专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

41. 发明授权

US4139682A Cells having cathodes derived from ammonium-copper-molybdenum-chalcogen compounds 失效
标题翻译：具有衍生自铵 - 铜 - 钼 - 硫属化合物的阴极的电池
公开(公告)号：US4139682A
公开(公告)日：1979-02-13
申请号：US910478
申请日：1978-05-30
申请人： Allan J. Jacobson , M. Stanley Whittingham
发明人： Allan J. Jacobson , M. Stanley Whittingham
IPC分类号： H01M4/136 , H01M4/58 , H01M10/052 , H01M10/054 , H01M10/36
CPC分类号： H01M10/052 , H01M4/136 , H01M4/581 , H01M10/054
摘要： The present invention is directed to an electric current-producing cell which contains:(a) an anode having as its anode-active material one or more metals selected from the group consisting of the Periodic Table Group IA metals, Group IB metals, Group IIA metals and Group IIB metals;(b) a cathode having as its cathode-active material one or more compounds selected from:(i) those having the formula:NH.sub.4 CuMoZy (1)wherein Z is a chalcogen selected from the group consisting of sulfur, selenium, sulfur-selenium mixtures, sulfur-oxygen mixtures and selenium-oxygen mixtures, and wherein y is a numerical value of about 4.(ii) the decomposition products of one or more compounds of subparagraph (i), resulting from the decomposition thereof below about 350.degree. C; and(c) an electrolyte which is chemically inert with respect to said anode and said cathode and which permits the migration of ions between said anode and said cathode.BACKGROUND OF THE INVENTION1. Field of the InventionThe present invention relates to electric current-producing cells, and more particularly to such cells employing specified cathode-active materials comprising or derived from ammonium-copper-molybdenum-chalcogenide compounds.2. Description of the Prior ArtThere has been considerable interest in recent years in developing high energy density batteries for voltaic cells. Exemplary of the developing systems is a high energy density electrochemical cell utilizing intercalation compounds of the transition metal chalcogenides as cathode-active materials and using alkali metal anodes, as set forth in U.S. Pat. No. 4,009,052. U.S. Pat. No. 3,915,740 describes a cell having lithium anode-active material and MoS.sub.x (where 2 .ltoreq. .times. .ltoreq. 3) as its cathode-active material, and U.S. Pat. No. 3,864,167 describes some fibrous transition metal trichalcogenides as cathode-active materials. U.S. Pat. No. 3,655,585 describes a cell utilizing as cathode active material vanadium pentoxide, prepared by the thermal decomposition of ammonium vanadate.U.S. Pat. Nos. 3,898,096, 3,925,098 and 4,003,753 describe electrochemical cells having alkali metal anodes, e.g., lithium, having molten salt electrolytes, and having cathodes containing chalcogenides such as Cu and Fe sulfides, Ni sulfide and oxide and molybdenum sulfide, as well as potassium thiomolybdate K.sub.2 MoS.sub.4.The compounds utilized as the cathode active materials in the cells of the present invention are ammonium-copper-molybdenum-chalcogenide type compounds. In this regard, it should be noted that ammonium-metal-chalcogenide compounds are known, as exemplified by U.S. Pat. No. 2,435,380. However, notwithstanding the considerable variety of high energy density electrochemical cell systems which have recently been developed, it is believed that the particular cells of the present invention containing the ammonium-copper-molybdenum-chalcogenides have not been heretofore disclosed or rendered obvious.SUMMARY OF THE INVENTIONThe present invention is directed to an electric current-producing cells which contains:(a) an anode having as its anode-active material one or more metals selected from the group consisting of the Periodic Table Group IA metals, Group IB metals, Group IIA metals and Group IIB metals;(b) a cathode having as its cathode-active material one or more compounds selected from:(i) those having the formula:NH.sub.4 CuMoZ.sub.y ( 1)wherein Z is a chalcogen selected from the group consisting of sulfur, selenium, sulfur-selenium mixtures, sulfur-oxygen mixtures and selenium-oxygen mixtures, and wherein y is a numerical value of about 4;(ii) the decomposition products of one or more compounds of subparagraph (i), resulting from the decomposition thereof below about 350.degree. C.; and(c) an electrolyte which is chemically inert with respect to said anode and said cathode and which permits the migration of ions between said anode and said cathode.DETAILED DESCRIPTION OF THE INVENTIONAs mentioned, the electric current-producing cell of the present invention is one which contains a specified anode, a functional electrolyte, and a cathode having as its cathode-active material compounds derived from ammonium-copper-molybdenum-chalcogenide compounds.In general, the anode employed in the cell of the present invention is one which contains as its anode-active material one or more metals selected from the group consisting of the Periodic Table Group IA metals, Group IB metals, Group IIA metals and Group IIB metals. Of these, the Group IA metals, also known as the alkali metals, are desirable. Preferred is the anode having as its anode-active material a metal selected from the group consisting of lithium and sodium, and most preferably lithium. The anode-active material may be in contact with other metal structures in the cell of the present invention, depending upon the particular anode-active material being used. Thus, for example, some anode-active materials are selfsupporting and may also serve as current collectors whereas other