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41. 发明授权

US4308412A Indane alkanols and tricyclic isochromans and organoleptic uses thereof 失效
标题翻译：茚烷醇和三环异染料及其感官用途
公开(公告)号：US4308412A
公开(公告)日：1981-12-29
申请号：US212992
申请日：1980-12-04
申请人： Wilhelmus J. Wiegers , Mark A. Sprecker , Hugh Watkins , Manfred H. Vock , Frederick L. Schmitt
发明人： Wilhelmus J. Wiegers , Mark A. Sprecker , Hugh Watkins , Manfred H. Vock , Frederick L. Schmitt
IPC分类号： C07C2/42 , C07C29/36 , C07C33/34 , C07D311/94 , C11B9/00 , C07C3/00
CPC分类号： C11B9/008 , C07C2/42 , C07C29/36 , C07C33/34 , C07D311/94 , C07C2102/08 , C07C2521/16 , C07C2531/08
摘要： Processes and compositions are described for the use in foodstuff flavor and aroma and perfume and perfumed article aroma augmenting, modifying, altering and enhancing compositions and as foodstuff, chewing gum, toothpaste, medicinal product, perfume and perfumed article aroma imparting materials of certain indane alkanols and tricyclic isochromans defined according to the generic structure: ##STR1## wherein one of R.sub.1, R.sub.2, R.sub.3 or R.sub.4 is C.sub.2 H.sub.5 and the remaining R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents methyl; wherein X is --CH.sub.2 -- or hydrogen and wherein the dashed line represents a carbon-carbon single bond or no bond with the proviso that when X is --CH.sub.2 --, then the dashed line is a carbon-carbon single bond and when X is hydrogen, the dashed line represents no bond.Addition of said indane alkanols or said tricyclic isochromans or mixtures thereof is indicated to produce:A. In food flavorings, a sweet, musky, patchouli-like, and ionone-like aroma and flavor characteristic; (useful for flavor augmentation or enhancement in pear, apricot and peach flavors);B. In perfumes and perfumed articles, a sweet, musky aroma with earthy, minty and sweet nuances.
摘要翻译：描述了用于食品香料和香料和香料和香料制品香气增强，改性，改变和增强组合物以及作为食品，口香糖，牙膏，药用产品，香料和香料制品中某些二烷基链烷醇的赋香材料的方法和组合物和根据通用结构定义的三环异染料：其中R 1，R 2，R 3或R 4中的一个为C 2 H 5，剩余的R 1，R 2，R 3和R 4表示甲基; 其中X是-CH 2 - 或氢，并且其中虚线表示碳 - 碳单键或没有键，条件是当X是-CH 2 - 时，虚线是碳 - 碳单键，当X是氢时，虚线表示没有键。表示添加所述二氢化茚烷醇或所述三环异色素或其混合物以产生：A.在食品调味品中，甜味，麝香，广藿香样和紫罗兰酮样芳香和风味特征; （用于梨，杏和桃味的增味或增强）; B.在香水和香水制品中，甜美，麝香的香气与土质，微小和甜美的细微差别。

