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    • 43. 发明授权
    • Quantitative measurement of isotope ratios by time-of-flight mass spectrometry
    • 通过飞行时间质谱定量测定同位素比
    • US07932491B2
    • 2011-04-26
    • US12365354
    • 2009-02-04
    • Marvin L. Vestal
    • Marvin L. Vestal
    • H01J49/00
    • H01J3/14H01J49/004H01J49/061H01J49/40
    • A mass spectrometer includes a pulsed ion source that generates an ion beam comprising a plurality of ions. A first timed ion selector passes a first group of ions. A first ion mirror generates a reflected ion beam comprising the first group of ions that at least partially compensates for an initial kinetic energy distribution of the first group of ions. A second timed ion selector passes a second group of ions. A second ion mirror generates a reflected ion beam comprising the second group of ions that at least partially compensates for an initial kinetic energy distribution of the second group of ions. A timed ion deflector deflects the second group of ions to a detector assembly comprising at least two ion detectors which detects the deflected ion beam.
    • 质谱仪包括产生包含多个离子的离子束的脉冲离子源。 第一定时离子选择器通过第一组离子。 第一离子镜产生包含至少部分地补偿第一组离子的初始动能分布的第一组离子的反射离子束。 第二个定时离子选择器通过第二组离子。 第二离子镜产生包含至少部分地补偿第二组离子的初始动能分布的第二组离子的反射离子束。 定时离子偏转器将第二组离子偏转到包括至少两个检测偏转离子束的离子检测器的检测器组件。
    • 44. 发明申请
    • Monolayer and/or Few-Layer Graphene On Metal or Metal-Coated Substrates
    • 单层和/或金属或金属涂层基板上的少量层状石墨烯
    • US20100255984A1
    • 2010-10-07
    • US12753281
    • 2010-04-02
    • Peter Werner SutterEli Anguelova Sutter
    • Peter Werner SutterEli Anguelova Sutter
    • B01J21/18C01B31/04H01B1/04H01B1/02B01J23/46B32B5/00G02B5/10H01J3/14
    • H05H3/00B82Y30/00B82Y40/00C01B32/188C01B2204/04G02B1/105G02B1/14G02B5/10H01J3/14H01J2201/30461
    • Graphene is a single atomic layer of sp2-bonded C atoms densely packed into a two-dimensional honeycomb crystal lattice. A method of forming structurally perfect and defect-free graphene films comprising individual mono crystalline domains with in-plane lateral dimensions of up to 200 μm or more is presented. This is accomplished by controlling the temperature-dependent solubility of interstitial C of a transition metal substrate having a suitable surface structure. At elevated temperatures, C is incorporated into the bulk at higher concentrations. As the substrate is cooled, a lowering of the interstitial C solubility drives a significant amount of C atoms to the surface where graphene islands nucleate and gradually increase in size with continued cooling. Ru(0001) is selected as a model system and electron microscopy is used to observe graphene growth during cooling from elevated temperatures. With controlled cooling, large arrays of macroscopic single-crystalline graphene domains covering the entire transition metal surface are produced. As the graphene domains coalesce to a complete layer, a second graphene layer is formed, etc. By controlling the interstitial C concentration and the cooling rate, graphene layers with thickness up to 10 atomic layers or more are formed in a controlled, layer-by-layer fashion.
    • 石墨烯是密集填充到二维蜂窝晶格中的sp2键合的C原子的单原子层。 提出了一种形成结构完美和无缺陷的石墨烯薄膜的方法,其包括单面单晶畴,其面内横向尺寸高达200μm以上。 这通过控制具有合适表面结构的过渡金属基底的间隙C的温度依赖性溶解度来实现。 在升高的温度下,C以更高的浓度加入到本体中。 当衬底被冷却时,间隙C溶解度的降低将大量的C原子驱动到石墨烯岛成核的表面上并随着冷却逐渐增大。 选择Ru(0001)作为模型系统,并且使用电子显微镜观察从高温冷却期间的石墨烯生长。 通过受控冷却,产生覆盖整个过渡金属表面的宏观单晶石墨烯畴的大阵列。 当石墨烯畴结合到完整的层时,形成第二个石墨烯层等。通过控制间隙C浓度和冷却速率,在受控的层间形成厚度达10个原子层或更多层的石墨烯层 时尚流行。
    • 45. 发明申请
    • Efficient Atmospheric Pressure Interface for Mass Spectrometers and Method
    • 用于质谱仪和方法的高效大气压力界面
    • US20090283674A1
    • 2009-11-19
    • US11833209
    • 2007-08-02
    • Reinhold Pesch
    • Reinhold Pesch
    • H01J49/04
    • H01J49/062H01J3/14
    • An interface for atmospheric pressure ionization sources has an ion transfer tube with a plurality of passageways through a sidewall such that background gas can be pumped away before it reaches an exit end of the ion transfer tube. A flow of the background gas out the exit end is reduced, and a proportion of laminar flow in the ion transfer tube may be increased. Pressure in the ion transfer tube is also reduced and desolvation is increased. In one embodiment, an enclosure surrounds an inner tube of the ion transfer tube within a first vacuum chamber such that the enclosure provides a reduced pressure region within the first vacuum chamber. Overall, transport efficiency is increased.
    • 用于大气压电离源的界面具有离子传输管,其具有通过侧壁的多个通道,使得背景气体可以在其到达离子传输管的出口端之前被泵送。 离开出口端的背景气体的流量减少,离子传输管中的层流的比例可能增加。 离子转移管中的压力也降低,并且去溶剂化增加。 在一个实施例中,外壳围绕第一真空室内的离子传输管的内管,使得外壳在第一真空室内提供减压区域。 总体而言,运输效率提高。