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    • 48. 发明申请
    • Aqueous paint composition of baking-drying type
    • 烘干型水性漆组合物
    • US20040220314A1
    • 2004-11-04
    • US10483260
    • 2004-03-23
    • Haruhisa SuzukiToshimichi HirakiAkira NonoyamaYutaka OhashiHidenori Nagaoka
    • C08K003/26C08K003/34
    • C09D125/10C08K3/013C08K3/26C08L23/0853C08L25/14C08L53/02C08L2205/02C09D5/022C09D7/61C09D7/69C09D123/0853C09D131/04C09D133/08C09D135/06C08L2666/24C08L2666/06C08L9/06
    • To propose a baking-drying water damping paint composition from which heavy film-thickness damping paint films can be obtained, heavy film-thickness damping paint films in which an inorganic filler is filled into the resinous component of paints to higher extent, and which are free from the occurrence of cracks and swelling in the paint films when the paint films are baked and dried. The composition comprises a water emulsion including at least one first granular resin selected from the group consisting of styrene-butadiene copolymers, acrylic ester copolymers and ethylene-vinyl acetate copolymers whose glass transition temperature is from 0 to 20null C. and gel ratio is from 60 to 80%, and an inorganic filler in an amount of 200 parts by weight or more with respect to 100 parts by weight of said first granular resin. By using water emulsion particles whose gel ratio is controlled in the specific range, it is possible to obtain cured paint films which are free from the occurrence of cracks and swelling in the paint films and which exhibit a high damping effect stably even when the inorganic filler is filled to higher extent and the paint films are further dried at ordinary baking temperatures.
    • 为了提出一种可以获得重膜厚度阻尼漆膜的烘干干燥水阻尼漆组合物,其中将无机填料更多地填充到涂料的树脂组分中的重膜厚度阻尼漆膜, 当漆膜烘烤和干燥时,在漆膜中没有发生裂纹和膨胀。 该组合物包括水乳液,其包含至少一种选自苯乙烯 - 丁二烯共聚物,丙烯酸酯共聚物和乙烯 - 乙酸乙烯酯共聚物的第一颗粒树脂,其玻璃化转变温度为0至20℃,并且凝胶比为 60〜80%,相对于100重量份的所述第一粒状树脂为200重量份以上的无机填料。 通过使用凝胶比控制在特定范围内的水乳液颗粒,可以获得在涂膜中不发生裂纹和膨胀的固化漆膜,即使当无机填料 被填充到较高程度,并且漆膜在普通烘烤温度下进一步干燥。
    • 50. 发明授权
    • Low formaldehyde, high gel fraction latex binder
    • 低甲醛,高凝胶分数乳胶粘合剂
    • US5494963A
    • 1996-02-27
    • US368526
    • 1995-01-04
    • Peter C. Hayes
    • Peter C. Hayes
    • C08L9/08C08F212/14C08F236/04C08F236/10C08L21/02C08L25/10C09D125/10C09J125/10D04H1/64D06M15/227D06M15/233D06M15/263D06M15/285D06M15/693D21H19/20D21H19/24D21H19/58C08L33/00
    • C08F212/14C08F236/10C08L25/10C09D125/10C09J125/10D04H1/587D04H1/64D06M15/227D06M15/233D06M15/263D06M15/285D06M15/693D21H19/58Y10T428/31895Y10T428/31982
    • A low formaldehyde high gel fraction latex binder is made utilizing a compound having the formula ##STR1## wherein R and R', independently, is an alkyl having from 1 to 10 carbon atoms, and R.sup.4 is hydrogen, or wherein R.sup.3 and R.sup.4, independently is an alkyl, an aromatic, or combinations thereof having from 1 to 10 carbon atoms, or wherein said R.sup.3 and R.sup.4 are connected to form an internal amide, and wherein the isopropenyl group is either in the ortho, meta or para position. The latex binder is generally an emulsion or latex copolymer made from various monomers including at least one or more conjugated dienes having a total of from 4 to 10 carbon atoms with butadiene being preferred and from one or more vinyl-substituted aromatics having from 8 to 14 carbon atoms, with styrene being preferred. The amount of the above formulation compounds is generally from about 0.25 to about 20 parts by weight based upon 100 parts by weight of the one or more conjugated dienes and the vinyl-substituted aromatic monomers. The latex binder has good stability, and has many applications such as to bind a paper-coating composition to a cellulose substrate, or to bind non-woven fibers together. The latex binder generally contains 10 parts or less by weight of formaldehyde per million parts by weight and desirably contains nil, that is, no detectable amounts of formaldehyde therein, even after extended periods of time, e.g., 28 days.
    • 使用具有下式的化合物制备低甲醛高凝胶分数乳胶粘合剂:其中R和R'独立地是具有1至10个碳原子的烷基,R 4是氢,或其中R 3 和R 4独立地是具有1至10个碳原子的烷基,芳族或其组合,或其中所述R 3和R 4连接形成内酰胺,并且其中所述异丙烯基在邻位,间位或对位 位置。 胶乳粘合剂通常是由各种单体制成的乳液或胶乳共聚物,包括至少一种或多种总共4至10个碳原子的共轭二烯,其中丁二烯是优选的,并且一种或多种乙烯基取代的芳族化合物具有8至14个 碳原子,苯乙烯是优选的。 基于100重量份的一种或多种共轭二烯和乙烯基取代的芳族单体,上述制剂化合物的量通常为约0.25至约20重量份。 胶乳粘合剂具有良好的稳定性,并且具有许多应用,例如将纸涂层组合物结合到纤维素基材上,或将非织造纤维粘合在一起。 胶乳粘合剂通常每百万重量份含有10重量份或更少的甲醛,并且理想地包含零,也就是说,即使在长时间(例如28天)之后也不含可检测量的甲醛。