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41. 发明授权

US5134242A Catalytic olefin upgrading process using synthetic mesoporous crystalline material 失效
标题翻译：催化烯烃升级过程采用合成介孔结晶材料
公开(公告)号：US5134242A
公开(公告)日：1992-07-28
申请号：US718884
申请日：1991-06-21
申请人： Quang N. Le , Robert T. Thomson , Grant H. Yokomizo
发明人： Quang N. Le , Robert T. Thomson , Grant H. Yokomizo
IPC分类号： B01J29/04 , B01J35/10 , C07C2/12 , C07C4/06 , C07C7/177 , C07C11/02
CPC分类号： C07C7/177 , B01J29/04 , B01J35/002 , B01J35/1019 , B01J35/1023 , B01J35/1028 , B01J35/1061 , C07C11/02 , C07C2/12 , C07C4/06 , C07C2529/70 , Y02P20/52
摘要： A process for upgrading aliphatic feedstocks containing lower olefins employing new synthetic catalyst of ultra-large pore crystalline material. The new crystalline material exhibits unusually large sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams at 50 torr and 25.degree. C., a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 Angstrom Units and a hexagonal arrangement of uniformly sized pores with a maximum perpendicular cross section of at least about 13 Angstrom units. A new process is provied for catalytic oligomerization of lower olefin component in paraffin-containing mixed aliphatic feedstock which comprises contacting the feedstock under catalytic conversion conditions with acid metallosilicate solid catalyst having the structure of MCM-41 with hexagonal honeycomb lattice structure consisting essentially of uniform pores in the range of about 20 to 100 Angstroms. The oligomerization reaction is very selective, especially when conducted at temperature of about 40.degree. to 250.degree. C., yielding branched intermediate olefins. Low severity reaction permits execellent conversion of lower olefins at pressure of about 100-13,000 pKa range and moderate space velocity. Oligomers of propene produced over MCM-41, when reacted under cracking/disproportionation conditions yield a propylene-rich mixture which is separated as a C.sub.3 stream, and C.sub.6 + isoalkenes are recovered in good yield.
摘要翻译：一种使用新型超大孔结晶材料合成催化剂升级含有低级烯烃的脂肪原料的方法。新的结晶材料表现出非常大的吸附能力，其吸附能力在50托和25℃时苯吸附能力大于约15克苯/ 100克，可以用大于约100的d100值进行指数的六方电子衍射图 18埃单位和具有至少约13埃单位的最大垂直截面的均匀尺寸孔的六边形排列。提出了一种新的方法，用于在含链烷烃的混合脂族原料中的低级烯烃组分的催化低聚，其包括在催化转化条件下使原料与具有基本上由均匀孔组成的六方蜂窝晶格结构的具有MCM-41结构的酸性金属硅酸盐固体催化剂在约20至100埃的范围内。低聚反应非常有选择性，特别是当在约40℃至250℃的温度下进行时，产生支链中间体烯烃。低强度反应允许在约100-13000pKa范围和适度的空间速度的压力下进行低级烯烃的非常好的转化。在裂解/歧化条件下反应时，MCM-41产生的丙烯的低聚物产生作为C3流分离的富丙烯混合物，以良好的收率回收C6 +异烯烃。

42. 发明授权

US5107049A Stabilization of polyalpha-olefins 失效
标题翻译：聚α-烯烃的稳定化
公开(公告)号：US5107049A
公开(公告)日：1992-04-21
申请号：US593171
申请日：1990-10-05
申请人： Quang N. Le , Joosup Shim , Stephen S. Wong
发明人： Quang N. Le , Joosup Shim , Stephen S. Wong
IPC分类号： B01J29/04 , C07C2/12 , C07C2/66 , C07C37/14 , C07C51/347
CPC分类号： C07C51/347 , B01J29/04 , C07C2/12 , C07C2/66 , C07C37/14 , C07C2529/06 , C07C2529/70
摘要： The thermal stability of poly alpha-olefin (PAO) lubricant basestocks are improved by reacting an aromatic compound with the alpha-olefin oligomer. The PAO materials are prepared by oligomerization of olefins such as 1-decene in the presence of a Lewis acid oligomerization catalyst. The resulting lubricant basestock product exhibits high viscosity, viscosity index and low pour point in addition to the unique enhancement in thermal stability. The reaction between the PAO and the aromatic is carried out in the presence of a solid, cyrstalline alkylation catalyst identified by a specific X-ray diffraction pattern. The preferred catalyst for this purpose is the material known as MCM-22.
摘要翻译：通过使芳族化合物与α-烯烃低聚物反应来改善聚α-烯烃（PAO）润滑剂基础油料的热稳定性。在路易斯酸低聚催化剂存在下，通过烯烃如1-癸烯的低聚制备PAO材料。除了独特的热稳定性提高之外，所得润滑剂基础油产品显示出高粘度，粘度指数和低倾点。 PAO和芳族化合物之间的反应是在特定X射线衍射图谱鉴定的固体，Cyrstalline烷基化催化剂的存在下进行的。用于该目的的优选催化剂是称为MCM-22的材料。

