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41. 发明授权

US5426088A Light-stabilizers for dyes for thermal dye transfer recording 失效
标题翻译：用于热染料转印记录的染料的光稳定剂
公开(公告)号：US5426088A
公开(公告)日：1995-06-20
申请号：US237022
申请日：1994-05-02
申请人： Wilhelmus Janssens , Luc Vanmaele
发明人： Wilhelmus Janssens , Luc Vanmaele
IPC分类号： B41M5/382 , B41M5/39 , B41M5/392 , B41M5/40 , B41M5/42 , B41M5/50 , B41M5/52 , B41M5/035 , B41M5/38
CPC分类号： B41M5/423 , B41M5/392 , B41M5/5227 , B41M5/39 , Y10S428/913 , Y10S428/914
摘要： Dye-donor element for thermal dye recording comprising a dye layer comprising a dye and leuco-indoaniline dye as a light-stabilizer. The leuco-indoaniline dye is preferably a compound according to the formula: ##STR1## wherein R.sup.1 is H or any substituent, n is 0-4 each of R.sup.2 and R.sup.3 (same or different) is H or acyl, X is 0 or represents atoms completing a ring (system), each of R.sup.4, R.sup.5, R.sup.6, and R.sup.7 (same or different) is H, (cyclo)alkyl, aryl, alkyloxy, aryloxy, carbamoyl, sulphamoyl, --OH, halogen, --NH--SO.sub.2 R.sup.12, --NH--COR.sup.12, --O--SO.sub.2 R.sup.12, or --O--COR.sup.12, or R.sup.4 and R.sup.7 together and R.sup.5 and R.sup.6 together represent the atoms completing a ring (system), or R.sup.4 and R.sup.8 and/or R.sup.5 and R.sup.9 together and R.sup.5 and R.sup.6 together represent the atoms completing a heterocyclic nucleus, each of R.sup.8 and R.sup.9 (same or different) is H, (cyclo)alkyl, aryl, a heterocyclic nucleus, or R.sup.8 and R.sup.9 together represent the atoms completing a heterocyclic nucleus, each of R.sup.10, R.sup.11, and R.sup.12 (same or different) represents (cyclo)alkyl group, alkenyl, aryl, alkyloxy, aryloxy, alkylthio, arylthio, amino, or a heterocyclic nucleus.
摘要翻译：用于热染料记录的染料供体元件，包括染料层，其包含染料和作为光稳定剂的无色 - 吲哚苯胺染料。无色 - 吲哚苯胺染料优选为根据下式的化合物：其中R 1为H或任何取代基，n为0-4，R 2和R 3（相同或不同）为H或酰基，X为0或表示完成环（体系）的原子是H，（环）烷基，芳基，烷氧基，芳氧基，氨基甲酰基，氨磺酰基，-OH，卤素，-NH-SO2R12（R4），R5，R6和R7（相同或不同），-NH-COR 12，-O-SO 2 R 12或-O-COR 12，或R 4和R 7一起以及R 5和R 6一起代表完成环（系）的原子，或者R 4和R 8和/或R 5和R 9一起和R 5 和R6一起表示完成杂环核的原子，R8和R9（相同或不同）各自为H，（环）烷基，芳基，杂环核，或R8和R9一起表示完成杂环核的原子， R10，R11和R12（相同或不同）表示（环）烷基，烯基，芳基，烷氧基，芳氧基，烷硫基，芳硫基，氨基或杂环。

42. 发明授权

US5397762A Dye-donor element comprising tricyanovinylaniline dyes 失效
标题翻译：染料供体元件包括三氰基乙烯基苯胺染料
公开(公告)号：US5397762A
公开(公告)日：1995-03-14
申请号：US152742
申请日：1993-11-16
申请人： Luc Vanmaele , Wilhelmus Janssens
发明人： Luc Vanmaele , Wilhelmus Janssens
IPC分类号： B41M5/385 , B41M5/388 , B41M5/39 , C09B23/14 , C09B57/00 , B41M5/035 , B41M5/38
CPC分类号： B41M5/39 , B41M5/3854 , C09B23/143 , Y10S428/913 , Y10S428/914 , Y10T428/31786
摘要： Dye-donor element for use according to thermal dye transfer methods, said element comprising a dye layer comprising at least one dicyanovinylaniline dye, wherein the amino group of the aniline function of said dye carries an aryl group not being substituted with a dicyanovinyl group and a hydrocarbon or substituted hydrocarbon group linked by a secondary carbon atom to said amino group. The dyes have very good light-fastness and good spectral absorption characteristics.
摘要翻译：用于根据热染料转移方法使用的染料供体元件，所述元件包括染料层，其包含至少一种二氰基乙烯基苯胺染料，其中所述染料的苯胺官能团的氨基带有未被二氰基乙烯基取代的芳基和烃或被仲碳原子连接到所述氨基的取代烃基。染料具有非常好的耐光性和良好的光谱吸收特性。