anode-active materials, e.g. lithium, may be in contact with other metal structures, such as nickel, copper or silver screen, which serve as current collectors. These anode configurations are a matter of design depending upon the particular anode-active material being used and are well known in the art.The cathode employed in the cell of the present invention is one which contains as its cathode-active material one or more compounds selected from the group consisting of(i) those having the formulaNH.sub.4 CuMoZ.sub.y ( 1)wherein Z is a chalcogen selected from the group consisting of sulfur, selenium, sulfur-selenium mixtures, sulfur-oxygen mixtures and selenium-oxygen mixtures, and wherein y is a numerical value of about 4;(ii) the decomposition products of one or more compounds of subparagraph (i) resulting from the decomposition thereof below about 350.degree. C.The variable Z as defined above represents a chalcogen selected from the group consisting of sulfur, selenium, sulfur-selenium mixtures, sulfur-oxygen mixtures and seleniumoxygen mixtures. Desirably, Z is selected from the group consisting of sulfur and selenium. Preferably, the chalcogen Z is sulfur.Among the many cathode-active materials which are used in the cells of the present invention are:Nh.sub.4 cuMoS.sub.4Nh.sub.4 cuMoSe.sub.4Nh.sub.4 cuMoS.sub.4-a Se.sub.aNh.sub.4 cuMoS.sub.4-a O.sub.aand the like, wherein 4 > a > 0. Also, as mentioned above, the decomposition products of the foregoing are included.The above-mentioned cathode-active compounds may be prepared by known techniques and are believed to be within the purview of the artisan. For example, ammonium copper thiomolybdate may be formed by passing sulfurous vapors through a solution of ammonium molybdate and copper sulfate. The decomposition products of ammonium copper thiomolybdate may be obtained at temperatures below about 350.degree. C. by thermal decomposition. Thus, heating ammonium copper thiomolybdate at temperatures about 50.degree. C. or so and up to as high as 350.degree. C. will effect at least to some degree the thermal decomposition of the compound. If the decomposition products of ammonium copper thiomolybdate are obtained at temperatures below about 350.degree. C., a poorly crystalline product is obtained with a sulfur/metal ratio greater than 2.5 but less than 4, whereas heating at higher temperature results in conversion to Cu.sub.2-x S and MoS.sub.2. The sulfide decomposition products obtained below about 350.degree. C. have surprisingly been found to effect significantly higher energy density electrochemical cells than the products obtained by thermal decomposition above 350.degree. C. or so.The cathode active materials of the compounds described above which have been decomposed thermally may be characterized by X-ray diffraction.Advantageously, the cathode active compounds of the present invention cells may simply be cold pressed into a cathode structure. Alternatively, they may be hot pressed (wherein at least partial thermal decomposition is inherent), into a cathode structure, although the thermal decompositions described may be employed prior to cathode construction. The cathode-active material may be supported on structures such as carbon, copper, nickel, stainless steel, iron, etc., and it may be supported on such materials or it may be impregnated into such materials. Advantageously, the cathode need not contain any conductive diluents within the cathode active material, such as carbon. However, plastic binding agents such as polyfluoroethylene may be utilized if desired.The electrolyte used in the cell of the present invention is any electrolyte which is chemically inert with respect to the anode and with respect to the cathode, and which permits the migration of ions between the anode and the cathode. In general, the choice of electrolyte depends upon the anode-active material being used in the cell. Thus, where the anode-active material is a Group IA metal, the electrolyte will most likely be nonaqueous. However, where the anode-active material is one which is selected, for example, from the Group IIB metals, an aqueous electrolyte may be employed. When the preferred anode-active material selected from the Group IA metals is used in a cell in the present invention, the electrolyte may typically be a nonaqueous alkali metal salt-organic solvent electrolyte solution. These alkali metal salts are well known in the art and need not be enumerated herein. However, such salts include the lithium and sodium salt complexes which are dissolved in organic solvents such as the inertly substituted and unsubstituted ethers, sulfones, organic sulfates, organic sulfites, organic nitrites and organic nitro compounds. One preferred electrolyte for use in conjunction with cells containing lithium as its anode-active material is an electrolyte containing lithium perchlorate salt dissolved in dioxolane or a dioxolane-containing solution. One preferred electrolyte in cells containing sodium as its anode-active material contains sodium triethyl pyrrole boron dissolved in a cyclic ether containing solution. Alternatively, solid electrolytes, such as the beta aluminas or halides, or molten salts, may be used.The electric current-producing cells of the present invention containing the above-mentioned anodes, cathodes and electrolytes not only have high energy densities, but are also capable of being cycled through charging and discharging, and may be readily produced on a large-scale basis.
摘要翻译：本发明涉及一种电流产生电池，其包含：

