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    • 42. 发明授权
    • Coating and dressing agents for leather and leather substitutes based on
polyurethane urea coating compounds
    • 基于聚氨酯脲涂料的皮革和皮革替代品的涂层和改性剂
    • US4401801A
    • 1983-08-30
    • US408371
    • 1982-08-16
    • Josef PedainWilhelm ThomaJurgen GrammelWalter Schroer
    • Josef PedainWilhelm ThomaJurgen GrammelWalter Schroer
    • C08G18/12C08G18/40C08G18/42C08G18/75C14C11/00D06N3/14C08G18/65
    • D06N3/14C08G18/12C08G18/4018C08G18/4202C08G18/75C14C11/006
    • This invention relates to coating agents and dressing agents for leather and leather substitutes with improved resistance to plasticizer migration, greater hardness and folding strength, a dry hand and resistance to aqueous alcoholic solutions, based on linear or only slightly branched thermoplastic polyurethane ureas built up from the following components(A) at least two macrodiols in a molar ratio of from about 1:6 to 6:1, one of which macrodiols(1) has an average molecular weight of from about 254 to 650 and contains at least one benzene, cyclohexane or cyclohexene ring, while(2) the second macrodiol has an average molecular weight in the range of from about 1200 to 3000 but has at least three times the molecular weight of A/l, and which contain(B) from about 0.5 to 11 mol of chain lengthening agent per mol of macrodiol mixture, at least about 50 mol % of the chain lengthening agents used being aliphatic and/or cycloaliphatic diamines and/or hydrazine,and in which(C) the diisocyanates used are cycloaliphatic diisocyanates, up to about 50 mol % of which may be replaced by aliphatic and/or aromatic diisocyanates.
    • 本发明涉及用于皮革和皮革代用品的涂料和改性剂,其具有改善的耐增塑剂迁移性,更高的硬度和折叠强度,干手和耐醇水溶液,基于线性或仅轻微分支的热塑性聚氨酯脲,其由 以下组分(A)至少两种摩尔比为约1:6至6:1的大分子二醇,其中一个大分子二醇(1)的平均分子量为约254至650,并含有至少一个苯, 环己烷或环己烯环,而(2)第二大二茂醇的平均分子量为约1200-3000,但具有至少三倍于A / l的分子量,并且含有(B)约0.5至 每摩尔大分子二醇混合物使用11摩尔的链延长剂,至少约50摩尔%的使用的链增长剂是脂族和/或脂环族二胺和/或肼,其中(C)二异氰酸酯 使用的氰酸酯是脂环族二异氰酸酯,其中最多约50mol%可以被脂族和/或芳族二异氰酸酯代替。