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41. 发明授权

US07776614B2 Test method for determining compounds capable of quenching electronic singlet state excitation of photoactive compounds 失效
标题翻译：用于测定能够淬灭光活性化合物的电子单线态激发的化合物的测试方法
公开(公告)号：US07776614B2
公开(公告)日：2010-08-17
申请号：US11891280
申请日：2007-08-09
申请人： Craig A. Bonda
发明人： Craig A. Bonda
IPC分类号： G01N21/76
CPC分类号： G01N21/6428 , G01N2021/6432 , Y10T436/2525
摘要： A method of testing a compound for its capability of quenching singlet excited state energy from a photon-excited photoactive compound, thereby photostabilizing said photoactive compound, comprising mixing: (1) a composition comprising a photoactive compound in a solvent and determining the degree of fluorescence of said composition (1) by exposing the composition (1) to UV radiation in an amount sufficient for the photoactive compound to reach an electronic singlet excited state, and (2) a mixture comprising said photoactive compound with a test compound in a solvent, and determining the degree of fluorescence of said mixture (2) by exposing the mixture to UV radiation to the same degree as composition (1), and comparing the degree of fluorescence of composition (1) with mixture (2).
摘要翻译：一种测试化合物其能够从光子激发的光活性化合物淬灭单重激发态能的能力的方法，由此使所述光活性化合物光稳定化，包括混合：（1）在溶剂中包含光活性化合物的组合物并测定荧光的程度通过将组合物（1）暴露于足以使光活性化合物达到电子单重激发态的量的UV辐射，和（2）包含所述光活性化合物与测试化合物在溶剂中的混合物，所述组合物（1）以及通过将混合物暴露于UV辐射至与组合物（1）相同的程度，并将组合物（1）的荧光与混合物（2）的比较来确定所述混合物（2）的荧光程度。

42. 发明授权

US07754191B2 Method of quenching electronic excitation of chromophore-containing organic molecules photoactive compositions 有权
标题翻译：淬灭含有发色团的有机分子光活性组合物的电子激发方法
公开(公告)号：US07754191B2
公开(公告)日：2010-07-13
申请号：US12290732
申请日：2008-11-03
申请人： Craig A. Bonda , Anna Pavlovic
发明人： Craig A. Bonda , Anna Pavlovic
IPC分类号： A61K8/18
CPC分类号： A61Q17/04 , A61K8/40 , C07C255/41 , C08G63/6856 , C08K5/315 , C08L67/02 , C08L67/04 , C08L101/00 , C08L2666/18
摘要： A method of quenching fluorescence of a naphthalate polyester that is subjected to UV-radiation in an amount sufficient to cause the naphthalate polyester to reach an excited state and fluoresce, comprising adding to the naphthalate polyester a fluorescence quenching amount of a compound of formula (1): wherein R1 is an alkoxy; R2 is an organic linker; k is either zero or one; l is either zero or one, wherein the sum of k+l is one; and m is an integer in a range from zero to about twenty.
摘要翻译：一种使足够使得萘二甲酸酯聚酯达到激发状态并发荧光的紫外线照射的萘二甲酸酯聚酯的荧光淬灭的方法，包括向萘二甲酸酯聚酯中加入荧光猝灭量的式（1 ）：其中R1是烷氧基; R2是有机接头; k是零或一; l是0或1，其中k + 1的和是1; m为0〜约20的整数。