43. 发明授权

US5326676A Dye-donor element for use according to laser-induced thermal dye transfer 失效
标题翻译：根据激光诱导的热染料转移使用的染料供体元件
公开(公告)号：US5326676A
公开(公告)日：1994-07-05
申请号：US40605
申请日：1993-03-31
申请人： Luc Vanmaele , Wilhelmus Janssens
发明人： Luc Vanmaele , Wilhelmus Janssens
IPC分类号： B41M5/39 , B41M5/46 , C09B53/02 , G11B7/24 , G03C5/54 , G03C1/72 , G03C5/16
CPC分类号： B41M5/465 , B41M5/39 , C09B53/02 , Y10S430/145 , Y10S430/165
摘要： Dye-donor element for use according to a laser-induced thermal dye transfer, said dye-donor element comprising a support having thereon a dye layer and an infrared-absorbing dye which is different from the dye in the dye-layer, characterized in that said infrared-absorbing dye is a 2-carbazoyl-4-[N-(o,o'-disubstituted, p-substituted aminoaryl)imino]-1,4-quinone or a 2-hydroxaminocarbonyl-4-[N-(o,o'-disubstituted,p-substituted aminoaryl)imino]1,4-quinone.
摘要翻译：用于根据激光诱导的热染料转移使用的染料供体元件，所述染料供体元件包括其上具有染料层的支持体和与染料层中染料不同的红外线吸收染料，其特征在于：所述红外线吸收染料是2-咔唑基-4- [N-（o，o'-二取代，对取代的氨基芳基）亚氨基] -1,4-醌或2-羟基氨基羰基-4- [N-（o ，二取代的，对取代的氨基芳基）亚氨基] 1,4-醌。

44. 发明授权

US5324621A Dyes and dye-donor elements for thermal dye transfer recording 失效
标题翻译：用于热染料转印记录的染料和染料供体元件
公开(公告)号：US5324621A
公开(公告)日：1994-06-28
申请号：US44041
申请日：1993-04-08
申请人： Wilhelmus Janssens , Luc Vanmaele
发明人： Wilhelmus Janssens , Luc Vanmaele
IPC分类号： B41M5/385 , B41M5/20 , B41M5/388 , B41M5/39 , B41M5/395 , C07D209/02 , C07D209/18 , C07D215/16 , C09B23/00 , C09B23/01 , G03C1/72 , G03C1/725 , G03C5/16 , G03C8/40 , G03C5/54
CPC分类号： B41M5/3854 , B41M5/39 , B41M5/395 , Y10S430/145 , Y10S430/165
摘要： Dye-donor element for thermal dye transfer comprising at least one magenta dye having extremely low side absorption in the blue and red regions of the spectrum, said dye corresponding to the general formula (I): ##STR1## wherein R.sup.1 is H, (cyclo)alkyl, or aryl; X represents the atoms completing a heterocycle; Z is an electron-withdrawing group; Y is an electron-withdrawing group or --N(R.sup.2)R.sup.3 ; R.sup.2 and R.sup.3 together represent the atoms completing a heterocycle; or R.sup.2 and R.sup.3 together represent .dbd.C(R.sup.4)R.sup.5, or each of R.sup.2 and R.sup.3 represents (same or different) (cyclo)alkyl, aryl, or an electron-withdrawing group; each of R.sup.4 and R.sup.5 (same or different) represents H, (cyclo)alkyl, aryl, a heterocycle, SO.sub.2 R.sup.6, COR.sup.6, CSR.sup.6, POR.sup.6 R.sup.7, OR.sup.8, NR.sup.8 R.sup.9, SR.sup.8, or R.sup.4 and R.sup.5 together represent the atoms completing an aliphatic ring or a heterocycle, each of R.sup.6 and R.sup.7 (same or different) represents (cyclo)alkyl, alkenyl, aryl group, alkyloxy, aryloxy, alkylthio, arylthio, amino, a heterocycle, or R.sup.6 and R.sup.7 together represent the atoms completing a 5- or 6-membered nucleus, and each of R.sup.8 and R.sup.9 (same or different) represents (cyclo)alkyl, alkenyl, aralkyl, aryl, a heterocycle, or R.sup.8 and R.sup.9 together represent the atoms completing a 5- or 6-membered nucleus.
摘要翻译：用于热染料转移的染料供体元件包括至少一种在光谱的蓝色和红色区域具有非常低的侧面吸收的品红染料，所述染料对应于通式（I）：其中R1是H ，（环）烷基或芳基; X表示完成杂环的原子; Z是吸电子基团; Y是吸电子基团或-N（R2）R3; R2和R3一起表示完成杂环的原子; 或R 2和R 3一起表示= C（R 4）R 5，或者R 2和R 3各自表示（相同或不同）（环）烷基，芳基或吸电子基团; R4和R5（相同或不同）表示H，（环）烷基，芳基，杂环，SO2R6，COR6，CSR6，POR6R7，OR8，NR8R9，SR8或R4和R5一起表示完成脂族环的原子或杂环，R6和R7（相同或不同）各自表示（环）烷基，烯基，芳基，烷氧基，芳氧基，烷硫基，芳硫基，氨基，杂环或R6和R7一起表示完成5-或 6元核，R8和R9（相同或不同）表示（环）烷基，烯基，芳烷基，芳基，杂环或R8和R9一起代表完成5或6元核的原子。

