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    • 43. 发明授权
    • Process for preparing resin binder for toner
    • 调色剂树脂粘合剂的制备方法
    • US07385002B2
    • 2008-06-10
    • US11139556
    • 2005-05-31
    • Eiji ShiraiTetsuya Ueno
    • Eiji ShiraiTetsuya Ueno
    • C08G63/20C08F212/08G03G9/00
    • G03G9/08755G03G9/0806G03G9/0808G03G9/08708G03G9/08711G03G9/08733Y10S430/108Y10S430/109
    • The present invention relates to a process for preparing a resin binder for toner, comprising the steps of (A) carrying out an addition polymerization reaction of addition polymerization resin monomers including styrene in the presence or absence of an organic solvent; and (B) mixing the resulting reaction mixture from the step (A) with water at a rate of 0.002 to 0.5 parts by weight based on 100 parts by weight of the addition polymerization resin monomers per minute at a temperature of 100° to 300° C. during and/or after the step (A), wherein the amount of water to be mixed in the step (B) is 0.1 to 50 parts by weight based on 100 parts by weight of the addition polymerization resin monomers. The resin binder for a toner obtained according to the present invention can be used, for instance, for developing electrostatic latent images formed in electrophotography, electrostatic recording method, electrostatic printing method, and the like, and a toner containing the resin binder.
    • 本发明涉及一种制备调色剂用树脂粘合剂的方法,包括以下步骤:(A)在存在或不存在有机溶剂的情况下进行包括苯乙烯的加成聚合树脂单体的加成聚合反应; 和(B)相对于100重量份的加成聚合树脂单体,在100〜300℃的温度下,以0.002〜0.5重量份的比例,将得自步骤(A)的反应混合物与水混合 在步骤(A)期间和/或之后,其中步骤(B)中待混合的水的量相对于100重量份的加成聚合树脂单体为0.1〜50重量份。 用于根据本发明获得的调色剂用树脂粘合剂可以用于例如用于显影在电子照相术,静电记录方法,静电印刷方法等中形成的静电潜像,以及含有树脂粘合剂的调色剂。
    • 44. 发明申请
    • Method For Producing Toner
    • 生产碳粉的方法
    • US20070207401A1
    • 2007-09-06
    • US11578292
    • 2005-04-20
    • Eiji Shirai
    • Eiji Shirai
    • G03G9/087
    • G03G9/0821G03G9/081G03G9/08755
    • The present invention relates to a process for producing a toner including the steps of melt-kneading raw materials containing two or more kinds of polyesters, heat-treating a melt-kneaded product, pulverizing a heat-treated product, and classifying a pulverized product, wherein the two or more kinds of polyesters contain at least one kind of an amorphous polyester, and the heat-treating step is carried out at a temperature t (° C.) and time h (hour) satisfying the following formulas (a) and (b), Tg1≦t≦Tm−10  (a) h≧100/(t−30), with proviso that t>30  (b) wherein Tg1 is a glass transition temperature (° C.) of the melt-kneaded product before the heat-treating step; and Tm is the lowest softening point (° C.) of softening points of the two or more kinds of polyesters, and the toner produced by the process. The toner obtained according to the present invention is suitably used, for example, for developing latent images formed in electrophotography, electrostatic recording method, electrostatic printing method, or the like.
    • 本发明涉及一种调色剂的制造方法,该方法包括以下步骤:将含有两种或多种聚酯的原料熔融捏合,热熔融捏合产物,粉碎热处理产物,分级粉碎产物, 其中所述两种或更多种聚酯含有至少一种无定形聚酯,并且所述热处理步骤在满足下列通式(a)和(b)的温度t(℃)和时间h(小时) (b)中,<?in-line-formula description =“In-line Formulas”end =“lead”?> Tg <1 <= T <= TM-10(a) line-formula description =“In-line Formulas”end =“tail”?> <?in-line-formula description =“In-line Formulas”end =“lead”?> h> = 100 /(t-30) ,条件是t> 30(b)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中Tg <1>是玻璃化转变温度(℃ )在热处理步骤之前的熔融捏合产物; 并且Tm是两种或多种聚酯的软化点的最低软化点(℃)和由该方法产生的调色剂。 根据本发明获得的调色剂适合用于例如用于在电子照相术,静电记录方法,静电印刷方法等中形成的显影潜像。
    • 45. 发明授权
    • Crystalline polyester
    • 结晶聚酯
    • US07208563B2
    • 2007-04-24
    • US10758416
    • 2004-01-16
    • Eiji Shirai
    • Eiji Shirai
    • C08G63/16G03G9/13
    • G03G9/08797C08G63/52G03G9/08755G03G9/08795
    • A crystalline polyester prepared by polycondensing an alcohol component comprising 1,6-hexanediol in an amount of 60% by mol or more, with a carboxylic acid component comprising fumaric acid in an amount of 60% by mol or more, wherein the crystalline polyester has a ratio of a softening point to the maximum peak temperature of heat of fusion is from 0.6 to 1.3, and wherein a tetrahydrofuran-soluble component of the crystalline polyester has a number-average molecular weight of from 1500 to 10000, and the crystalline polyester has a softening point of from 50° to 120° C.; a resin binder for a toner comprising the crystalline polyester; and a toner comprising the resin binder. The crystalline polyester can be used as a resin binder for a toner used, for example, for developing electrostatic latent images formed in electrophotography, electrostatic recording method, electrostatic printing method, and the like.