43. 发明申请

US20090208435A1 METHOD OF QUENCHING ELECTRONIC EXCITATION OF CHROMOPHORE-CONTAINING ORGANIC MOLECULES IN PHOTOACTIVE COMPOSITIONS 审中-公开
公开(公告)号：US20090208435A1
公开(公告)日：2009-08-20
申请号：US12432581
申请日：2009-04-29
申请人： CRAIG A. BONDA , Anna Pavlovic
发明人： CRAIG A. BONDA , Anna Pavlovic
IPC分类号： A61K8/40 , A61Q17/04
CPC分类号： A61K8/40 , A61K2800/52 , A61Q17/04
摘要： The photostabilizing electronic excited state energy—particularly singlet state energy from a UV-absorbing molecule has been found to be readily transferred to (accepted by) α-cyanodiphenylacrylate compounds of formulas (I) and (V) having an alkoxy radical preferably in the four (para) position (hereinafter methoxycrylenes) on one or both of the phenyl rings: wherein at least one of R1 and R2 is a straight or branched chain C1-C12 alkoxy radical, preferably C1-C8, more preferably C1-C4, and most preferably methoxy, and any non-alkoxy radical R1 or R2 is hydrogen; and R3 is a straight or branched chain C1-C24 alkyl radical, preferably C12-C24, more preferably C20; wherein A and B are the same or different and are selected from the group consisting of oxygen, amino and sulfur; R1 and R3 are the same or different and are selected from the group consisting of C1-C30 alkyl, C2-C30 alkylene, C2-C30 alkyne, C3-C8 cycloalkyl, C1-C30 substituted alkylene, C2-C30 substituted alkyne, aryl, substituted aryl, heteroaryl, heterocycloalkyl, substituted heteroaryl and substituted heterocycloalkyl; R2 is selected from the group consisting of C1-C30 alkyl, C2-C30 alkylene, C2C30 alkyne, C3-C8 cycloalkyl, C1-C30 substituted alkyl, C3-C8 substituted cycloalkyl, C1-C30 substituted alkylene, C2-C30 substituted alkyne; R4, R5, R6 and R7 are the same or different and are selected from the group consisting of C1-C30 alkoxy straight chin on branched and a, b, c and d are each either 0 or 1, and a, b, c and d add up to 1, 2, 3, or 4.

44. 发明申请

US20090057627A1 Method of quenching electronic excitation of chromophore-containing organic molecules photoactive compositions 有权
标题翻译：淬灭含有发色团的有机分子光活性组合物的电子激发方法
公开(公告)号：US20090057627A1
公开(公告)日：2009-03-05
申请号：US12290732
申请日：2008-11-03
申请人： Craig A. Bonda , Anna Pavlovic
发明人： Craig A. Bonda , Anna Pavlovic
IPC分类号： C09K11/06 , C09K21/14 , H01B1/12
CPC分类号： A61Q17/04 , A61K8/40 , C07C255/41 , C08G63/6856 , C08K5/315 , C08L67/02 , C08L67/04 , C08L101/00 , C08L2666/18
摘要： A method of quenching fluorescence of a naphthalate polyester that is subjected to UV-radiation in an amount sufficient to cause the naphthalate polyester to reach an excited state and fluoresce, comprising adding to the naphthalate polyester a fluorescence quenching amount of a compound of formula (1): wherein R1 is an alkoxy; R2 is an organic linker; k is either zero or one; l is either zero or one, wherein the sum of k+l is one; and m is an integer in a range from zero to about twenty.
摘要翻译：一种使足够使得萘二甲酸酯聚酯达到激发状态并发荧光的紫外线照射的萘二甲酸酯聚酯的荧光淬灭的方法，包括向萘二甲酸酯聚酯中加入荧光猝灭量的式（1 ）：其中R1是烷氧基; R2是有机接头; k是零或一; l是0或1，其中k + 1的和是1; m为0〜约20的整数。

45. 发明授权

US09443624B2 Aryl substituted propenoic amides and esters 有权
标题翻译：芳基取代的丙烯酰胺和酯
公开(公告)号：US09443624B2
公开(公告)日：2016-09-13
申请号：US14452356
申请日：2014-08-05
申请人： HALLSTAR INNOVATIONS CORP.
发明人： Craig Bonda , Shengkui Hu , Gary A. Neudahl , Stephen O'Rourke , Stephen J. Semlow , Zhihui Zhang
IPC分类号： G21F1/10 , C07C327/12 , C07C255/41 , A61Q17/04 , A61K31/277 , A61K8/46 , A61K8/42
CPC分类号： G21F1/10 , A61K8/42 , A61K8/46 , A61K31/277 , A61Q17/04 , C07C255/41 , C07C327/12
摘要： The present disclosure relates, according to some embodiments, to molecules, including substituted propenoic amides (e.g., aryl substituted propenoic amides), that may receive excited state energy from light-absorbing molecules. According to some embodiments, the present disclosure relates to molecules, including substituted propenoic amides (e.g., aryl substituted propenoic amides), that may quench, dissipate, and/or otherwise resolve excited state energy (e.g., as heat).
摘要翻译：根据一些实施方案，本公开内容涉及可以从光吸收分子接收激发态能的分子，包括取代的丙烯酰胺（例如芳基取代的丙烯酰胺）。根据一些实施方案，本公开涉及分子，包括取代的丙烯酰胺（例如芳基取代的丙烯酰胺），其可以淬灭，消散和/或以其他方式分解激发态能量（例如，作为热）。