45. 发明授权

US4855211A Polymeric phosphonium mordant and photographic element containing the same 失效
标题翻译：聚合物絮凝剂和含有它们的摄影元素
公开(公告)号：US4855211A
公开(公告)日：1989-08-08
申请号：US228173
申请日：1988-08-04
申请人： Wilhelmus Janssens , Daniel M. Timmerman , Daniel A. Claeys
发明人： Wilhelmus Janssens , Daniel M. Timmerman , Daniel A. Claeys
IPC分类号： C08F212/14 , C07F9/54 , C08F12/00 , C08F30/02 , C08F230/02 , G03C8/56
CPC分类号： G03C8/56 , C07F9/5456 , C08F30/02 , Y10S430/142 , Y10S525/916
摘要： Phosphonium mordanting polymer, that is capable of fixing acid dyes and that comprises randomly distributed recurring units corresponding to the general formula (I) ##STR1## wherein: A represents a unit that is derived from a copolymerizable monomer capable of quenching singlet oxygen e.g. N-vinylimidazole or 2-methyl-1-vinylimidazole;B represents a unit that is derived from a copolymerizable monomer having a hydrophobic character e.g. acrylonitrile or methacrylonitrile;n represents an integer of from 1 to about 12;each of R.sub.1, R.sub.2 and R.sub.3 (same or different) represents a C.sub.1 -C.sub.8 alkyl group e.g. n-butyl, a substituted C.sub.1 -C.sub.8 alkyl group e.g. a methylol group, a cyanoethyl group or an aralkyl group, a cycloalkyl group, an aryl group e.g. phenyl, or a substituted aryl group;X.sup.- represents an acid anion e.g. a halogen anion e.g. Cl.sup.-, Br.sup.- or I.sup.-, or an anion derived from an inorganic acid e.g. NO.sub.3.sup.-, HSO.sub.4.sup.-, SO.sub.4.sup.--, H.sub.2 PO.sub.4.sup.-, HPO.sub.4.sup.-- or PO.sub.4.sup.---;x represents from about 5 mole % to about 80 mole %;y represents from about 20 mole % to about 95 mole % andz represents from about 0 mole % to about 65 mole %.
摘要翻译：鏻媒染聚合物，其能够固定酸性染料并且包含对应于通式（I）的无规分布的重复单元其中：A表示衍生自能够淬灭单线态氧的可共聚单体的单元例如 N-乙烯基咪唑或2-甲基-1-乙烯基咪唑; B表示衍生自具有疏水性的可共聚单体的单元，丙烯腈或甲基丙烯腈; n表示1〜12的整数， R 1，R 2和R 3（相同或不同）各自表示C 1 -C 8烷基。正丁基，取代的C 1 -C 8烷基，例如羟甲基，氰乙基或芳烷基，环烷基，芳基例如。苯基或取代的芳基; X-表示酸性阴离子例如卤素阴离子 Cl-，Br-或I-，或衍生自无机酸的阴离子例如。 NO331，HSO4-，SO4-，H 2 PO 4 - ，HPO 4 - 或PO 4 - ; x表示约5摩尔％至约80摩尔％; y表示约20摩尔％至约95摩尔％，z表示约0摩尔％至约65摩尔％。

