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41. 发明授权

US5177273A Process for the manufacture of halogen-substituted propanes containing hydrogen and at least five fluorine substituents 失效
标题翻译：制备含氢氢原子和至少五氟代替替代物的卤素取代的丙烷的方法
公开(公告)号：US5177273A
公开(公告)日：1993-01-05
申请号：US648947
申请日：1991-02-01
申请人： Douglas W. Bruhnke , Jan J. Lerou , V. N. Mallikarjuna Rao , William C. Seidel , Frank J. Weigert
发明人： Douglas W. Bruhnke , Jan J. Lerou , V. N. Mallikarjuna Rao , William C. Seidel , Frank J. Weigert
IPC分类号： B01J23/26 , C07B61/00 , C07C17/06 , C07C17/08 , C07C17/10 , C07C19/08
CPC分类号： C07C17/10 , C07C17/06
摘要： A vapor phase process is disclosed for producing HCFC-225s, HCFC-235s, HCFC-226s, HFC-236s, and HFC-227s by reacting certain three-carbon reactants containing at least one less fluorine than, and at least as many hydrogen substituents as the desired product (e.g. propane propylene, allene or methylacetylene) with Cl.sub.2 and HF in the presence of a catalyst consisting essentially of chromium oxide or of chromium oxide which is combined with a refractory oxide, fluorinated and/or modified with manganese, iron, cobalt, nickel, copper and/or zinc. The temperature and contact time for the reaction are chosen to provide a product having the desired fluorine and hydrogen content.
摘要翻译：公开了一种用于生产HCFC-225s，HCFC-235s，HCFC-226s，HFC-236s和HFC-227s的气相方法，其通过使某些含有至少少于一个氟的至少一个或多个氢取代基的三碳反应物作为所需产物（例如丙烷丙烯，丙烯或甲基乙炔）与Cl 2和HF在主要由氧化铬或氧化铬组成的催化剂存在下存在下，该催化剂与难熔氧化物结合，氟化和/或用锰，铁，钴，镍，铜和/或锌。选择反应的温度和接触时间以提供具有所需氟和氢含量的产物。

42. 发明授权

US5008475A Gas-phase fluorination process 失效
标题翻译：气相氟化工艺
公开(公告)号：US5008475A
公开(公告)日：1991-04-16
申请号：US465402
申请日：1990-01-16
申请人： Leo E. Manzer , V. N. Mallikarjuna Rao
发明人： Leo E. Manzer , V. N. Mallikarjuna Rao
IPC分类号： C07C17/087 , C07C17/21
CPC分类号： C07C17/087 , C07C17/21
摘要： An improved gas-phase process for the manufacture of 1,1,1-trifluorodichloroethane and/or 1,1,1,2-tetrafluorochloroethane by contacting a suitable tetrahaloethylene with hydrogen fluoride in the presence of a selected metal in combination with a high fluorine content aluminum-containing compound, the reaction being conducted under controlled conditions whereby the production of pentafluoroethane is minimized.
摘要翻译：在选择的金属与高氟化合物的存在下，通过使合适的四卤乙烯与氟化氢接触来制备1,1,1-三氟二氯乙烷和/或1,1,1,2-四氟氯乙烷的改进的气相方法含量的含铝化合物，反应在控制条件下进行，五氟乙烷的生产最小化。

