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    • 41. 发明申请
    • GAS SENSOR
    • 气体传感器
    • US20110226618A1
    • 2011-09-22
    • US13043888
    • 2011-03-09
    • Hiroki FujitaSumiko HorisakaMika MurakamiTakashi Ito
    • Hiroki FujitaSumiko HorisakaMika MurakamiTakashi Ito
    • G01N27/30
    • G01N27/41G01N27/4071G01N27/4072G01N27/4074G01N27/417G01N27/419
    • A gas sensor including an internal space, a first electrode, a second electrode, a pumping cell, a third electrode, a fourth electrode, a measuring cell, and a porous diffusion layer. The first and third electrodes, and the second and fourth electrodes are formed inside and outside the internal space, respectively. The pumping cell includes the first and second electrodes, and the measuring cell includes the third and fourth electrodes. The pumping cell pumps oxygen from the internal space when a predetermined voltage is applied between the first and second electrodes. The third electrode reduces an oxide gas component in a predetermined gas component to which a predetermined diffusion resistance has been applied by the porous diffusion layer. The measuring cell measures current flow between the third and fourth electrodes when a voltage corresponding to the degree of reduction in the third electrode is applied between the third and fourth electrodes.
    • 一种气体传感器,包括内部空间,第一电极,第二电极,泵浦单元,第三电极,第四电极,测量单元和多孔扩散层。 第一和第三电极以及第二和第四电极分别形成在内部空间内部和外部。 泵浦单元包括第一和第二电极,测量单元包括第三和第四电极。 当在第一和第二电极之间施加预定电压时,泵送单元从内部空间泵送氧气。 第三电极通过多孔扩散层减少预定的扩散电阻施加到预定的气体成分中的氧化物气体成分。 当在第三和第四电极之间施加与第三电极的减小程度相对应的电压时,测量单元测量第三和第四电极之间的电流。
    • 42. 发明申请
    • GAS SENSOR AND METHOD FOR MANUFACTURING SAME
    • 气体传感器及其制造方法
    • US20110186431A1
    • 2011-08-04
    • US13013094
    • 2011-01-25
    • Sumiko HORISAKAHiroki FujitaMika MurakamiTakashi Ito
    • Sumiko HORISAKAHiroki FujitaMika MurakamiTakashi Ito
    • G01N27/30C03B29/00
    • G01N27/4077G01N27/4075G01N33/0037Y02A50/245
    • A NOx sensor 100 includes a sensor device 110 and a heater 70 capable of heating the sensor device 110. The sensor device 110 includes an inner pump electrode 22 and an outer pump electrode 23 disposed respectively on the inner side and the outer side of a solid electrolyte layer 6. The sensor device 110 detects the concentration of NOx by introducing a gas to be measured into a first inner vacancy 20, pumping out oxygen in the gas to be measured from the inner pump electrode 22 to the outer pump electrode 23, introducing the gas to be measured, from which the oxygen has been pumped out, into a second inner vacancy 40, reducing the NOx in the gas to be measured, to thereby generate oxygen, and detecting the generated oxygen. A characteristic stabilizing layer 24 covers the outer pump electrode 23 and is made of a porous body with a thickness of 10 to 200 μm and a thickness variation of 20% or less.
    • NOx传感器100包括能够加热传感器装置110的传感器装置110和加热器70.传感器装置110包括分别设置在固体的内侧和外侧的内泵电极22和外泵电极23 电解质层6.传感器装置110通过将待测量的气体引入第一内部空间20来检测NOx的浓度,从内部泵电极22向外部泵电极23抽出待测量的气体中的氧气,引入 待被测量的气体已被排出氧气,进入第二内部空位40,减少要测量的气体中的NOx,从而产生氧气,并检测所产生的氧气。 特性稳定层24覆盖外泵电极23,由厚度为10〜200μm,厚度变化为20%以下的多孔体构成。
    • 45. 发明授权
    • Gas sensor
    • 气体传感器
    • US06337009B1
    • 2002-01-08
    • US09523198
    • 2000-03-10
    • Norihiko NadanamiTakafumi OshimaHiroki FujitaRyuji Inoue
    • Norihiko NadanamiTakafumi OshimaHiroki FujitaRyuji Inoue
    • G01N27407
    • G01N27/4074G01N33/005
    • A gas sensor comprising a proton-conductive layer 5 formed of a polymer electrolyte; first and second electrodes 3 and 4 disposed in contact with the proton-conductive layer 5 and having a function of dissociating hydrogen; a gas-diffusion-rate limiting layer 2 disposed between a measurement gas atmosphere and the first electrode 3 and adapted to diffuse the gas under measurement to the first electrode 3 in a diffusion-rate limited state; and a dense support 1 supporting these elements. Hydrogen gas having reached the first electrode 3 via the gas-diffusion-rate limiting layer 2 is dissociated into protons by virtue of the catalytic action of Pt contained in the electrode and the voltage applied to the first electrode 3, and the generated protons are pumped to the second electrode 4 via the proton-conductive layer 5 and are converted to hydrogen gas, which diffuses into the measurement gas atmosphere. When the applied voltage is sufficiently high, saturation current flows between the first and second electrodes 3 and 4, and the magnitude of the saturation current varies in proportion to the hydrogen gas concentration of the gas under measurement. A hydrogen gas sensor which operates at low temperature in a hydrogen-rich atmosphere, and which can accurately measure hydrogen gas concentration of a fuel gas of a fuel cell, is thereby provided.
    • 一种气体传感器,包括由聚合物电解质形成的质子传导层5; 设置成与质子传导层5接触并具有解离氢的功能的第一和第二电极3和4; 设置在测量气体气氛和第一电极3之间并适于以扩散速率限制状态将测量中的气体扩散到第一电极3的气体扩散限制层2; 以及支撑这些元件的致密支撑件1。 通过气体扩散限制层2到达第一电极3的氢气由于电极中包含的Pt的催化作用和施加到第一电极3的电压而被解离成质子,所产生的质子被泵送 通过质子传导层5向第二电极4转移,并将其转化为扩散到测量气体气氛中的氢气。 当施加的电压足够高时,在第一和第二电极3和4之间流过饱和电流,并且饱和电流的大小与被测气体的氢气浓度成比例地变化。 由此,能够在富氢气氛中在低温下工作,能够精确地测定燃料电池的燃料气体的氢气浓度的氢气传感器。