42. 发明授权

US08637209B2 Cathode and electrolyte materials for solid oxide fuel cells and ion transport membranes 有权
标题翻译：用于固体氧化物燃料电池和离子迁移膜的阴极和电解质材料
公开(公告)号：US08637209B2
公开(公告)日：2014-01-28
申请号：US11990295
申请日：2006-08-09
申请人： Allan J. Jacobson , Shuangyan Wang , Gun Tae Kim
发明人： Allan J. Jacobson , Shuangyan Wang , Gun Tae Kim
IPC分类号： H01M4/62 , H01M4/90 , H01M4/88
CPC分类号： C04B35/016 , B01D53/228 , B01D71/024 , B01D2256/12 , C01B13/0255 , C01G49/009 , C01G51/68 , C01P2002/34 , C01P2002/72 , C01P2002/77 , C01P2002/78 , C01P2004/32 , C01P2006/40 , C04B35/01 , C04B35/2641 , C04B35/50 , C04B2235/3215 , C04B2235/3224 , C04B2235/3229 , C04B2235/3275 , C04B2235/449 , C04B2235/658 , C04B2235/6584 , C04B2235/761 , C04B2235/77 , C04B2235/79 , C04B2235/80 , C04B2235/81 , H01M4/9033 , H01M2008/1293
摘要： Novel cathode, electrolyte and oxygen separation materials are disclosed that operate at intermediate temperatures for use in solid oxide fuel cells and ion transport membranes based on oxides with perovskite related structures and an ordered arrangement of A site cations. The materials have significantly faster oxygen kinetics than in corresponding disordered perovskites.
摘要翻译：公开了新型阴极，电解质和氧分离材料，其在中等温度下操作，用于基于具有钙钛矿相关结构的氧化物和A位阳离子的有序排列的固体氧化物燃料电池和离子迁移膜。与相应的无序钙钛矿相比，这些材料具有显着更快的氧动力学。