43. 发明授权

US5100533A Process for production of iso-olefin and ether 失效
标题翻译：异烯烃和醚的生产方法
公开(公告)号：US5100533A
公开(公告)日：1992-03-31
申请号：US607952
申请日：1990-11-01
申请人： Quang N. Le , Hartley Owen , Paul H. Schipper
发明人： Quang N. Le , Hartley Owen , Paul H. Schipper
IPC分类号： C10G57/00 , C10L1/02
CPC分类号： C10L1/023 , C10G57/00
摘要： Process and apparatus for upgrading paraffinic naphtha to high octane fuel by contacting a fresh virgin naphtha feedstock stream medium pore acid cracking catalyst comprising MCM-22 zeolite under low pressure selective cracking conditions effective to produce increased yield of total C4-C5 branched aliphatic hydrocarbhons. The preferred feedstock is straight run naptha containing C7+ alkanes, at least 15 wt % C7+ cycloaliphatic hydrocarbons and less than 20% aromatics, which can be converted with a fluidized bed catalyst in a vertical riser reactor during a short contact period.The isoalkene products of cracking are etherified to provide high octane fuel components.
摘要翻译：通过在低压选择性裂解条件下接触包含MCM-22沸石的新鲜原始石脑油原料流介质孔隙酸裂解催化剂，有效地产生总C4-C5支链脂族烃的产率提高，将石蜡石脑油升级成高辛烷值燃料的方法和设备。优选的原料是含有C7 +烷烃，至少15重量％的C7 +脂环族烃和少于20％的芳族化合物的直馏石脑油，其可以在短时间接触期间在垂直提升管反应器中用流化床催化剂转化。裂化的异烯烃产物被醚化以提供高辛烷值的燃料成分。

44. 发明授权

US5037528A Lubricant production process with product viscosity control 失效
标题翻译：润滑油生产过程与产品粘度控制
公开(公告)号：US5037528A
公开(公告)日：1991-08-06
申请号：US517958
申请日：1990-04-30
申请人： William E. Garwood , Quang N. Le , Stephen S. Wong
发明人： William E. Garwood , Quang N. Le , Stephen S. Wong
IPC分类号： C10G65/04 , C10G67/04
CPC分类号： C10G65/043 , C10G67/04
摘要： High viscosity index, low pour point lubricants are produced by the oligomerization of a wax-derived lubricant fraction. The fraction may be produced from slack wax or de-oiled wax by hydroisomerization over zeolite beta or hydrocracking/isomerization over an amorphous catalyst followed by selective dewaxing, preferably by catalytic dewaxing over a highly shape selective zeolite such as ZSM-23. The preferred peroxides are ditertiary alkyl peroxides such as ditertiary butyl peroxide (DTBP) and are typically used at temperatures of 100.degree.-300.degree. C.
摘要翻译：高粘度指数，低倾点润滑剂是通过蜡衍生的润滑剂部分的低聚产生的。馏分可以通过在沸石β上的加氢异构化或非晶态催化剂上的加氢裂化/异构化，然后进行选择性脱蜡，优选通过高度形状选择性沸石如ZSM-23的催化脱蜡来由松散蜡或脱油蜡产生。优选的过氧化物是二叔烷基过氧化物，例如二叔丁基过氧化物（DTBP），通常在100-300℃的温度下使用