43. 发明授权

US4843181A Process for the manufacture of 1,1,1-trifluorodichloroethane and 1,1,1,2-tetrafluorochloroethane 失效
标题翻译：制备1,1,1-三氟二氯乙烷和1,1,1,2-四氟氯乙烷的方法
公开(公告)号：US4843181A
公开(公告)日：1989-06-27
申请号：US111292
申请日：1987-10-22
申请人： William H. Gumprecht , Leo E. Manzer , V. N. Mallikarjuna Rao
发明人： William H. Gumprecht , Leo E. Manzer , V. N. Mallikarjuna Rao
IPC分类号： C07B61/00 , B01J23/26 , C07C17/00 , C07C17/08 , C07C17/087 , C07C17/20 , C07C17/21 , C07C19/08 , C07C19/12 , C07C67/00
CPC分类号： C07C17/087 , C07C17/21
摘要： An improved gas-phase process for the manufacture of 1,1,1-trifluorodichloroethane and/or 1,1,1,2-tetrafluorochloroethane by contacting a suitable tetrahaloethylene and/or pentahaloethane with hydrogen fluoride in the presence of Cr.sub.2 O.sub.3, prepared by pyrolysis of (NH.sub.4).sub.2 Cr.sub.2 O.sub.7, the reaction being conducted under controlled conditions whereby the production of pentafluoroethane is minimized.

44. 发明授权

US4766259A Gas-phase fluorination process 失效
标题翻译：气相氟化工艺
公开(公告)号：US4766259A
公开(公告)日：1988-08-23
申请号：US85027
申请日：1987-08-13
申请人： Leo E. Manzer , V. N. Mallikarjuna Rao
发明人： Leo E. Manzer , V. N. Mallikarjuna Rao
IPC分类号： C07C17/087 , C07C17/21 , C07C17/04 , C07C17/20 , C07C19/02 , C07C19/08
CPC分类号： C07C17/087 , C07C17/21
摘要： An improved gas-phase process for the manufacture of 1,1-difluoro-1,2-dichloroethane and 1-fluoro-1,1,2-trichloroethane by contacting a suitable trihaloethylene and/or a tetrahaloethane with hydrogen fluoride in the presence of a metal in combination with a high fluorine content alumina, the reaction being preferably conducted under controlled conditions whereby the production of 1,1,1-trifluorochloroethane is minimized.
摘要翻译：通过在合适的三卤代乙烯和/或四卤乙烷与氟化氢的存在下接触，制备1,1-二氟-1,2-二氯乙烷和1-氟-1,1,2-三氯乙烷的改进的气相方法与高氟含量的氧化铝组合的金属，该反应优选在控制条件下进行，由此使1,1,1-三氟氯乙烷的生成最小化。

45. 发明授权

US06762333B1 Process for reducing the fluorine content of hydrofluorocarbons and hydrohalofluorocarbons 失效
标题翻译：减少氢氟碳化合物和氢卤氟烃氟含量的方法
公开(公告)号：US06762333B1
公开(公告)日：2004-07-13
申请号：US08460023
申请日：1995-06-02
申请人： Leo Ernest Manzer , V. N. Mallikarjuna Rao , Steven Henry Swearingen
发明人： Leo Ernest Manzer , V. N. Mallikarjuna Rao , Steven Henry Swearingen
IPC分类号： C07C2513
CPC分类号： C07C17/21 , C07C17/00 , C07C17/206 , C07C21/12
摘要： The fluorine content of an acyclic saturated compound of the formula CnFaXbHc (wherein each X is independently selected from the group consisting of Cl and Br, and wherein n is 1 to 6, a is 1 to 13, b is 0 to 12, c is 1 to 9, and a+b+c equals 2n+2) is reduced by reacting the acyclic saturated compound with HCl in the vapor phase at an elevated temperature in the presence of a catalyst, the mole ratio of HCl to the acyclic saturated compound being at least about 1:1.
摘要翻译：式CnFaXbHc的无环饱和化合物的氟含量（其中X各自独立地选自Cl和Br，n为1至6，a为1至13，b为0至12，c为 1〜9，a + b + c等于2n + 2）通过在催化剂存在下，在高温下在气相中使无环饱和化合物与HCl反应，HCl与无环饱和化合物的摩尔比至少约1：1。