43. 发明授权

US5047567A Heteropolyoxo vanadium compounds containing molecular anions and their structure 失效
标题翻译：含有分子阴离子的杂多钒化合物及其结构
公开(公告)号：US5047567A
公开(公告)日：1991-09-10
申请号：US583406
申请日：1990-09-17
申请人： Guohe Huan , Allan J. Jacobson
发明人： Guohe Huan , Allan J. Jacobson
IPC分类号： C07F9/38 , C07F9/70
CPC分类号： C07F9/703 , C07F9/38
摘要： A solid composition of matter comprising heteropolyoxo vanadium oxide compounds of the general formula: (R'.sub.4 N).sub.x H.sub.y (VO.sub.b).sub.a (RQO.sub.3).sub.-- nH.sub.2 O) wherein (VO.sub.b).sub.a (RQO.sub.3) is a molecular anion; R' is a substituted or unsubstituted monovalent organic group covalently bound to nitrogen to form a tetraorgano ammonium cation (R'.sub.4 N); R is a substituted or unsubstituted monovalent organic group covalently bound to Q to form an organophosphorus or organoarsenous group; R and R' are selected from the group consisting of C.sub.1 -C.sub.20 alkyl, aryl, hetero alkyl, hetero aryl or mixtures thereof; Q is a phosphorus or arsenic atom; a is about 1.0 to about 3.0; b is about 1.0 to about 2.0; (x+y) are determined by the vanadium oxidation state (m) where (x+y) equals (2ab+2)-ma and where (x+y) and x can not equal zero; and n is zero or a positive number.
摘要翻译：包含通式为（R'4N）xHy（VOb）a（RQO3）-nH2O）的杂多氧化钒化合物的固体组合物，其中（VOb）a（RQO3）是分子阴离子; R'是与氮共价结合以形成四有机铵阳离子（R'4N）的取代或未取代的一价有机基团。 R是与Q共价结合形成有机磷或有机砷基团的取代或未取代的一价有机基团; R和R'选自C1-C20烷基，芳基，杂烷基，杂芳基或其混合物; Q是磷或砷原子; a为约1.0至约3.0; b为约1.0至约2.0; （x + y）由钒氧化态（m）确定，其中（x + y）等于（2ab + 2）-ma，其中（x + y）和x不能等于零; n为零或正数。

44. 发明授权

US4518534A Layered vanadium compounds containing phosphorus or arsenic and pendant organic groups 失效
标题翻译：含有磷或砷的分层钒化合物和有机基团
公开(公告)号：US4518534A
公开(公告)日：1985-05-21
申请号：US525142
申请日：1983-08-22
申请人： Jack W. Johnson , Allan J. Jacobson
发明人： Jack W. Johnson , Allan J. Jacobson
IPC分类号： B01D15/00 , B01J20/18 , B01J27/198 , B01J31/02 , B01J31/12 , B01J31/16 , B01J31/18 , C07B61/00 , C07C31/02 , C07C33/20 , C07F9/00 , C07F9/09 , C07F9/38 , C07F9/70
CPC分类号： C07F9/703 , B01J23/002 , B01J27/198 , B01J31/1691 , B01J31/185 , C07C31/02 , C07C33/20 , C07F9/09 , C07F9/38 , B01J2523/00 , B01J2531/56
摘要： A layered oxide containing vanadium together with phosphorus or arsenic and an organic group may be prepared which has a unique layered structure of the formula: VORAO.sub.3.nS or VOROAO.sub.3.nS where A is phosphorus or arsenic, S is a solvent molecule, R is an unsubstituted or alkyl-, alkoxy- or aryl-substituted alkyl or aryl group, and n is zero or a positive number. These layered compounds are characterized in that the vanadium is substantially in a 4+ oxidation state and is present in an amount such that the molar ratio of A:V ranges from 0.8 to 1.2 throughout the oxide. Also the R groups are covalently bound to an A atom in the vanadium oxide layer directly through either carbon or oxygen atoms.
摘要翻译：可以制备含有钒与磷或砷的有机基团的层状氧化物和有机基团，其具有下式的独特层状结构：VORAO3.nS或VOROAO3.nS，其中A为磷或砷，S为溶剂分子，R为未取代或烷基，烷氧基或芳基取代的烷基或芳基，n为零或正数。这些层状化合物的特征在于钒基本上处于4+氧化态，并且存在的量使得在整个氧化物中A:V的摩尔比范围为0.8-1.2。 R基团也直接通过碳原子或氧原子与氧化钒层中的A原子共价结合。

