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41. 发明申请

US20090234158A1 Catalyst for use in production of methacrylic acid and method for manufacturing the same 失效
标题翻译：用于生产甲基丙烯酸的催化剂及其制造方法
公开(公告)号：US20090234158A1
公开(公告)日：2009-09-17
申请号：US11887017
申请日：2006-03-28
申请人： Atsushi Sudo , Tatsuhiko Kurakami , Toshitake Kojima , Shigeo Hayashimoto
发明人： Atsushi Sudo , Tatsuhiko Kurakami , Toshitake Kojima , Shigeo Hayashimoto
IPC分类号： B01J27/24 , C07C51/16
CPC分类号： B01J37/0221 , B01J21/04 , B01J23/002 , B01J27/199 , B01J35/08 , B01J37/0009 , B01J37/0045 , B01J37/0219 , B01J37/03 , B01J2523/00 , C07C51/252 , C07C57/04 , B01J2523/15 , B01J2523/17 , B01J2523/51 , B01J2523/53 , B01J2523/55 , B01J2523/68
摘要： It is an object to provide a simple method for producing catalysts available in various reaction conditions, that allow gas-phase catalytic oxidation of methacrolein and the like to give methacrylic acid with high yield, high selectivity and stable methacrylic yield over extended time.A method for manufacturing a catalyst of which active components are partly neutralized salt of heteropoly acid comprising molybdenum, phosphorus, vanadium, cesium, antimony, and ammonia as essential components, wherein the method is characterized in mixing an antimony compound with a complex oxide of the essential active components in the catalyst containing active components other than antimony. The antimony compound may be added during slurry preparation.
摘要翻译：本发明的目的是提供一种用于制备可在各种反应条件下获得的催化剂的简单方法，其允许甲基丙烯醛等的气相催化氧化以在延长的时间内以高产率，高选择性和稳定的甲基丙烯酸收率得到甲基丙烯酸。一种制造催化剂的方法，其中活性组分是包含钼，磷，钒，铯，锑和氨作为必要组分的杂多酸的部分中和盐，其中该方法的特征在于将锑化合物与催化剂中含有锑以外的活性成分的必需活性成分。可以在浆料制备过程中加入锑化合物。

42. 发明授权

US07432381B2 1,3-oxathiolane-2-thione compounds 失效
标题翻译： 1,3-氧硫杂环戊烷-2-硫酮化合物
公开(公告)号：US07432381B2
公开(公告)日：2008-10-07
申请号：US11354390
申请日：2006-02-15
申请人： Kazuya Uenishi , Atsushi Sudo , Hiroshi Morikawa , Takeshi Endo , Olaf Lammerschop , Thomas Huver , Pavel Gentschev
发明人： Kazuya Uenishi , Atsushi Sudo , Hiroshi Morikawa , Takeshi Endo , Olaf Lammerschop , Thomas Huver , Pavel Gentschev
IPC分类号： C07D327/04
CPC分类号： C08G77/28 , C07F7/1804 , C08G75/28
摘要： The present invention relates to 1,3-oxathiolane-2-thione compounds of the general formula (I): wherein R1 and R2 are the same or different, each of which denotes a straight-chain or branched alkoxy residue with 1 to 6 carbon atoms or an aryloxy or aralkyloxy residue, R3 is different or the same as R1 or R2 or an aliphatic residue, an amino residue, a halogen residue, an aromatic or heteroaromatic residue, or an araliphatic or heteroaraliphatic residue, R4 is a bridging group selected from the groups consisting of aliphatic, heteroaliphatic, araliphatic, heteroaraliphatic, aromatic and heteroaromatic groups and R5 is hydrogen, an aliphatic, heteroaliphatic, araliphatic, heteroaraliphatic, aromatic, heteroaromatic, cycloaliphatic or heterocycloaliphatic group or R4 and R5 form a cycloaliphatic, cycloheteroaliphatic, aromatic or heteroaromatic residue, which is optionally substituted with an aliphatic, heteroaliphatic residue serving as a bridging group to the silicon atom and X and Y are different and selected from oxygen and sulfur and mixtures of such compounds.
摘要翻译：本发明涉及通式（I）的1,3-氧硫杂环戊烷-2-硫酮化合物：其中R 1和R 2各自相同或不同，各自相同或不同，表示具有1至6个碳原子的直链或支链烷氧基残基或芳氧基或芳烷氧基残基，R 3不同于或不同于R 1或R 2 脂族残基，氨基残基，卤素残基，芳香族或杂芳族残基或芳脂族或杂脂族残基，R 4是选自以下的桥连基团：由脂族，杂脂族，芳脂族，杂脂肪族，芳族和杂芳族基团组成的基团，R 5是氢，脂族，杂脂族，芳脂族，杂脂族，芳族，杂芳族，脂环族或杂脂族基团或R 4和R 5形成脂环族，杂脂族，芳族或杂芳族残基，其任选被 n个作为与硅原子的桥连基团的脂族，杂脂族残基，X和Y不同，选自氧和硫以及这些化合物的混合物。