46. 发明授权

US4537853A Photographic silver halide material containing a ballasted electron-donor precursor compound 失效
标题翻译：含有镇流电子给体前体化合物的摄影卤化银材料
公开(公告)号：US4537853A
公开(公告)日：1985-08-27
申请号：US581723
申请日：1984-02-21
申请人： Christian C. Van de Sande , Andre Verhecken , Wilhelmus Janssens
发明人： Christian C. Van de Sande , Andre Verhecken , Wilhelmus Janssens
IPC分类号： G03C8/36 , C07F9/6571 , G03C7/392 , G03C8/08 , G03C5/54 , C07F9/02 , G03C1/42 , G03C5/30
CPC分类号： G03C8/08 , C07F9/657181 , G03C7/39288 , Y10S430/156 , Y10S430/16
摘要： Photographic silver halide material containing a ballasted electron-donor precursor compound yielding by alkaline hydrolysis an electron-donor compound (ED-compound) capable (1) of donating electrons to an oxidized electron-accepting silver halide developing agent e.g. for scavenging it, said electron-donor precursor compound corresponding to the following general formula: ##STR1## wherein: R represents hydrogen or a substituent, e.g. an acyl group, which on hydrolytic removal allows the replacement of R by H,R.sup.1, R.sup.2 and R.sup.3 (same or different) are hydrocarbon substituents or R.sup.3 is H, andZ and Y represent the necessary atoms to close a benzene ring that may be substituted or form a fused ring system.
摘要翻译：含有通过碱水解产生的镇流电子给体前体化合物的照相卤化银材料，能够（1）向被氧化的受电子的卤化银显影剂提供电子的电子给体化合物（ED化合物）为了清除它，所述电子给体前体化合物对应于以下通式：其中：R表示氢或取代基，例如，酰基，其在水解除去时允许由H取代R，R 1，R 2和R 3（相同或不同）是烃取代基或R 3是H，并且Z和Y表示封闭苯环的必要原子，所述苯环可以是取代或形成稠环体系。

47. 发明授权

US4514494A Photographic color material incorporating developing agents for color development 失效
标题翻译：含彩色显影剂的摄影彩色材料
公开(公告)号：US4514494A
公开(公告)日：1985-04-30
申请号：US548784
申请日：1983-11-04
申请人： Raymond G. Lemahieu , Wilhelmus Janssens
发明人： Raymond G. Lemahieu , Wilhelmus Janssens
IPC分类号： G03C7/26 , G03C1/42 , G03C7/392 , G03C7/40 , G03C1/02 , G03C7/16
CPC分类号： G03C7/3924 , Y10S430/167
摘要： A photographic material suited for the production of (an) azine dye image(s), and having at least one silver halide emulsion layer and/or a separate layer in water-permeable relationship with such an emulsion layer which contains:(1) a heterocyclic hydrazone compound,(2) a phenol, naphthol or active methylene coupler compound capable of forming on oxidative coupling with compound (1) an azine dye,(3) an electron transfer agent or ETA-compound capable of forming a positively charged semiquinone on oxidation with exposed silver halide,(4) a reducing agent capable of reducing the thus-formed semiquinone in acidic medium, and having in the pH range of 2-5, a polarographic half-wave potential (E 1/2) which is at least 40 mV more negative (according to the European Convention) than the polarographic half-wave potential of the ETA-compound in the same pH range, said material being suited for processing with a simple aqueous alkaline liquid, and(5) an acidic medium.
摘要翻译：适用于制备（a）吖嗪染料影像的照相材料，并且具有至少一种卤化银乳剂层和/或与这种乳液层具有水可渗透关系的单独层，其包含：（1）杂环腙化合物，（2）能够与化合物（1）吖嗪染料氧化偶联形成的苯酚，萘酚或活性亚甲基成色剂化合物，（3）能够形成带正电的半醌的电子转移剂或ETA-化合物用暴露的卤化银氧化，（4）还原剂，其能够在酸性介质中还原如此形成的半醌，并且在pH范围为2-5，极谱半波电位（E 1/2）至少40mV更负（根据欧洲公约）比相同pH范围内的ETA化合物的极谱半波电位，所述材料适于用简单的碱性水溶液处理，和（5）酸性介质。