45. 发明授权

US4233375A High energy density plural chalcogenide cathode-containing cell 失效
标题翻译：高能密度多硫族化物阴极电池
公开(公告)号：US4233375A
公开(公告)日：1980-11-11
申请号：US63107
申请日：1979-08-02
申请人： M. Stanley Whittingham , Allan J. Jacobson
发明人： M. Stanley Whittingham , Allan J. Jacobson
IPC分类号： H01M4/36 , H01M4/58 , H01M6/14
CPC分类号： H01M4/5815 , H01M4/36 , H01M4/364
摘要： The present invention is directed to electric current-producing cells having specified mixed cathodes. The cells comprise: (a) an anode having as its anode-active material one or more metals selected from the group consisting of the Periodic Table Group IA metals, Group IB metals, Group IIA metals and Group IIB metals; (b) a cathode having as its cathode-active material a mixture containing: (i) one or more cathode-active, high energy density chalcogenide compounds selected from the group consisting of VS.sub.a, VO.sub.a, C.sub.x S, MoO.sub.z and MoS.sub.z, wherein a is a numerical value of about 1.8 to about 2.7, wherein x is a numerical value of about 4 to about 16 and wherein z is a numerical value of about 2.5 to about 3.5; and (ii) one or more cathode-active, high rate chalcogenide compounds selected from the group consisting of TiS.sub.y, TiSe.sub.y and VSe.sub.y wherein y is a numerical value of about 1.8 to about 2.2; and (c) an electrolyte which is chemically inert with respect to said anode and said cathode and which permits the migration of ions between said anode and said cathode. A preferred embodiment contains a lithiumactive material anode and a cathode containing a mixture of MoS.sub.3 and TiS.sub.2.
摘要翻译：本发明涉及具有特定混合阴极的电流产生电池。电池包括：（a）阳极，其具有作为其阳极活性材料的一种或多种金属，其选自元素周期表IA族金属，第IB族金属，IIA族金属和IIB族金属; （b）具有作为其阴极活性材料的阴极，其混合物包含：（i）一种或多种选自VSa，VOa，CxS，MoOz和MoSz的阴极活性高能量密度硫属化物化合物，其中a为约1.8至约2.7的数值，其中x为约4至约16的数值，并且其中z为约2.5至约3.5的数值; 和（ii）一种或多种选自TiSy，TiSey和VSey + L的阴极活性的高比率硫族化物化合物，其中y是约1.8至约2.2的数值; 和（c）相对于所述阳极和所述阴极化学惰性的电解质，并允许离子在所述阳极和所述阴极之间迁移。优选的实施方案包含含有MoS 3和TiS 2的混合物的锂活性材料阳极和阴极。

46. 发明申请

US20130123560A1 POROUS SOLIDS, SELECTIVE SEPARATIONS, REMOVAL OF SULFUR COMPOUNDS, ADSORPTION 审中-公开
标题翻译：多孔固体，选择性分离，去除硫化合物，吸附
公开(公告)号：US20130123560A1
公开(公告)日：2013-05-16
申请号：US13656851
申请日：2012-10-22
申请人： Allan J. Jacobson , Xiqu Wang , Lumei Liu
发明人： Allan J. Jacobson , Xiqu Wang , Lumei Liu
IPC分类号： B01J20/22
CPC分类号： B01J20/223 , B01J20/226
摘要： Crystals of [VOBDC](H2BDC)0.71 were synthesized hydrothemally. The guest acid molecules were removed by heating in air to give high quality single crystals of VOBDC. VOBDC was observed to show crystal-to-crystal transformations on absorption of the guest molecules aniline, thiophene and acetone from the liquid phase. Accurate structural data of the guest molecules and framework deformations were obtained from single crystal X-ray data. VOBDC was also shown to absorb selectively thiophene and dimethyl sulphide from methane.
摘要翻译：水合物合成[VOBDC]（H2BDC）0.71的晶体。通过在空气中加热除去游离酸分子，得到高质量的VOBDC单晶。观察到VOBDC在从液相中吸收客体分子苯胺，噻吩和丙酮时发生晶体 - 晶体转变。从单晶X射线数据获得客体分子和骨架变形的精确结构数据。还显示VOBDC从甲烷中选择性吸收噻吩和二甲基硫化物。