45. 发明授权

US4990713A Process for the production of high VI lube base stocks 失效
标题翻译：生产高VI润滑油基础油的工艺
公开(公告)号：US4990713A
公开(公告)日：1991-02-05
申请号：US267888
申请日：1988-11-07
申请人： Quang N. Le , Robert A. Ware , Stephen S. Wong
发明人： Quang N. Le , Robert A. Ware , Stephen S. Wong
IPC分类号： C10G29/20 , C10G50/02 , C10G69/00
CPC分类号： C10G50/02 , C10G2400/10
摘要： High viscosity index, low pour point lubricants are produced by reacting an iso-paraffinic component, preferably with significant mono- and di-methyl chain branching, with an olefinic reactant in the presence of a free radical generator such as an organic peroxide, preferably ditertiary butyl peroxide. The isoparaffinic reactant is preferably obtained by the isomerization of a waxy feed such as slack wax over a zeolite beta isomerization catalyst, preferably Pt/zeolite beta. The olefinic reactant is preferably a distillate fraction produced by the oligomerization of low molecular weight olefins e.g., C.sub.3 to C.sub.5 olefins, produced by oligomerization over an intermediate pore size zeolite oligomerization catalyst such as ZSM-5.
摘要翻译：高粘度指数，低倾点润滑剂是通过在自由基发生剂如有机过氧化物，优选二次反应的存在下使异链烷烃组分，优选与显着的单 - 和二 - 甲基支链反应与烯属反应物反应制备的丁基过氧化物。异链烷烃反应物优选通过在沸石β异构化催化剂，优选Pt /沸石β上异构化蜡状进料如松散蜡来获得。烯烃反应物优选是通过低分子量的低分子量烯烃（例如C 3 -C 5烯烃）产生的馏出物馏分，其通过在中等孔径的沸石低聚催化剂如ZSM-5上低聚制得。

46. 发明授权

US4986894A Catalytic hydroisomerization process 失效
标题翻译：催化加氢异构化过程
公开(公告)号：US4986894A
公开(公告)日：1991-01-22
申请号：US495545
申请日：1990-03-19
申请人： Kathleen M. Keville , Quang N. Le , Wang-Tsee T. Mo , Mae K. Rubin
发明人： Kathleen M. Keville , Quang N. Le , Wang-Tsee T. Mo , Mae K. Rubin
IPC分类号： B01J29/04 , B01J29/70 , B01J29/86 , C07C2/12 , C10G45/64
CPC分类号： C10G45/64 , B01J29/04 , B01J29/86 , C07C2/12 , B01J29/70 , C07C2529/70
摘要： A process for dewaxing waxy hydrocarbon feedstocks to produce distillate fuels or lubricant stocks having improved pour point properties. The process comprises catalytic hydroisomerization of the feedstock over catalyst comprising a synthetic porous crystalline material characterized in its calcined form by an X-ray diffraction pattern including interplanar d-spacings at 12.36.+-.0.4, 11.03.+-.0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07, 3.91.+-.0.07 and 3.42.+-.0.06 Angstroms, and an Alpha Value of 10 or less.
摘要翻译：用于脱蜡蜡质原料以生产具有改进的倾点性质的馏出燃料或润滑剂原料的方法。该方法包括催化剂的催化加氢异构化，其包括合成多孔结晶材料，其特征在于其煅烧形式的X射线衍射图，其包括在12.36 +/- 0.4,11.03 +/- 0.2,8.83 +/-的平面d间距 0.14，6.18 +/- 0.12，6.00 +/- 0.10,4.06 +/- 0.07,3.91 +/- 0.07和3.42 +/- 0.06埃，Alpha值为10以下。

47. 发明授权

US4647369A Catalyst dewaxing process using a slurry phase bubble column reactor 失效
标题翻译：催化剂脱蜡工艺使用浆液相鼓泡塔反应器
公开(公告)号：US4647369A
公开(公告)日：1987-03-03
申请号：US848905
申请日：1986-04-04
申请人： Anthony Y. Kam , James C. Kuo , Quang N. Le , Jonah Smith
发明人： Anthony Y. Kam , James C. Kuo , Quang N. Le , Jonah Smith
IPC分类号： C10G45/66 , C10G11/00 , C10G47/24
CPC分类号： C10G45/66
摘要： Dewaxing a waxy feedstock is achieved by dispersing dewaxing catalyst particles within the liquid waxy feedstock and removing gaseous products out of contact with the catalyst by purging a gas stream through the liquid feedstock.
摘要翻译：脱蜡蜡质原料通过将脱蜡催化剂颗粒分散在液体蜡质原料中并通过吹扫通过液体原料的气流除去与催化剂接触的气态产物来实现。