46. 发明授权

US6165931A Catalytic hydrofluorination processes and catalysts 失效
标题翻译：催化氢氟化方法和催化剂
公开(公告)号：US6165931A
公开(公告)日：2000-12-26
申请号：US825173
申请日：1997-04-11
申请人： V. N. Mallikarjuna Rao
发明人： V. N. Mallikarjuna Rao
IPC分类号： B01J21/10 , B01J23/06 , B01J23/10 , B01J23/26 , B01J23/75 , B01J23/755 , B01J27/12 , B01J37/03 , B01J37/26 , C07C17/20 , B01J27/08 , B01J27/128 , B01J27/138
CPC分类号： C07C17/206 , B01J21/10 , B01J23/06 , B01J23/10 , B01J23/26 , B01J23/75 , B01J23/755 , B01J27/12 , B01J37/03 , B01J37/26 , C07C19/10 , C07C19/08 , C07C19/12
摘要： A process is disclosed for increasing the fluorine content of a saturated or olefinic halogenated hydrocarbon starting material of the formula C.sub.n H.sub.a Cl.sub.b F.sub.c, wherein n is an integer from 1 to 6, a is an integer from 0 to to 12, b is an integer from 0 to 13 and c is an integer from 0 to 13. The process involves contacting the starting material in the vapor phase at a temperature in the range of about 150.degree. C. to about 500.degree. C. with HF and a catalytic metal supported on a trivalent lanthanum compound support (the catalytic metal being chromium, cobalt, nickel, zinc, magnesium, copper, silver and/or gold). Certain catalytic compositions including catalytic metal (e.g., chromium, nickel, cobalt, zinc and/or magnesium) supported on a support at trivalent lanthanum compound containing fluoride anion are also disclosed. The atomic ratio of catalytic metal to lanthanum in the compositions is from about 1:1 to 1:999.
摘要翻译：公开了一种用于提高式CnHaClbFc的饱和或烯烃卤代烃起始物质的氟含量的方法，其中n为1至6的整数，a为0至12的整数，b为0至 13和c是0至13的整数。该方法包括使气相中的原料在约150℃至约500℃的温度下与HF和负载在三价的催化金属镧化合物载体（催化金属为铬，钴，镍，锌，镁，铜，银和/或金）。还公开了一些催化组合物，包括负载在含有氟阴离子的三价镧化合物的载体上的催化金属（例如铬，镍，钴，锌和/或镁）。组合物中催化金属与镧的原子比为约1:1至1:9999。

47. 发明授权

US6040486A Process for the manufacture of 2-chloro-1,1,1-trifluoroethane 失效
标题翻译： 2-氯-1,1,1-三氟乙烷的制备方法
公开(公告)号：US6040486A
公开(公告)日：2000-03-21
申请号：US167656
申请日：1993-12-20
申请人： David Richard Corbin , V. N. Mallikarjuna Rao
发明人： David Richard Corbin , V. N. Mallikarjuna Rao
IPC分类号： B01J27/138 , B01J23/06 , B01J27/12 , B01J27/125 , C07B61/00 , C07C17/08 , C07C17/087 , C07C17/20 , C07C17/21
CPC分类号： C07C17/087 , B01J23/06 , B01J27/12 , B01J27/125 , C07C17/21
摘要： A process is disclosed for producing HCFC-133a which includes reacting certain trihaloethene starting materials (e.g., trichloroethene) with HF in the gaseous phase at an elevated temperature in the presence of certain supported metal catalysts containing effective amounts of zinc. A catalyst of metal fluoride on a fluorinated alumina support having an atomic ratio of F to Al of at least 2.7:1 and containing .beta.-aluminum fluoride, is employed.
摘要翻译：公开了用于生产HCFC-133a的方法，其包括在含有有效量的锌的某些负载型金属催化剂的存在下，在高温下使某些三卤乙烯原料（例如三氯乙烯）与HF在气相中反应。使用原子比为F至Al至少为2.7:1且含有β-氟化铝的氟化氧化铝载体上的金属氟化物的催化剂。