47. 发明授权

US08293133B2 Porous solids, selective separations, removal of sulfur compounds, adsorption 有权
标题翻译：多孔固体，选择性分离，去除硫化合物，吸附
公开(公告)号：US08293133B2
公开(公告)日：2012-10-23
申请号：US12376804
申请日：2007-08-09
申请人： Allan J. Jacobson , Xiqu Wang , Lumei Liu
发明人： Allan J. Jacobson , Xiqu Wang , Lumei Liu
IPC分类号： C09K3/00 , B01D39/00 , C07F7/00 , C07F9/00 , C07F11/00 , C07F15/00 , C07F5/06
CPC分类号： B01D53/02 , B01D15/00 , B01D53/508 , B01D2215/021 , B01D2251/90 , B01D2253/204 , B01D2253/308 , B01D2257/302 , B01J20/226 , C02F1/285 , C02F2101/101 , C10G25/003 , C10G2300/1011 , C10G2300/202 , C10L3/10 , C10L3/102 , Y02P30/20
摘要： Crystals of [VOBDC](H2BDC)0.71 were synthesized hydrothemally. The guest acid molecules were removed by heating in air to give high quality single crystals of VOBDC. VOBDC was observed to show crystal-to-crystal transformations on absorption of the guest molecules aniline, thiophene and acetone from the liquid phase. Accurate structural data of the guest molecules and framework deformations were obtained from single crystal X-ray data. VOBDC was also shown to absorb selectively thiophene and dimethyl sulphide from methane.
摘要翻译：水合物合成[VOBDC]（H2BDC）0.71的晶体。通过在空气中加热除去游离酸分子，得到高质量的VOBDC单晶。观察到VOBDC在从液相中吸收客体分子苯胺，噻吩和丙酮时发生晶体 - 晶体转变。从单晶X射线数据获得客体分子和骨架变形的精确结构数据。还显示VOBDC从甲烷中选择性吸收噻吩和二甲基硫化物。

48. 发明授权

US5183788A Modular surface catalyzed membrane containing a microporous membrane catalyst layer and transport layer 失效
标题翻译：模块化表面催化膜含有微孔膜催化剂层和输送层
公开(公告)号：US5183788A
公开(公告)日：1993-02-02
申请号：US775646
申请日：1991-10-10
申请人： Allan J. Jacobson , Wen-Yih F. Lai , Michael G. Matturro , Harry W. Deckman , James A. McHenry , Robert P. Reynolds , Qiyao Zhang
发明人： Allan J. Jacobson , Wen-Yih F. Lai , Michael G. Matturro , Harry W. Deckman , James A. McHenry , Robert P. Reynolds , Qiyao Zhang
IPC分类号： B01J23/652 , B01J35/06 , B01J35/10 , B01J37/02 , C04B41/85 , C04B41/89 , C07C5/03 , C07C43/18
CPC分类号： B01J37/0244 , B01J35/065
摘要： Accordingly, there is provided a catalytic membrane comprising a porous substrate having a first surface and a second surface. The substrate has micropores, for example, pores ranging from about 10 .ANG. to about 2000 .ANG. in diameter, at least in a region extending from the first surface toward the second surface for a preselected distance. Preferably, the preselected distance will be sufficient to provide a measurable resistance to the flow of a fluid, such as a gas, through the micropores. A catalyst is deposited at least on the first surface of the substrate, although optionally, the catalyst is deposited on the substrate in the micorpore region. A transport layer is provided on the first surface of the substrate, including any catalyst on the first surface.