42. 发明授权

US4293453A Process for using bridged ketones in augmenting or enhancing the organoleptic properties of consumable materials 失效
标题翻译：使用桥连酮增强或增强消耗材料的感官特性的方法
公开(公告)号：US4293453A
公开(公告)日：1981-10-06
申请号：US200060
申请日：1980-10-23
申请人： Mark A. Sprecker , James M. Sanders , William L. Schreiber , Hugh Watkins , Joaquin F. Vinals , Edward J. Shuster , Thomas J. O'Rourke , Myrna L. Hagedorn , Philip Klemarczyk
发明人： Mark A. Sprecker , James M. Sanders , William L. Schreiber , Hugh Watkins , Joaquin F. Vinals , Edward J. Shuster , Thomas J. O'Rourke , Myrna L. Hagedorn , Philip Klemarczyk
IPC分类号： A24B15/30 , A24B15/34 , C07C45/00 , C07C45/67 , C07C47/445 , C07C49/453 , C11B9/00 , C11D3/50 , D06M13/00 , C07C13/30
CPC分类号： D06M13/005 , A24B15/30 , A24B15/345 , C07C403/02 , C07C45/00 , C07C45/67 , C07C47/445 , C07C49/453 , C11B9/0042 , C11D3/50 , C07C2101/16 , C07C2103/66
摘要： Described are compounds covered by the generic structure: ##STR1## where one, two or all of R.sub.1, R.sub.2 and R.sub.3 are the same or different and each represents hydrogen or lower alkyl of from 1 up to 3 carbon atoms; a process for preparing same using compounds having the generic structure: ##STR2## where one of the dashed lines is a carbon-carbon double bond and the other of the dashed lines represents carbon-carbon single bonds and organoleptic uses thereof in perfumes, colognes, perfumed articles such as anionic, cationic and non-ionic detergents, cosmetic powders and dryer-added fabric softener articles, as well as in smoking tobaccos and smoking tobacco articles, e.g., the body of smoking tobacco, the wrapper or the filter therefor. Thus, the tricyclic ketone compounds of our invention, having the generic structure: ##STR3## impart, augment or enhance low-keyed oily, woody, amber, leathery, warm spice, earthy camphoraceous, patchouli-like, balsamic-like, green, cardamom-like, vetiver-like, sweet woody or minty nuances in or to perfumed compositions or perfumed articles or colognes. The tricyclic ketones of our invention further augment, enhance or impart sweet, floral, woody, spicy, leathery and amber aroma nuances to smoking tobacco prior to smoking and sweet aromas with natural tobacco taste and aroma nuances on smoking in the main stream and in the side stream.
摘要翻译：描述的是由通式结构覆盖的化合物：其中R 1，R 2和R 3中的一个，两个或全部相同或不同并且各自表示氢或1至3个碳原子的低级烷基; 使用具有以下通用结构的化合物制备方法：其中虚线中的一条是碳 - 碳双键，虚线中的另一条代表香料，古龙水，香水等中的碳 - 碳单键和感官用途，加香制品如阴离子，阳离子和非离子洗涤剂，化妆品粉末和干燥剂添加织物柔软剂制品，以及吸烟烟草和烟草制品，例如吸烟烟草，包装物或其过滤器。因此，本发明的三环酮化合物具有通用结构：赋予，增强或增强低调油性，木质，琥珀色，革质，温香料，樟脑酸，广藿香样，香脂状，绿色，香草类似，香甜的，甜的木质或细小的或在加香的组合物或香水制品或古龙水中的细微差别。本发明的三环酮在吸烟之前进一步增强，增强或赋予吸烟烟草中甜，香，木质，辛辣，革质和琥珀香气的细微差别，并且具有天然烟草味道和香味在主流和吸烟中的细微差别侧流。

43. 发明授权

US4287081A Bridged ketones, process for preparing same and use thereof in augmenting or enhancing the organoleptic properties of consumable materials 失效
标题翻译：桥接酮，其制备方法及其在增加或增强消耗材料的感官特性中的用途
公开(公告)号：US4287081A
公开(公告)日：1981-09-01
申请号：US200024
申请日：1980-10-23
申请人： Mark A. Sprecker , James M. Sanders , William L. Schreiber , Hugh Watkins , Joaquin F. Vinals , Edward J. Shuster , Thomas J. O'Rourke , Myrna L. Hagedorn , Philip Klemarczyk
发明人： Mark A. Sprecker , James M. Sanders , William L. Schreiber , Hugh Watkins , Joaquin F. Vinals , Edward J. Shuster , Thomas J. O'Rourke , Myrna L. Hagedorn , Philip Klemarczyk
IPC分类号： A24B15/30 , A24B15/34 , C07C45/00 , C07C45/67 , C07C47/445 , C07C49/453 , C11B9/00 , C11D3/50 , D06M13/00 , C11D9/44
CPC分类号： D06M13/005 , A24B15/30 , A24B15/345 , C07C403/02 , C07C45/00 , C07C45/67 , C07C47/445 , C07C49/453 , C11B9/0042 , C11D3/50 , C07C2101/16 , C07C2103/66
摘要： Described is a process for augmenting or enhancing the aroma of a solid or liquid anionic, cationic or nonionic detergent comprising the step of adding in an aroma augmenting or enhancing quantity to a solid or liquid anionic, cationic or nonionic detergent base at least one tricyclic ketone having the structure: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are the same or different and each represents hydrogen or C.sub.1 --C.sub.3 lower alkyl.
摘要翻译：描述了用于增强或增强固体或液体阴离子，阳离子或非离子洗涤剂的香味的方法，其包括将芳香增加或增加量添加到固体或液体阴离子，阳离子或非离子洗涤剂基质的步骤，至少一种三环酮具有以下结构：其中R 1，R 2和R 3相同或不同，各自表示氢或C 1 -C 3低级烷基。