48. 发明授权

US4539101A Method and catalyst for removing contaminants from hydrocarbonaceous fluids using a copper-Group VIA metal-alumina catalyst 失效
标题翻译：使用铜基VIA金属 - 氧化铝催化剂从含烃流体中除去污染物的方法和催化剂
公开(公告)号：US4539101A
公开(公告)日：1985-09-03
申请号：US524064
申请日：1983-08-17
申请人： Stephen M. Oleck , Quang N. Le , Daniel J. Neuman
发明人： Stephen M. Oleck , Quang N. Le , Daniel J. Neuman
IPC分类号： B01J23/85 , C10G45/04 , C01G45/04
CPC分类号： B01J23/85 , C10G45/04
摘要： There is provided a method and catalyst for removing catalyst-poisoning impurities or contaminants such as arsenic, iron and nickel from hydrocarbonaceous fluids, particularly shale oil and fractions thereof. More particularly there is provided a method of removal of such impurities by contacting the fluids with a copper-Group VIA metal-alumina catalyst. For example, a copper-molybdenum-alumina catalyst may be used as a guard bed material in a step preceding most refining operations, such as desulfurization, denitrogenation, catalytic hydrogenation, etc.
摘要翻译：提供了一种从含烃流体，特别是页岩油及其馏分中除去催化剂中毒杂质或污染物如砷，铁和镍的方法和催化剂。更具体地，提供了通过使流体与铜基团VIA金属 - 氧化铝催化剂接触来除去这些杂质的方法。例如，可以在大多数精炼操作之前的步骤中使用铜 - 钼 - 氧化铝催化剂作为保护床材料，例如脱硫，脱氮，催化氢化等。

49. 发明授权

US5271825A Turbine oil production 失效
标题翻译：涡轮机油生产
公开(公告)号：US5271825A
公开(公告)日：1993-12-21
申请号：US807003
申请日：1991-12-13
申请人： Robert W. Bortz , William E. Garwood , Quang N. Le , Stephen S. Wong
发明人： Robert W. Bortz , William E. Garwood , Quang N. Le , Stephen S. Wong
IPC分类号： C10G67/12 , C10G47/00
CPC分类号： C10G67/12 , C10G2400/10
摘要： Turbine oils are produced from a distillate lube fraction by hydrocracking to remove aromatics, catalytically dewaxing, hydrofinishing then treating with an organic peroxide, such as ditertiary butyl peroxide (DTBP) to increase viscosity and reduce cloud point.
摘要翻译：涡轮机油通过加氢裂化从馏出液润滑油馏分产生，以除去芳族化合物，催化脱蜡，加氢精制，然后用有机过氧化物如二叔丁基过氧化物（DTBP）处理以增加粘度和降低浊点。

50. 发明授权

US5220089A Olefin upgrading by selective catalysis 失效
标题翻译：通过选择性催化提升烯烃
公开(公告)号：US5220089A
公开(公告)日：1993-06-15
申请号：US718887
申请日：1991-06-21
申请人： Quang N. Le , Robert T. Thomson
发明人： Quang N. Le , Robert T. Thomson
IPC分类号： C07C6/04
CPC分类号： C07C6/04
摘要： Olefins are converted to lower alkene hydrocarbon products, e.g., propene, butenes, and isoalkenes with zeolite MCM-22 catalyst. This catalytic conversion is particularly useful in the selective separation of linear olefins in mixed hydrocarbon streams, employing MCM-22 catalyst to convert these straight-chain unsaturated components to lighter products, particularly, C.sub.3 -C.sub.4 olefins. One potential application of this selective separation is in the removal of linear olefins from FCC gasoline.
摘要翻译：使用沸石MCM-22催化剂将烯烃转化为低级烯烃产物，例如丙烯，丁烯和异烯烃。该催化转化特别可用于混合烃流中的线性烯烃的选择性分离，采用MCM-22催化剂将这些直链不饱和组分转化成较轻的产物，特别是C 3 -C 4烯烃。这种选择性分离的一个潜在应用是从FCC汽油中除去线性烯烃。

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