48. 发明授权

US5866730A Process for enriching 1,2-dichloro-1,1,2,2-tetrafluoroethane from a mixture of dichlorotetrafluoroethane isomers 失效
标题翻译：从二氯四氟乙烷异构体的混合物中富集1,2-二氯-1,1,2,2-四氟乙烷的方法
公开(公告)号：US5866730A
公开(公告)日：1999-02-02
申请号：US42200
申请日：1993-04-02
申请人： V. N. Mallikarjuna Rao
发明人： V. N. Mallikarjuna Rao
IPC分类号： C07C17/395 , C07C17/38
CPC分类号： C07C17/395
摘要： A process is disclosed for enriching the amount of CFC-114 relative to the amount of CFC-114a from an initial mixture containing both isomers, by contacting said initial mixture with hydrogen chloride in the vapor phase at an elevated temperature in the presence of a catalyst to produce a product mixture containing C.sub.2 Cl.sub.2 F.sub.3 and chlorination products of CCl.sub.2 FCF.sub.3 wherein the weight ratio of CClF.sub.2 CClF.sub.2 to the total C.sub.2 Cl.sub.2 F.sub.4 is higher than the weight ratio of CClF.sub.2 CClF.sub.2 to the total C.sub.2 Cl.sub.2 F.sub.4 in the initial mixture. The chlorination products of CFC-114a (e.g., CCl.sub.3 CF.sub.3) in the product mixture may then be separated from the C.sub.2 Cl.sub.2 F.sub.4 therein (e.g., by distillation).
摘要翻译：公开了一种用于从含有两种异构体的初始混合物中相对于CFC-114a量相对于CFC-114a的量富集的方法，通过在催化剂存在下，在升高的温度下将所述初始混合物与气相中的氯化氢接触以产生含有C2Cl2F3和CCl2FCF3的氯化产物的产物混合物，其中CClF 2 CClF 2与总C 2 Cl 2 F 4的重量比高于初始混合物中CClF 2 CClF 2与总C 2 Cl 2 F 4的重量比。然后可以将产物混合物中的CFC-114a（例如CCl 3 CF 3）的氯化产物从其中的C2Cl2F4（例如通过蒸馏）分离。

