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    • 42. 发明授权
    • Flame-retardant resin composition
    • 阻燃树脂组合物
    • US07498368B2
    • 2009-03-03
    • US10557199
    • 2004-05-25
    • Hatsuhiko HarashinaShinya Yamada
    • Hatsuhiko HarashinaShinya Yamada
    • C08K5/3492C08K3/38C08K3/10
    • C08K5/0066C08K5/22C08K5/3492C08K5/42C08L67/02C08L2666/02
    • A flame-retardant resin composition comprises a base resin (e.g., a polyester-series resin), a flame retardant (A) comprising a salt of an amino group-containing triazine compound with a sulfuric acid and/or a sulfonic acid, a flame-retardant auxiliary (B). The flame-retardant auxiliary (B) includes an aromatic resin, acyclic urea-series compound or a derivative thereof [e.g., acetyleneurea, uric acid, a salt of melamine or a condensate thereof (e.g., melam, melem, and melon) with cyanuric acid], an amino group-containing triazine compound (e.g., melamine or a condensate thereof), and/or an inorganic metal-series compound (e.g., a metal salt of an oxygen acid having no sulfur atom, a metal oxide, a metal hydroxide, and a metal sulfide). The present invention provides a flame-retardant resin composition to which flame retardancy is imparted without using a halogen-series flame retardant and an organic phosphorus-series flame retardant.
    • 阻燃树脂组合物包含基础树脂(例如聚酯系树脂),包含含氨基的三嗪化合物的盐与硫酸和/或磺酸的阻燃剂(A),火焰 - 辅助剂(B)。 阻燃助剂(B)包括芳族树脂,无环脲系列化合物或其衍生物[例如乙炔脲,尿酸,三聚氰胺盐或其缩合物(例如二聚氰胺,蜜胺和甜瓜)和氰尿酸 酸],含氨基的三嗪化合物(例如三聚氰胺或其缩合物)和/或无机金属系化合物(例如,不含硫原子的氧酸的金属盐,金属氧化物,金属 氢氧化物和金属硫化物)。 本发明提供一种不使用卤素系阻燃剂和有机磷系阻燃剂而赋予阻燃性的阻燃性树脂组合物。
    • 45. 发明申请
    • Printer, printing method and printing program
    • 打印机,打印方式和打印程序
    • US20070177205A1
    • 2007-08-02
    • US11699470
    • 2007-01-30
    • Shinya YamadaSatoshi Ueda
    • Shinya YamadaSatoshi Ueda
    • G06F3/12
    • G06F3/12H04N1/00307H04N1/0044H04N1/0049H04N1/3873H04N2201/0082
    • According to a printer of the present invention, the displaying unit creates a print image of the image received by the receiving unit and displays a preview of the print image when the loss detecting unit detects the lost part of the image, and the displaying unit creates a print image of an image obtained as a result of the trimming and displays a preview of the print image when the trimming unit trims the image, and the printing unit prints an image obtained as a result of the trimming by the trimming unit. Consequently, if a user failed in communicating an image as the user did not set an external communication terminal to an appropriate place and the image has been lost, the user can display a preview of the image by removing the lost part by trimming and display the lost part by a preview, check the trimmed image and print it.