46. 发明申请

US20140050681A1 METHOD OF PHOTOSTABILIZING UV ABSORBERS, PARTICULARLY DIBENZYOLMETHANE DERIVATIVES, E.G., AVOBENZONE, WITH CYANO-CONTAINING FUSED TRICYCLIC COMPOUNDS 有权
标题翻译：紫外线吸收剂，特别是二苯基甲基衍生物，E.G.，AVOBENZONE，含有氰基含量的三元共轭化合物的光致稳定化方法
公开(公告)号：US20140050681A1
公开(公告)日：2014-02-20
申请号：US13588662
申请日：2012-08-17
申请人： Craig A. Bonda , Shengkui Hu
发明人： Craig A. Bonda , Shengkui Hu
IPC分类号： A61K8/37 , A61Q17/04 , A61K8/36
CPC分类号： A61K8/40 , A61K8/498 , A61K8/4986 , A61Q17/04
摘要： A photostabilized photoactive composition comprising a mixture of a photoactive compound that develops a singlet excited state, or fluoresces when subjected to UV radiation and an effective amount of an excited state quencher comprising a cyano-containing fused tricyclic compound of formula (I): wherein: A is selected from the group consisting of O, S, C═O, and n is selected from the group consisting of 0 and 1; and, R1 and R2 are each independently selected from the group consisting of alkyl, cycloalkyl, ether, aryl, and amino.
摘要翻译：包含形成单重激发态的光活性化合物的混合物或经受紫外线辐射时发荧光的有光稳定的光活性组合物和有效量的包含式（I）的含氰基稠合三环化合物的激发态猝灭剂：其中： A选自O，S，C = O，n选自0和1; 并且R 1和R 2各自独立地选自烷基，环烷基，醚，芳基和氨基。

47. 发明授权

US08263051B2 Photostabilization of resveratrol with alkoxycrylene compounds 有权
标题翻译：白藜芦醇与烷氧基亚芳基化合物的稳定化
公开(公告)号：US08263051B2
公开(公告)日：2012-09-11
申请号：US13080247
申请日：2011-04-05
申请人： Craig A. Bonda , Anna Pavlovic , Jean Zhang
发明人： Craig A. Bonda , Anna Pavlovic , Jean Zhang
IPC分类号： A61K8/00 , A61K8/18 , A61Q17/04 , F21V9/04 , F21V9/06 , G02B5/22 , G02B5/26 , A61K38/43
CPC分类号： A61K47/14 , A61K8/361 , A61K8/368 , A61K8/37 , A61K8/40 , A61K8/49 , A61K8/671 , A61K9/0014 , A61K31/05 , A61K2800/52 , A61Q17/04 , A61Q19/00 , A61Q19/08
摘要： The photostabilizing electronic excited state energy—particularly singlet state energy from resveratrol compounds—has been found to be readily transferred to (accepted by) α-cyanodiphenylacrylate compounds having an alkoxy radical in the four (para) position (hereinafter “alkoxycrylenes”) on one of the phenyl rings having the formula (I): wherein one of R1 and R2 is a straight or branched chain C1-C30 alkoxy radical, preferably C1-C8, more preferably methoxy, and the non-alkoxy radical R1 or R2 is hydrogen; and R3 is a straight or branched chain C1-C30 alkyl radical, preferably C2-C20. The alkoxycrylene compounds of formula (I) significantly increase the photostability of resveratrol compounds in a composition by at least 3-fold and as much as 10-fold or greater. The ability of the alkoxycrylene compounds to stabilize the resveratrol compound is concentration dependent, with the amount of resveratrol photostabilization increasing with the concentration of the alkoxycrylene compound.
摘要翻译：已经发现光稳定化电子激发态能量 - 特别是白藜芦醇化合物的单态能量 - 已经被发现容易地转移到（接受）在四（对）位置具有烷氧基的α-氰基二苯基丙烯酸酯化合物（以下称为“烷氧基烯”）的具有式（I）的苯环：其中R 1和R 2中的一个是直链或支链C 1 -C 30烷氧基，优选C 1 -C 8，更优选甲氧基，并且非烷氧基R 1或R 2是氢; 并且R 3是直链或支链C 1 -C 30烷基，优选C 2 -C 20。式（I）的烷氧基亚
烷基化合物显着提高组合物中白藜芦醇化合物的光稳定性至少3倍和10倍或更高。烷氧基化合物稳定白藜芦醇化合物的能力是浓度依赖性的，白藜芦醇光稳定化的量随着烷氧基化合物的浓度而增加。

