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    • 43. 发明授权
    • Agents for the stimulation and cultivation of plant growth and process
for producing said agents
    • 用于刺激和培养植物生长的试剂和用于生产所述试剂的方法
    • US5554577A
    • 1996-09-10
    • US307595
    • 1994-10-13
    • Wolfgang KempfPeter SchroederWolfgang RitterBernd Ebbe
    • Wolfgang KempfPeter SchroederWolfgang RitterBernd Ebbe
    • B01J2/28C05G3/00C05G5/00A01N25/10
    • C05G3/0052B01J2/28C05G3/0058
    • The subject matter comprises shaped mixtures of valuable materials for the stimulation and cultivation of plant growth, said materials containing plant nutrients and/or plant-protective agents in admixture with a thermoplastic binder. According to the invention the mixtures of valuable materials, which mixtures have in particular been shaped as fertilizer rods, are characterized in that they contain, as the binder, a starch that has been thermomechanically digested at elevated pressures and temperatures.The invention further relates to the process for producing these multi-component mixtures and to the use of thermomechanically digested starch, optionally in admixture with inferior amounts of further biologically compatible binder components, as a biologically degradable binder for mixtures of valuable materials of the type described.
    • PCT No.PCT / EP93 / 00646 Sec。 371日期:1994年10月13日 102(e)日期1994年10月13日PCT 1993年3月18日PCT公布。 第WO93 / 19023号公报 日期1993年9月30日主题包括用于刺激和培养植物生长的有价值材料的成型混合物,所述材料含有与热塑性粘合剂混合的植物营养物和/或植物保护剂。 根据本发明,这些混合物特别是形成肥料棒的有价值材料的混合物的特征在于,它们含有在升高的压力和温度下热机械消化的淀粉作为粘合剂。 本发明还涉及生产这些多组分混合物的方法,以及使用热机械消化的淀粉,任选地与较少量的其它生物相容性粘合剂组分混合,作为生物可降解粘合剂,用于所述类型的有价值材料的混合物 。
    • 44. 发明授权
    • Retard systems for the sustained release of medicinal and/or biological
valuable materials from a depot carrier material
    • 阻止用于从贮库载体材料持续释放药物和/或生物有价物质的系统
    • US5538738A
    • 1996-07-23
    • US133205
    • 1993-10-18
    • Wolfgang RitterRudolf LehmannRainer Sorg
    • Wolfgang RitterRudolf LehmannRainer Sorg
    • A61K9/00A61K20060101A61K9/20A61K9/22A61K47/30A61K47/32A61K47/34A61L26/00A61K9/10A61K9/14
    • A61K9/2027A61K9/204A61L26/0066A61L2300/406A61L2300/602Y10S424/13Y10T428/31786
    • The invention relates to the use of free radical-reactive cross-linker components based on olefinically unsaturated esters of lower hydroxycarboxylic acids and/or oligomers thereof for modifying depot materials, and especially retard systems, which contain medicinal and/or biological valuable materials in admixture with a carrier material in a sustained release form. The cross-linkers are present as polymer compounds in the application form of the retard system and may be provided in the retard system or depot material to be applied in a largely homogeneous as well as in a non-uniform distribution. The invention also relates to retard systems which contain medicinal and/or biological valuable materials and have been based on oligomer and/or polymer compounds of lower hydroxycarboxylic acids as carrier materials providing a sustained release of the active substance. The retard systems and/or depot materials are modified with polymer compounds prepared from olefinically unsaturated esters of lower hydroxycarboxylic acids and/or oligomers thereof.