44. 发明授权

US4250338A Bridged ketones and process for preparing same 失效
标题翻译：桥接酮及其制备方法
公开(公告)号：US4250338A
公开(公告)日：1981-02-10
申请号：US95149
申请日：1979-11-16
申请人： Mark A. Sprecker , James M. Sanders , William L. Schreiber , Hugh Watkins , Joaquin F. Vinals , Edward J. Shuster , Thomas J. O'Rourke , Myrna L. Hagedorn , Philip Klemarczyk
发明人： Mark A. Sprecker , James M. Sanders , William L. Schreiber , Hugh Watkins , Joaquin F. Vinals , Edward J. Shuster , Thomas J. O'Rourke , Myrna L. Hagedorn , Philip Klemarczyk
IPC分类号： A24B15/30 , A24B15/34 , C07C45/00 , C07C45/67 , C07C47/445 , C07C49/453 , C11B9/00 , C11D3/50 , D06M13/00
CPC分类号： D06M13/005 , A24B15/30 , A24B15/345 , C07C403/02 , C07C45/00 , C07C45/67 , C07C47/445 , C07C49/453 , C11B9/0042 , C11D3/50 , C07C2101/16 , C07C2103/66
摘要： Described are compounds covered by the generic structure; ##STR1## where one, two or all of R.sub.1, R.sub.2 and R.sub.3 are the same or different and each represents hydrogen or lower alkyl of from 1 up to 3 carbon atoms; a process for preparing same using compounds having the generic structure; ##STR2## where one of the dashed lines is a carbon-carbon double bond and the other of the dashed lines represents carbon-carbon single bonds and organoleptic uses thereof in perfumes, colognes, perfumed articles such as anionic, cationic and non-ionic detergents, cosmetic powders and dryer-added fabric softener articles, as well as in smoking tobaccos and smoking tobacco articles, e.g., the body of smoking tobacco, the wrapper or the filter therefor. Thus, the tricyclic ketone compounds of our invention, having the generic structure: ##STR3## impart, augment or enhance low-keyed oily, woody, amber, leathery, warm spice, earthy camphoraceous, patchouli-like, balsamic-like, green, cardamom-like, vetiver-like, sweet woody or minty nuances in or to perfumed compositions or perfumed articles or colognes. The tricyclic ketones of our invention further augment, enhance or impart sweet, floral, woody, spicy, leathery and amber aroma nuances to smoking tobacco prior to smoking and sweet aromas with natural tobacco taste and aroma nuances on smoking in the main stream and in the side stream.
摘要翻译：描述的是通用结构覆盖的化合物; 其中R1，R2和R3中的一个，两个或全部相同或不同，并且各自表示氢或1至3个碳原子的低级烷基; 使用具有通式结构的化合物制备方法; 其中虚线之一是碳 - 碳双键，虚线中的另一条代表香烟，古龙水，香料制品如阴离子，阳离子和非离子洗涤剂中的碳 - 碳单键和感官用途，化妆品粉末和干燥剂添加的织物柔软剂制品，以及吸烟烟草和烟草制品，例如吸烟烟草，包装物或其过滤器。因此，本发明的三环酮化合物具有通用结构：赋予，增强或增强低调油性，木质，琥珀色，革质，温香料，樟脑酸，广藿香样，香脂状，绿色，香草类似，香甜的，甜的木质或细小的或在加香的组合物或香水制品或古龙水中的细微差别。本发明的三环酮在吸烟之前进一步增强，增强或赋予吸烟烟草中甜，香，木质，辛辣，革质和琥珀香气的细微差别，并且具有天然烟草味道和香味在主流和吸烟中的细微差别侧流。

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