48. 发明授权

US08263050B2 Method of quenching electronic excitation of chromophore-containing organic molecules in photoactive compositions 有权
标题翻译：在光活性组合物中淬灭含有发色团的有机分子的电子激发的方法
公开(公告)号：US08263050B2
公开(公告)日：2012-09-11
申请号：US12432450
申请日：2009-04-29
申请人： Craig A. Bonda , Anna Pavlovic
发明人： Craig A. Bonda , Anna Pavlovic
IPC分类号： A61K8/18 , A01N43/40 , A61K31/44 , A61K38/43 , A61K8/00 , A61Q17/04
CPC分类号： A61K8/40 , A61K2800/52 , A61Q17/04
摘要： The photostabilizing electronic excited state energy—particularly singlet state energy from a UV-absorbing molecule has been found to be readily transferred to (accepted by) α-cyanodiphenylacrylate compounds of formulas (I) and (V) having an alkoxy radical preferably in the four (para) position (hereinafter methoxycrylenes) on one or both of the phenyl rings: wherein at least one of R1 and R2 is a straight or branched chain C1-C12 alkoxy radical, preferably C1-C8, more preferably C1-C4, and most preferably methoxy, and any non-alkoxy radical R1 or R2 is hydrogen; and R3 is a straight or branched chain C1-C24 alkyl radical, preferably C12-C24, more preferably C20; wherein A and B are the same or different and are selected from the group consisting of oxygen, amino and sulfur; R1 and R3 are the same or different and are selected from the group consisting of C1-C30 alkyl, C2-C30 alkylene, C2-C30 alkyne, C3-C8 cycloalkyl, C1-C30 substituted alkylene, C2-C30 substituted alkyne, aryl, substituted aryl, heteroaryl, heterocycloalkyl, substituted heteroaryl and substituted heterocycloalkyl; R2 is selected from the group consisting of C1-C30 alkyl, C2-C30 alkylene, C2-C30 alkyne, C3-C8 cycloalkyl, C1-C30 substituted alkyl, C3-C8 substituted cycloalkyl, C1-C30 substituted alkylene, C2-C30 substituted alkyne; R4, R5, R6 and R7 are the same or different and are selected from the group consisting of C1-C30 alkoxy straight chin on branched and a, b, c and d are each either 0 or 1, and a, b, c and d add up to 1, 2, 3, or 4.
摘要翻译：已经发现光稳定化电子激发态能量 - 特别是来自UV吸收分子的单态能量已被发现易于转移到具有烷氧基的式（I）和（V）的α-氰基二苯基丙烯酸酯化合物（优选在四（对位）位置（以下为甲氧基）;其中R 1和R 2中的至少一个为直链或支链C 1 -C 12烷氧基，优选C 1 -C 8，更优选C 1 -C 4，最优选优选甲氧基，任何非烷氧基R 1或R 2为氢; 并且R 3是直链或支链C 1 -C 24烷基，优选C 12 -C 24，更优选C 20; 其中A和B相同或不同，并且选自氧，氨基和硫; R 1和R 3相同或不同，选自C 1 -C 30烷基，C 2 -C 30亚烷基，C 2 -C 30炔基，C 3 -C 8环烷基，C 1 -C 30取代的亚烷基，C 2 -C 30取代的炔基，芳基，取代的芳基，杂芳基，杂环烷基，取代的杂芳基和取代的杂环烷基; R 2选自C 1 -C 30烷基，C 2 -C 30亚烷基，C 2 -C 30炔基，C 3 -C 8环烷基，C 1 -C 30取代的烷基，C 3 -C 8取代的环烷基，C 1 -C 30取代的亚烷基，C 2 -C 30取代的炔烃 R4，R5，R6和R7相同或不同，选自支链上的C1-C30烷氧基直链，a，b，c和d各自为0或1，a，b，c和 d加起来1，2，3或4。