49. 发明授权

US5015461A Novel high surface area oxide compositions with a pyrochlore structure, methods for their preparation, and conversion processes utilizing same 失效
标题翻译：具有烧绿石结构的新型高表面积氧化物组合物，其制备方法和利用其的转化方法
公开(公告)号：US5015461A
公开(公告)日：1991-05-14
申请号：US343752
申请日：1989-06-26
申请人： Allan J. Jacobson , Richard B. Hall , Charles A. Mims , Joseph T. Lewandowski
发明人： Allan J. Jacobson , Richard B. Hall , Charles A. Mims , Joseph T. Lewandowski
IPC分类号： B01J23/00 , C01G19/00 , C01G29/00 , C01G33/00 , C01G35/00 , C01G41/00 , C01G55/00 , C07C2/84
CPC分类号： C01G55/00 , B01J23/005 , C01G19/00 , C01G29/00 , C01G33/00 , C01G35/00 , C01G35/006 , C01G41/006 , C07C2/84 , C01P2002/36 , C01P2002/54 , C01P2002/72 , C01P2002/74 , C01P2002/77 , C01P2004/84 , C01P2006/12 , C01P2006/80 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2521/14 , C07C2523/02 , C07C2523/10 , C07C2523/14 , C07C2523/18
摘要： Processes for the conversion of hydrocarbons, and most preferably methane, to higher hydrocarbons and olefins are disclosed, including contacting the hydrocarbons with a mixed metal oxide catalyst having the pyrochlore structure. Preferably, these catalysts have the general formula A.sub.n B.sub.2 O.sub.7 -x, where A can be various mono-, di-, and trivalent metal cations, B can be various tri-, tetra-, penta-, and hexavalent metal cations, 0.ltoreq.n.ltoreq.2.0, and 0.ltoreq.x.ltoreq.1.0. Novel, high surface area, mixed metal oxide cataysts having the pyrochlore structure are also disclosed, including those having the formula A.sub.2 B.sub.2 O.sub.7, where A is divalent and B is niobium and/or tantalum, and those having the formula A.sub.2 (Sn.sub.2-y A.sub.y)O.sub.7-z, where A is bismuth and/or lead, 0.0.ltoreq.y.ltoreq.1.0, and 0.0.ltoreq.z.ltoreq.1.0.

50. 发明授权

US4503166A Cation-reordered, bismuth-containing perovskites 失效
标题翻译：阳离子重排序，含铋钙钛矿
公开(公告)号：US4503166A
公开(公告)日：1985-03-05
申请号：US601076
申请日：1984-04-16
申请人： Robert A. Beyerlein , Kenneth R. Poeppelmeier , Allan J. Jacobson
发明人： Robert A. Beyerlein , Kenneth R. Poeppelmeier , Allan J. Jacobson
IPC分类号： C10G29/00 , B01J23/00 , B01J23/18 , C01G29/00 , C07B61/00 , C07C1/00 , C07C2/42 , C07C2/76 , C07C2/84 , C07C15/02 , C07C15/04 , C07C67/00 , C10G35/06 , B01J23/02
CPC分类号： C01G29/006 , B01J23/18 , C07C2/84 , C01P2002/34 , C01P2002/72 , C01P2002/88 , C07C2523/02 , C07C2523/10 , C07C2523/18 , Y02P20/52 , Y10S502/525
摘要： A class of cation-reordered, bismuth-containing compounds having a perovskite-type structure of the formulaBa.sub.2 La.sub.y Bi.sub.2-y O.sub.6wherein y is greater than 0 but less than 1, is provided. Preferably, y is from 0.25 to 0.75, and most preferably y is 0.5.The compositions herein are found to be particularly advantageous in the selective production of aromatic compounds from acyclic olefins, particularly in the production of benzene from propylene.
摘要翻译：提供一类具有式Ba2LayBi2-yO6的钙钛矿型结构的阳离子重排的含铋化合物，其中y大于0但小于1。优选地，y为0.25〜0.75，最优选为0.5。发现本文中的组合物特别有利于从无环烯烃选择性地制备芳族化合物，特别是在从丙烯生产苯中。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式