02B90/18
摘要： A microfibrous fuel cell structure of elongated form with a longitudinal axis. Such microfibrous fuel cell includes electrocatalyst layers supported by a fiber network formed of unidirectional or substantially unidirectional conductive fibers. The conductive fibers of such fiber network are oriented parallelly or substantially parallelly to the longitudinal axis of the fuel cell, therefore allowing such fiber network to conform to the curvature of the microfibrous fuel cell along the radial direction but without causing overbending of the individual fibers.
摘要翻译：具有纵向轴线的细长形式的微纤维燃料电池结构。这种微纤维燃料电池包括由单向或基本上单向导电纤维形成的纤维网支撑的电催化剂层。这种纤维网络的导电纤维与燃料电池的纵向轴线平行或基本上平行地定向，从而允许这种纤维网络沿着径向方向符合微纤维燃料电池的曲率，但是不会引起单个纤维的过度弯曲。

48. 发明授权

US07629426B2 Blend of ionic (co)polymer resins and matrix (co)polymers 有权
标题翻译：离子（共）聚合物树脂和基质（共）聚合物的共混物
公开(公告)号：US07629426B2
公开(公告)日：2009-12-08
申请号：US12141390
申请日：2008-06-18
申请人： James T. Goldbach
发明人： James T. Goldbach
IPC分类号： C08F30/02 , C08F230/02 , C08F12/30 , C08F28/02 , C08F128/02 , C08F228/02
CPC分类号： B01D71/34 , B01D67/0093 , B01D71/28 , B01D71/32 , B01D71/38 , B01D71/40 , B01D71/44 , B01D71/82 , B01D2323/30 , C08F8/12 , C08F8/26 , C08F8/34 , C08F8/44 , C08F12/30 , C08F212/14 , C08L25/18 , C08L27/16 , C08L29/04 , C08L29/10 , H01M6/181 , H01M8/1004 , H01M8/1023 , H01M8/1044 , H01M8/1081 , H01M10/052 , H01M10/0565 , H01M2300/0082 , Y02P70/56 , Y10T428/1352 , C08F112/14 , C08F120/58 , C08L2666/04 , C08F16/06 , C08F116/08 , C08F216/08 , C08F2220/281 , C08F128/02
摘要： The invention relates to polymeric resin blends containing polyelectrolyte resins blended into a polymer or copolymer matrix. Specifically, the polyelectrolyte resins are (co)polymers without hydrolyzable groups. The matrix polymer is a tough, and highly chemical-resistant (co)polymer, preferably a fluoropolymer. The polymeric resin blend is useful for forming films, and especially films useful for MEAs for use in fuel cells.
摘要翻译：本发明涉及含有聚电解质树脂的聚合物树脂共混物，其混合到聚合物或共聚物基质中。具体地说，聚电解质树脂是不含可水解基团的（共）聚合物。基质聚合物是韧性高且耐化学性（共）聚合物，优选含氟聚合物。聚合树脂共混物可用于形成膜，特别是可用于燃料电池中的多溴联苯的膜。

49. 发明授权

US07604886B2 Polymer membrane for fuel cell, method of preparing the same, and stack for fuel cell and fuel cell system comprising the same 有权
标题翻译：用于燃料电池的聚合物膜，其制备方法以及用于燃料电池和包含该燃料电池的燃料电池系统的堆叠
公开(公告)号：US07604886B2
公开(公告)日：2009-10-20
申请号：US11390162
申请日：2006-03-28
申请人： Hee-Tak Kim , Hae-Kwon Yoon , Jun-Won Suh
发明人： Hee-Tak Kim , Hae-Kwon Yoon , Jun-Won Suh
IPC分类号： H01M8/10
CPC分类号： H01M8/1081 , H01M8/0289 , H01M8/1016 , H01M8/1044 , H01M8/1051 , H01M8/1053 , H01M8/106 , H01M8/1062 , Y02P70/56
摘要： The polymer electrolyte membrane of the present invention includes a porous supporter having pores, and a metal ion adsorptive material and a proton conductive polymer which are present in the pores of the porous supporter.
摘要翻译：本发明的高分子电解质膜包括具有孔的多孔性支持体和存在于多孔质支持体的孔中的金属离子吸附材料和质子传导性聚合物。

50. 发明申请

US20090239114A1 POLYMER ELECTROLYTE FUEL CELL 审中-公开
标题翻译：聚合物电解质燃料电池
公开(公告)号：US20090239114A1
公开(公告)日：2009-09-24
申请号：US11721297
申请日：2005-09-12
申请人： Yasutaka Kouno , Satoshi Tomoeda , Yoshimi Kubo , Tsutomu Yoshitake , Takeshi Obata
发明人： Yasutaka Kouno , Satoshi Tomoeda , Yoshimi Kubo , Tsutomu Yoshitake , Takeshi Obata
IPC分类号： H01M8/10
CPC分类号： H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1044 , H01M8/1072 , Y02P70/56
摘要： A polymer electrolyte fuel cell which has a polymer electrolyte membrane, an anode disposed on one side of the polymer electrolyte membrane and a cathode disposed on the other side of the polymer electrolyte membrane, wherein an organic fuel is supplied to the anode, and wherein the anode has an anode catalyst layer containing a catalyst and a proton-conducting material, and the cathode has a cathode catalyst layer containing a catalyst, a proton-conducting material and an oxygen-permeating material.
摘要翻译：一种高分子电解质型燃料电池，其具有聚合物电解质膜，阳极，位于高分子电解质膜的一侧，阴极配置在高分子电解质膜的另一侧，其中向阳极供给有机燃料，其中，阳极具有包含催化剂和质子传导材料的阳极催化剂层，阴极具有含有催化剂，质子传导材料和透氧材料的阴极催化剂层。

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