49. 发明授权

US08158731B2 Biopolymer compositions having improved flexibility 有权
标题翻译：生物聚合物组合物具有改善的柔韧性
公开(公告)号：US08158731B2
公开(公告)日：2012-04-17
申请号：US12694426
申请日：2010-01-27
申请人： Kimberly L. Stefanisin , Urvil B. Shah , Stephen O'Rourke , Gary Wentworth
发明人： Kimberly L. Stefanisin , Urvil B. Shah , Stephen O'Rourke , Gary Wentworth
IPC分类号： C08G63/02
CPC分类号： C08L1/02 , C08L3/02 , C08L67/02 , C08L67/04 , C08L2666/18
摘要： The present disclosure is directed to polymer blends comprising a biopolymer and a substituted or unsubstituted aliphatic polyester. The aliphatic polyester comprises repeating units derivable from a substituted or unsubstituted aliphatic diacid, repeating units derivable from a substituted or unsubstituted aliphatic diol, and one or two terminator units derivable from a substituted or unsubstituted aliphatic alcohol. The polymer blends disclosed herein provide improved flexibility, and are useful, for example, in the production of packaging materials, industrial products, durable goods, and the like.
摘要翻译：本公开涉及包含生物聚合物和取代或未取代的脂族聚酯的聚合物共混物。脂肪族聚酯包含可从取代或未取代的脂肪族二酸衍生的重复单元，可衍生自取代或未取代的脂族二醇的重复单元，以及可衍生自取代或未取代的脂族醇的一个或两个终止单元。本文公开的聚合物共混物提供改进的柔性，并且可用于例如包装材料，工业产品，耐用品等的生产。

50. 发明申请

US20120065232A1 PHOTOSTABILIZATION OF RETINOIDS WITH ALKOXYCRYLENE COMPOUNDS 有权
标题翻译：用烷氧基化合物对反应物进行光化学反应
公开(公告)号：US20120065232A1
公开(公告)日：2012-03-15
申请号：US13282667
申请日：2011-10-27
申请人： Craig A. Bonda , Anna Pavlovic , Jean Zhang
发明人： Craig A. Bonda , Anna Pavlovic , Jean Zhang
IPC分类号： A61K31/07 , A61K31/11 , A61K31/216 , A61K31/192 , A61K31/4436 , A61P17/00 , A61P35/00 , A61P19/00 , A61P17/10 , A61K8/67 , A61K8/49 , A61K8/92 , A61K8/37 , A61K8/36 , A61Q19/00 , A61Q19/08 , A61K31/203
CPC分类号： A61Q19/08 , A61K8/361 , A61K8/368 , A61K8/37 , A61K8/40 , A61K8/49 , A61K8/671 , A61K2800/52 , A61Q17/04 , A61Q19/00
摘要： The photostabilizing electronic excited state energy—particularly singlet state energy from retinoid compounds—has been found to be readily transferred to (accepted by) α-cyanodiphenylacrylate compounds having an alkoxy radical in the four (para) position (hereinafter “alkoxycrylenes”) on one of the phenyl rings having the formula (I): wherein one of R1 and R2 is a straight or branched chain C1-C30 alkoxy radical, preferably C1-C8, more preferably methoxy, and the non-alkoxy radical R1 or R2 is hydrogen; and R3 is a straight or branched chain C1-C30 alkyl radical, preferably C2-C20. The alkoxycrylene compounds of formula (I) significantly increase the photostability of retinoid compounds in a composition by at least 3-fold.
摘要翻译：已经发现光稳定化电子激发态能量 - 特别是来自类视黄醇化合物的单态态能够容易地转移到（接受）在四（对）位置具有烷氧基的α-氰基二苯基丙烯酸酯化合物（以下称为“烷氧基烯”）的具有式（I）的苯环：其中R 1和R 2中的一个是直链或支链C 1 -C 30烷氧基，优选C 1 -C 8，更优选甲氧基，并且非烷氧基R 1或R 2是氢; 并且R 3是直链或支链C 1 -C 30烷基，优选C 2 -C 20。式（I）的烷氧基亚烷基化合物显着地将组合物中类视黄醇化合物的光稳定性提高至少3倍。

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