    • PCT No.PCT / EP92 / 00825 Sec。 371日期:1993年10月18日 102(e)日期1993年10月18日PCT提交1992年4月11日PCT公布。 WO92 / 18108 PCT出版物 日期:1992年10月29日本发明涉及使用基于低级羟基羧酸和/或其低聚物的烯属不饱和酯的自由基 - 反应性交联剂组分来改性储存材料,特别是延迟体系,其包含药物和/或 生物有价值的材料与持续释放形式的载体材料混合。 交联剂以延迟体系的应用形式作为聚合物化合物存在,并且可以在延迟体系或储库材料中提供以在很大程度上均匀和非均匀分布中施用。 本发明还涉及包含药物和/或生物有价值物质并且基于低级羟基羧酸的低聚物和/或聚合物化合物作为提供活性物质的持续释放的载体材料的延迟系统。 延迟系统和/或贮库材料用由低级羟基羧酸和/或其低聚物的烯属不饱和酯制备的聚合物改性。
    • 45. 发明授权
    • Dry neutralization of olefinically reactive organic liquid phases
    • 烯烃反应有机液相的干中和
    • US5522971A
    • 1996-06-04
    • US244680
    • 1994-06-07
    • Wolfgang RitterStefanie Ortanderl
    • Wolfgang RitterStefanie Ortanderl
    • C07C67/62C07B63/02C07C67/48C07C69/54B01D3/34B01D3/38
    • C07C67/48C07B63/02
    • Pure, substantially neutral, low-volatile organic compounds including reactive double bonds are advantageously isolated from a liquid feedstock which contains said compounds in combination with acidic reaction components or auxiliary materials by (i) adding to the feedstock, as neutralizing agents, finely powdered oxides, carbonates and/or hydroxides of the alkali metals and/or alkaline earth metals; (ii) adding, at the same time as the addition of the neutralizing agents or thereafter, a limited amount of water to the mixture of feedstock and neutralizing agents; (iii) mechanically mixing the liquid and solid mixture thus formed for at least a few minutes; (iv) distilling off water from the hot reaction mixture under reduced pressure; and (v) removal from the liquid product of the solid phase now present. Pure products which even without distillation exhibit low residual acid values in combination with low color values result. In a particular embodiment, a process according to the invention is used for an exchange of inhibitors in a mixture reactive when initiated by free radicals; in this exchange, a preparation inhibitor capable of undergoing a salt formation with bases is exchanged for an application inhibitor that may be freely selected with respect to kind and amounts thereof.
    • PCT No.PCT / EP92 / 02785 Sec。 371日期:1994年6月7日 102(e)日期1994年6月7日PCT提交1992年12月2日PCT公布。 公开号WO93 / 12066 日本6月24日,纯净的,基本上中性的,包含反应性双键的低挥发性有机化合物有利地从含有所述化合物与酸性反应组分或辅助材料的液体原料分离,通过(i)向原料, 作为中和剂,碱金属和/或碱土金属的细粉末状氧化物,碳酸盐和/或氢氧化物; (ii)在添加中和剂或此后加入有限量的水至原料和中和剂的混合物; (iii)将如此形成的液体和固体混合物机械混合至少几分钟; (iv)在减压下从热反应混合物中蒸出水; 和(v)从现在存在的固相的液体产物中除去。 即使没有蒸馏的纯产品也会产生低残留酸值和低颜色值。 在一个具体实施方案中,根据本发明的方法用于在由自由基引发时交换反应性混合物中的抑制剂; 在这种交换中,可以将能够与碱形成盐的制剂抑制剂交换为可以根据其种类和数量自由选择的施用抑制剂。
    • 47. 发明授权
    • Starch-based materials and/or molded parts modified by synthetic polymer
compounds and process for producing the same
    • 由合成聚合物化合物改性的淀粉基材料和/或模塑部件及其制备方法
    • US5439953A
    • 1995-08-08
    • US70409
    • 1993-10-12
    • Wolfgang RitterRainer BergnerWolfgang Kempf
    • Wolfgang RitterRainer BergnerWolfgang Kempf
    • C08B31/00C08L3/00C08L3/02C08L31/04C08L33/00C08L33/04C08L67/00C08L67/02C08L75/00C08L75/04C08L77/00C08L101/00C08L101/16C08B30/12
    • C08L3/02
    • Disclosed are materials and/or shaped articles based on a starch which has been thermomechanically digested at elevated pressures and temperatures and with the addition of water and/or lower molecular weight plasticizing agents, said starch containing thermoplastic synthetic polymer compounds in an at least largely homogeneous mixture. The materials and/or shaped articles according to the invention are characterized in that their contents of synthetic thermoplastic polymer compounds is derived from aqueous polymer dispersions comprising a disperse polymer phase in an aqueous phase and that the synthetic thermoplastic polymer compounds have been incorporated in the starch in combination with the aqueous phase in such a manner that the starch digestion has been effected by the concomitant use of the aqueous phase of the polymer dispersions. Said materials and/or shaped articles have been preferably produced by a process wherein the starch digestion to form a thermoplastic material has occurred together with homogeneously mixing the aqueous polymer dispersions into the starch in one process step.