48. 发明授权

US3965282A Thermographic recording material 失效
标题翻译：热成像记录材料
公开(公告)号：US3965282A
公开(公告)日：1976-06-22
申请号：US572669
申请日：1975-04-29
申请人： Wilhelmus Janssens , Daniel Alois Claeys , Raymond Gerard Lemahieu , Jozef Aime Dierckx
发明人： Wilhelmus Janssens , Daniel Alois Claeys , Raymond Gerard Lemahieu , Jozef Aime Dierckx
IPC分类号： B41M5/333 , C07C205/57 , B32B5/00
CPC分类号： C07C205/57 , B41M5/3335 , Y10S430/165 , Y10T428/277 , Y10T428/31536 , Y10T428/31786
摘要： A thermographic recording process in which a dye is produced by bringing image-wise into reactive contact with the aid of heat a dye precursor compound and a compound with acid reaction corresponding to the following general formula: ##EQU1## wherein : Z represents the necessary atoms to close an unsubstituted benzene nucleus, a halogen-substituted benzene nucleus or a nitro-substituted benzene nucleus, andR represents an unsubstituted aliphatic group containing at least 4 carbon atoms, a cycloaliphatic group or an aliphatic group substituted with hydroxyl, with an etherified hydroxyl group or with an acyloxy grup.
摘要翻译：一种热成像记录方法，其中通过使色素前体化合物和具有对应于以下通式的酸反应的化合物通过加热成像反应性接触来制备染料：-COOH Z并行平行-COOR其中：

49. 发明授权

US5571765A Thermal dye transfer image with improved light-fastness 失效
标题翻译：热染料转印图像具有改善的耐光性
公开(公告)号：US5571765A
公开(公告)日：1996-11-05
申请号：US363279
申请日：1994-12-22
申请人： Luc VanMaele , Wilhelmus Janssens
发明人： Luc VanMaele , Wilhelmus Janssens
IPC分类号： B41M5/382 , B41M5/385 , B41M5/388 , B41M5/39 , B41M5/40 , B41M5/46 , B41M5/50 , B41M5/52 , C09B29/033 , B41M5/035 , B41M5/38
CPC分类号： C09B29/0025 , B41M5/388 , B41M5/465 , B41M5/5227 , Y10S428/913 , Y10S428/914
摘要： The present invention provides a dye donor element comprising on a support a dye layer containing a dye dispersed or dissolved in a binder and a thermotransferable infrared absorbing azo dye having an absorption maximum above 700 nm as a stabilizer, said thermotransferable infrared absorbing azo dye being comprised in said dye layer and/or in a layer adjacent thereto. There is further provided an image receiving element comprising an infrared absorbing azo dye as a stabilizer.
摘要翻译：本发明提供了一种染料供体元件，其在载体上包含含有分散或溶解在粘合剂中的染料的染料层和具有700nm以上吸收最大值的可热转移的红外线吸收偶氮染料作为稳定剂，所述热转移红外吸收偶氮染料包括在所述染料层和/或与其相邻的层中。还提供了一种包含红外线吸收偶氮染料作为稳定剂的图像接收元件。

50. 发明授权

US5547809A Thermal transfer imaging system based on the heat transfer of a reducing agent for reducing a silver source to metallic silver 失效
标题翻译：基于用于将银源还原成金属银的还原剂的热传递的热转印成像系统
公开(公告)号：US5547809A
公开(公告)日：1996-08-20
申请号：US426817
申请日：1995-04-21
申请人： Geert Defieuw , Wilhelmus Janssens , Luc Vanmaele , Jean-Marie Dewanckele , Herman Uytterhoeven
发明人： Geert Defieuw , Wilhelmus Janssens , Luc Vanmaele , Jean-Marie Dewanckele , Herman Uytterhoeven
IPC分类号： B41M5/32 , G03C1/498 , G03C8/08 , G03C8/24
CPC分类号： G03C1/4989
摘要： The present invention provides a printing process using a donor element and a receiving element. The donor element comprises on a support a donor layer comprising a binder and a thermotransferable strong reducing agent capable of reducing a silver source to metallic silver upon heating.The donor element is image-wise heated while being in contact with an image receiving material comprising a thermoreducible silver source and a weak reducing agent, only being capable of reducing a silver source to metallic silver in the presence of metallic silver formed by said strong reducing agent. Image density is increased and stability of the reductor donor element can be improved.
摘要翻译：本发明提供使用施主元件和接收元件的印刷方法。供体元件在载体上包含供体层，其包含粘合剂和可热转移的强还原剂，其能够在加热时将银源还原成金属银。供体元件在与包含可热还原银源和弱还原剂的图像接收材料接触的同时进行成像加热，仅在由所述强还原形成的金属银存在下才能将银源还原成金属银代理商图像密度增加，并且可以提高减电体施主元件的稳定性。

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