    • 将含有60摩尔%以上的1,6-己二醇的醇成分与含有60摩尔%以上的富马酸的羧酸成分缩聚而成的结晶性聚酯,其中,结晶性聚酯具有 软化点与熔融热的最大峰值温度的比例为0.6〜1.3,其中结晶性聚酯的四氢呋喃可溶成分的数均分子量为1500〜10000,结晶性聚酯具有 软化点为50〜120℃。 用于包含结晶聚酯的调色剂的树脂粘合剂; 和包含树脂粘合剂的调色剂。 结晶性聚酯可以用作用于调色剂的树脂粘合剂,例如用于显影在电子照相术中形成的静电潜像,静电记录方法,静电印刷方法等。
    • 46. 发明授权
    • Polyester resin composition for toner
    • 调色剂用聚酯树脂组合物
    • US07205357B2
    • 2007-04-17
    • US10693881
    • 2003-10-28
    • Takashi KuboKatsutoshi AokiEiji Shirai
    • Takashi KuboKatsutoshi AokiEiji Shirai
    • C08K3/32C08G9/087G03G63/16
    • C08G63/195C08G63/85G03G9/08755G03G9/09708
    • A polyester resin composition for a toner comprising a titanium compound in an amount of from 0.005 to 4% by weight, and an inorganic phosphorus compound in an amount of from 0.001 to 5% by weight; a toner comprising the polyester resin composition as defined above; and a process for preparing the polyester resin composition for a toner as defined above, comprising the step of polycondensing the raw material monomers for the polyester in the presence of a titanium compound and an inorganic phosphorus compound. The polyester resin composition for a toner is suitably used as a resin binder for a toner for developing a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method or the like, a process for preparing the same, and a toner comprising the polyester resin composition.
    • 一种用于调色剂的聚酯树脂组合物,其包含0.005至4重量%的钛化合物和0.001至5重量%的无机磷化合物; 包含如上所述的聚酯树脂组合物的调色剂; 以及制备如上所述的调色剂用聚酯树脂组合物的方法,包括在钛化合物和无机磷化合物的存在下将聚酯原料单体缩聚的步骤。 用于调色剂的聚酯树脂组合物适合用作用于显影在电子照相术,静电记录方法,静电印刷方法等中形成的潜像的调色剂的树脂粘合剂,其制备方法和包含聚酯的调色剂 树脂组合物。
    • 48. 发明授权
    • Crystalline polyester
    • 结晶聚酯
    • US06998212B2
    • 2006-02-14
    • US10621387
    • 2003-07-18
    • Eiji ShiraiKatsutoshi Aoki
    • Eiji ShiraiKatsutoshi Aoki
    • G03G9/087
    • C08G63/16G03G9/08755
    • A crystalline polyester having a number-average molecular weight of from 5000 to 10000, a weight-average molecular weight of from 150000 to 8000000, a maximum peak temperature of heat of fusion of from 60° to 150° C., and a ratio of a softening point to a maximum peak temperature of heat of fusion (softening point/peak temperature) of from 0.6 to 1.3. The crystalline polyester can be used as a resin binder for a toner used for developing electrostatic latent images formed in electrophotography, electrostatic recording method, electrostatic printing method, and the like.
    • 数均分子量为5000〜10000,重均分子量为150000〜8000000,熔融热最大峰值温度为60〜150℃的结晶性聚酯, 熔化热的最大峰值温度(软化点/峰值温度)的软化点为0.6〜1.3。 结晶性聚酯可以用作用于显影在电子照相术,静电记录方法,静电印刷法等中形成的静电潜像的调色剂的树脂粘合剂。