43. 发明申请

US20080003369A1 Low Shrinking Amine-Curing Epoxy Compositions 审中-公开
标题翻译：低收缩胺固化环氧组合物
公开(公告)号：US20080003369A1
公开(公告)日：2008-01-03
申请号：US11780170
申请日：2007-07-19
申请人： Kazuya Uenishi , Masashi Horikiri , Atsushi Sudo , Takeshi Endo
发明人： Kazuya Uenishi , Masashi Horikiri , Atsushi Sudo , Takeshi Endo
IPC分类号： C09J163/00 , B05D3/02
CPC分类号： C08L63/00 , C08G59/626 , C08K5/1545
摘要： The present invention relates to the use of one or more 6-membered lactones condensed to an aromatic or heteroaromatic moiety as shrinkage-suppressing agents in amine-curing epoxy compositions, such compositions and the use of such compositions in adhesives, sealants and coatings.
摘要翻译：本发明涉及一种或多种在芳族或杂芳族部分缩合的6-元内酯在胺固化环氧组合物中的收缩抑制剂的用途，以及这些组合物在粘合剂，密封剂和涂料中的用途。

44. 发明申请

US20050130057A1 Acid-degradable resin compositions containing ketene-aldehyde copolymer 有权
标题翻译：含有乙烯酮 - 醛共聚物的酸降解树脂组合物
公开(公告)号：US20050130057A1
公开(公告)日：2005-06-16
申请号：US10504496
申请日：2003-02-14
申请人： Atsushi Sudo , Hideo Kubo
发明人： Atsushi Sudo , Hideo Kubo
IPC分类号： C08G63/00 , C08G63/06 , C08K5/00 , C08K5/13 , C08K5/34 , G03F7/039 , G03C1/76
CPC分类号： C08K5/0025 , C08G63/005 , C08G63/06 , C08K5/0033 , C08K5/0041 , C08K5/13 , C08K5/34 , G03F7/0392 , C08L67/04 , C08L69/00
摘要： It is intended to provide compositions to be used in resists and the like for forming fine patterns with a high sensitivity and a high resolution by increasing the difference in the solubilities between exposed parts and unexposed parts. Acid-degradable compositions contain a polymer having a repeating unit represented by the following general formula (I): wherein R1 and R2 independently represent hydrogen atom, halogen atom, C1-20 hydrocarbon group, a heterocyclic group, a cyano group, a nitro group, C(═O)R4 group, S(O)nR4 group, P(═O)(R4)2 group or M(R4)3 group; R3 represents C1-20 hydrocarbon group or a heterocyclic group: R4 represents C1-20 hydrocarbonoxy group, C1-20 hydrocarbon group, C1-20 hydrocarbonthio group or mono- or di-C1-20 hydrocarbonamino group; M represents a silicon, germanium, tin or lead atom; and n is 0, 1 or 2, and an acid or a compound capable of generating an acid in response to an external stimulus.
摘要翻译：旨在提供用于抗蚀剂等的组合物，以通过增加曝光部分和未曝光部分之间的溶解度的差异来形成具有高灵敏度和高分辨率的精细图案。酸降解组合物含有具有由以下通式（I）表示的重复单元的聚合物：其中R 1和R 2独立地表示氢原子，卤素原子，C C 1-20烷基，杂环基，氰基，硝基，C（O）R 4基团，S（O） P（-O）（R 4）2基团或M（R 4）4个基团 >）<3> 组; R 3表示C 1-20烃基或杂环基：R 4表示C 1-20烃基氧基基团，C 1-20烃基，C 1-20烃基或单或二-C 1-20烃氨基; M表示硅，锗，锡或铅原子; 和n为0,1或2，以及能够响应外部刺激产生酸的酸或化合物。