    • PCT No.PCT / EP91 / 02295 371日期:1993年10月12日 102(e)日期1993年10月12日PCT 1991年12月3日PCT PCT。 公开号WO92 / 10539 日期:1992年6月25日。公开的是基于淀粉的材料和/或成型制品,其在升高的压力和温度下热机械消化,并且加入水和/或较低分子量的增塑剂,所述淀粉含有热塑性合成聚合物 化合物在至少很均匀的混合物中。 根据本发明的材料和/或成形制品的特征在于它们的合成热塑性聚合物化合物的含量来源于水相中包含分散聚合物相的聚合物水分散体,并且合成的热塑性聚合物化合物已经掺入淀粉中 与水相组合,使得淀粉消化已经通过伴随使用聚合物分散体的水相而实现。 所述材料和/或成型制品优选地通过一种方法制备,其中淀粉消化形成热塑性材料已经在一个工艺步骤中一起发生,并将水性聚合物分散体均匀混合到淀粉中。
    • 48. 发明授权
    • Process for exchanging inhibitor(s) in olefinically unsaturated systems
which are reactive via free radicals
    • 在通过自由基反应的烯属不饱和体系中交换抑制剂的方法
    • US5278336A
    • 1994-01-11
    • US859429
    • 1992-09-24
    • Hans-Dieter SitzWolfgang Ritter
    • Hans-Dieter SitzWolfgang Ritter
    • C07C67/62C07C67/56C07C69/54C08F2/40C07C69/74
    • C07C67/62
    • The invention describes a process for the partial or complete exchange of the free radical inhibitors (preparation inhibitor) from their admixtures with free radical-reactive--and especially polymerizable and/or cross-linkable--olefinically mono- and/or polyunsaturated compounds against free radical inhibitors or inhibitor systems (application inhibitor), the kind and amount of which are freely determinable. The process according to the invention is characterized in that admixtures reactive via free radicals are employed which contain, as the preparation inhibitor, appropriate compounds of the phenol type comprising hydroxyl groups capable of forming salts, this feedstock mixture as a liquid phase is subjected to a treatment with solid oxides, carbonates and/or hydroxides of the alkali metals and/or alkaline earth metals, which may also be present in admixture with further oxidic metal compounds, thereby in a pre-determinable manner binding all or part of the preparation inhibitor to the solid phase, the resulting solid phase is separated from the liquid phase, and the content of the application inhibitor in this liquid phase is adjusted with respect to kind an amount thereof. The process is preferably applied to free radical-reactive substance mixtures, from which the preparation inhibitors contained therein cannot be satisfactorily removed by way of a distillation.
    • PCT No.PCT / EP90 / 01976 Sec。 371日期:1992年7月24日 102(e)日期1992年7月24日PCT 1990年11月19日PCT PCT。 出版物WO91 / 08192 日本1991年6月13日。本发明描述了将自由基抑制剂(制剂抑制剂)与其与自由基反应性特别是可聚合和/或可交联烯属单体和/或可交联烯烃的混合物的混合物部分或完全交换的方法 /或针对自由基抑制剂或抑制剂体系的多不饱和化合物(应用抑制剂),其种类和量可自由确定。 根据本发明的方法的特征在于,使用通过自由基反应的混合物,其含有作为制剂抑制剂的包含能够形成盐的羟基的酚类的适当化合物,将作为液相的原料混合物经受 用碱金属和/或碱土金属的固体氧化物,碳酸盐和/或氢氧化物处理,其还可以与其它氧化金属化合物混合存在,从而以预定的方式将所有或部分制剂抑制剂与 固相,将所得到的固相与液相分离,并且将该液相中的施加抑制剂的含量相对于其种类进行调整。 该方法优选应用于自由基反应性物质混合物,其中含有的制剂抑制剂不能通过蒸馏令人满意地除去。