49. 发明授权

US5773637A Perfluoroalkyl sulfonates, their preparation and use 失效
标题翻译：全氟烷基磺酸盐，其制备和用途
公开(公告)号：US5773637A
公开(公告)日：1998-06-30
申请号：US708997
申请日：1996-09-06
申请人： Walter Vladimir Cicha , Andreas Josef Kornath , Ronald James McKinney , V. N. Mallikarjuna Rao , Joseph Stuart Thrasher , Alfred Waterfeld
发明人： Walter Vladimir Cicha , Andreas Josef Kornath , Ronald James McKinney , V. N. Mallikarjuna Rao , Joseph Stuart Thrasher , Alfred Waterfeld
IPC分类号： C07F5/00 , C07F7/00 , C07F9/00 , C07F9/68 , C07F9/90 , C07F9/94 , C07F11/00 , C07F9/70 , C07F7/22
CPC分类号： C07F5/003 , C07F11/005 , C07F7/006 , C07F9/005 , C07F9/68 , C07F9/902 , C07F9/94
摘要： A process is disclosed for preparing a perfluoroalkyl sulfonate of the formula R.sub.a MX.sub.b-c O.sub.g �(SO.sub.3).sub.d (R.sub.f).sub.e !.sub.c. This process involves reacting a reagent of the fonnula R.sub.a MX.sub.b O.sub.g and a second reagent of the formula R'.sub.x E�(SO.sub.3).sub.d (R.sub.f).sub.e !.sub.y, where R is selected from the group consisting of C.sub.1 to C.sub.6 alkyl, C.sub.1 to C.sub.6 perfluoroalkyl, cyclopentadienyl (i.e., C.sub.5 H.sub.5), phenyl and perfluorophenyl; M is selected from the group consisting of transistion metals of groups 3 to 12, main group elements of group 13 to 16 and lanthanide metals; X is selected from the group consisting of F, Cl and Br; R.sub.f is selected from the group consisting of C.sub.h F.sub.2h+1, C.sub.h F.sub.2h, wherein h is an integer from 0 to 10, perfluorophenyl, C.sub.6 F.sub.4 (CF.sub.2).sub.2 i, wherein i is an integer from 0 to 6, provided that when E is boron, R.sub.f is selected from the group consisting of C.sub.h' F.sub.2h'+1, wherein h' is an integer from 1 to 10, perfluorophenyl; R' is selected from the group consisting of C.sub.j H.sub.2j+1, wherein j is an integer from 1 to 4, and phenyl; E is selected from the group consisting of B and Si; a is an integer from 0 to 3; b is an integer from 2 to 6; c is an integer from 1 to 6; d is an integer from 1 to 3; e is an integer from 1 to 4; g is an integer from 0 to 1; x is an integer from 0 to 3; and y is an integer from 1 to 3. Novel perfluoroalkyl sulfonates are provided, as are methods which employ perfluoroalkyl sulfonates as catalysts for increasing the fluorine content of halogenated hydrocarbons and as promoters for hydrocyanation of olefins.
摘要翻译：公开了制备式RaMXb-cOg [（SO3）d（Rf）e] c的全氟烷基磺酸盐的方法。该方法包括使得式IaMXbOg的试剂与式R'xE [（SO3）d（Rf）e] y的第二试剂反应，其中R选自C1至C6烷基，C1至C6全氟烷基，环戊二烯基（即C 5 H 5），苯基和全氟苯基; M选自组3至12的交联金属，第13至16族的主要元素和镧系金属; X选自F，Cl和Br; Rf选自ChF2h + 1，ChF2h，其中h为0至10的整数，全氟苯基，C6F4（CF2）2i，其中i为0至6的整数，条件是当E为硼时，Rf 选自Ch'F2h'+ 1，其中h'是1至10的整数，全氟苯基; R'选自CjH2j + 1，其中j是1至4的整数，和苯基; E选自B和Si; a是从0到3的整数; b是2至6的整数; c是1至6的整数; d为1〜3的整数; e是1至4的整数; g是0到1的整数; x是0到3的整数; y是1至3的整数。提供新的全氟烷基磺酸盐，使用全氟烷基磺酸盐作为用于增加卤代烃的氟含量的催化剂和作为烯烃氢化氰化促进剂的方法。

50. 发明授权

US5430204A Halocarbon hydrogenolysis 失效
标题翻译：卤烃氢解
公开(公告)号：US5430204A
公开(公告)日：1995-07-04
申请号：US242503
申请日：1994-05-13
申请人： William H. Manogue , V. N. Mallikarjuna Rao
发明人： William H. Manogue , V. N. Mallikarjuna Rao
IPC分类号： C07C17/23 , C07C19/08
CPC分类号： C07C17/23
摘要： Halocarbons such as CCl.sub.2 F.sub.2, CF.sub.3 CFHCl or CF.sub.3 CFCl.sub.2 which contain chlorine and/or bromine are contacted with hydrogen in the presence of silicon carbide and/or a metal selected from aluminum, molybdenum, titanium, nickel, iron or cobalt (or their alloys) at temperatures of 350.degree. to 700.degree. C. and pressures of 0 to 1000 psig to obtain a product wherein at least one chlorine or bromine in the starting material has been replaced by hydrogen.
摘要翻译：在碳化硅和/或选自铝，钼，钛，镍，铁或钴（或它们的合金）的金属的存在下，在温度下，将含有氯和/或溴的碳氢化合物如CCl 2 F 2，CF 3 CFHCl或CF 3 CFCl 2与氢气接触 350℃至700℃，压力为0-1000psig，得到其中原料中至少一个氯或溴被氢代替的产物。

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