45. 发明授权

US6028220A Producing acrolein and acrylic acid using a supported dual activity molybdenum, iron, and bismuth based catalyst in a fixed bed multitubular reactor 失效
标题翻译：在固定床多管反应器中使用支撑的双活性钼，铁和铋基催化剂生产丙烯醛和丙烯酸
公开(公告)号：US6028220A
公开(公告)日：2000-02-22
申请号：US117461
申请日：1998-07-28
申请人： Koichi Wada , Yoshimasa Seo , Akira Iwamoto , Atsushi Sudo , Fumio Sakai , Kazuo Shiraishi , Hiroyoshi Nowatari
发明人： Koichi Wada , Yoshimasa Seo , Akira Iwamoto , Atsushi Sudo , Fumio Sakai , Kazuo Shiraishi , Hiroyoshi Nowatari
IPC分类号： B01J23/88 , B01J8/06 , B01J23/31 , B01J23/887 , C07B61/00 , C07C27/14 , C07C45/35 , C07C47/22 , C07C51/25 , C07C57/05 , C07C205/00 , C07C51/16
CPC分类号： C07C45/35 , B01J23/002 , B01J23/31 , B01J23/8876 , B01J8/06 , C07C51/252 , B01J2208/025 , B01J2523/00
摘要： The present invention concerns a method for producing acrolein and acrylic acid by carrying out vapor phase catalytic oxidation of propylene with molecular oxygen or a gas containing molecular oxygen using a oxidation catalysts comprising Mo, Bi and Fe as an essentially element and a fixed bed multitubular reactor, which comprisesa) using a plurality of supported catalysts having different activities, which was obtained, for example, by different calcination method in the production process of the supported catalysts,b) setting a catalyst layer in a reaction tube, which is formed by dividing it into plural portions in the tube axial direction, andc) arranging the aforementioned plural supported catalysts in such order that the activity becomes high toward the outlet from the inlet of the material gas in the reaction tube axial direction.According to the present invention, the generation of hot spot can be avoided and over oxidation reaction can be avoided and the acrolein and acrylic acid are produced constantly for a prolonged period of time.
摘要翻译： PCT No.PCT / JP97 / 04402 Sec。 371日期：1998年7月28日 102（e）日期1998年7月28日PCT 1997年12月2日PCT PCT。第WO98 / 24746号公报日期1998年6月11日本发明涉及通过使用包含Mo，Bi和Fe作为基本元素的氧化催化剂，通过用分子氧或含有分子氧的气体进行丙烯的气相催化氧化来生产丙烯醛和丙烯酸的方法，一种固定床多管反应器，其包括a）使用多种活性不同的负载催化剂，其通过例如在负载型催化剂的制备方法中通过不同的煅烧方法获得，b）将催化剂层设置在反应管通过在管轴方向上分成多个部分而形成，以及c）按照反应管轴向从原料气体的入口出口的活性变高的顺序排列上述多个负载型催化剂。根据本发明，可以避免产生热点，可以避免过度氧化反应，并且持续长时间地生产丙烯醛和丙烯酸。

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