    • 根据本发明的打印机,显示单元创建由接收单元接收的图像的打印图像,并且当损失检测单元检测到图像的丢失部分时显示打印图像的预览,并且显示单元创建 作为修剪结果获得的图像的打印图像,并且当修剪单元修剪图像时显示打印图像的预览,并且打印单元打印通过修剪单元修剪的结果获得的图像。 因此,如果用户在没有将外部通信终端设置到适当的位置并且图像已经丢失的情况下传送图像失败,则用户可以通过修剪去除丢失的部分来显示图像的预览并显示 通过预览丢失部分,检查修剪的图像并打印。
    • 48. 发明授权
    • Flame-retardant resin composition
    • 阻燃树脂组合物
    • US06790886B2
    • 2004-09-14
    • US09914141
    • 2001-08-23
    • Hatsuhiko HarashinaToshio NakaneShinya YamadaYuji Tada
    • Hatsuhiko HarashinaToshio NakaneShinya YamadaYuji Tada
    • C08K55399
    • C08K5/5399C08L25/18C08L61/00C08L65/00C08L67/02C08L2666/02C08L71/00
    • A polyalkylene terephthalate-series resin (e.g., polyethylene terephthalate-series resin, polybutylene terephthalate-series resin) is improved in flame retardancy by using a flame retardant containing a phosphazene compound and a phenolic resin. The phosphazene compound is a compound shown by the following formulae (1) and/ or (2), and/or a compound being the above compound crosslinked with a phenylene group or a crosslinking group shown by the following formula (3a). The proportion of the phosphazene compound to the phenolic resin is the former/the latter=5/95 to 95/5 (weight ratio). By means of the above flame retardant, a polyalkylene terephthalate-series resin can be highly improved in flame retardancy without deteriorating the properties. Further, by adding the other flame retardant (e.g., a nitrogen-containing flame retardant, a phosphate-series flame retardant), and a carbonizable resin, the flame retardancy can be enhanced. Mechanical Property In accordance with ASTM D-638 and ASTM D-790, the mechanical strength was determined with use of a test piece obtained by injection molding.
    • 通过使用含有磷腈化合物和酚醛树脂的阻燃剂,聚对苯二甲酸亚烷基酯系树脂(例如聚对苯二甲酸乙二醇酯系树脂,聚对苯二甲酸丁二醇酯系树脂)的阻燃性提高。 磷腈化合物是下述通式(1)和/或(2)所示的化合物,和/或上述化合物,与上述通式(3a)所示的亚苯基或交联基团交联的化合物。 磷腈化合物与酚醛树脂的比例为前者/后者= 5/95〜95/5(重量比)。 通过上述阻燃剂,聚对苯二甲酸亚烷基对苯二甲酸酯系树脂可以在阻燃性方面得到高度改善,而不会降低性能。 此外,通过添加另一种阻燃剂(例如含氮阻燃剂,磷酸酯系阻燃剂)和可碳化树脂,可以提高阻燃性。机械性能根据ASTM D-638和ASTM D- 790中,使用通过注射成型获得的试验片测定机械强度。
    • 49. 发明授权
    • Method of preparing an acrylic copolymer having an acid anhydride group
    • 制备具有酸酐基团的丙烯酸共聚物的方法
    • US06723813B2
    • 2004-04-20
    • US10462636
    • 2003-06-17
    • Tomohito AsaiShinya YamadaYusuke Ninomiya
    • Tomohito AsaiShinya YamadaYusuke Ninomiya
    • C08F12204
    • C08F222/04C08F220/12
    • The present invention is a method of preparing an acrylic copolymer having an acid anhydride group with a number average molecular weight of 1,500-5,000 comprising; polymerizing a monomer mixture of a radical polymerizable monomer having an acid anhydride group and another radical polymerizable monomer at a temperature of 150° C. or higher by using a radical initiator, wherein the concentration of the monomer mixture is 50-75 wt %. This method can provide an acrylic copolymer having an acid anhydride group with a relatively low molecular weight that does not cause the problem of yellowing after baking when used in an acid/epoxy curing type clear paint, by means of high temperature polymerization without the use of a large amount of an expensive initiator.
    • 本发明是一种制备具有数均分子量为1,500-5,000的酸酐基的丙烯酸共聚物的方法,其包括:将具有酸酐基的可自由基聚合单体和另一种可自由基聚合的单体的单体混合物在温度 通过使用自由基引发剂为150℃以上,其中单体混合物的浓度为50-75重量%。该方法可以提供具有相对低分子量的酸酐基团的丙烯酸共聚物,其不会引起 用于酸/环氧树脂固化型透明涂料中的烘烤后的黄变问题,通过高温聚合而不使用大量昂贵的引发剂。