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41. 发明授权

US07476466B2 Alkaline dry battery with a nickel oxyhydroxide and manganese oxide positive electrode including a calcium compound 失效
标题翻译：碱性干电池，含有羟基氧化镍和锰氧化物正极，包括钙化合物
公开(公告)号：US07476466B2
公开(公告)日：2009-01-13
申请号：US11885663
申请日：2006-09-22
申请人： Hidekatsu Izumi , Tadaya Okada , Yasuo Mukai , Michiko Fujiwara , Shigeto Noya
发明人： Hidekatsu Izumi , Tadaya Okada , Yasuo Mukai , Michiko Fujiwara , Shigeto Noya
IPC分类号： H01M4/42 , H01M4/52 , H01M4/50
CPC分类号： H01M6/06 , H01M2/0235 , H01M4/02 , H01M4/244 , H01M4/32 , H01M4/364 , H01M4/381 , H01M4/42 , H01M4/48 , H01M4/50 , H01M4/52 , H01M4/62 , H01M4/625 , H01M6/08 , H01M10/30 , H01M10/4235 , H01M2004/021 , H01M2004/023 , H01M2004/027
摘要： Provided is an alkaline dry battery allowing suppression of polarization in pulse discharge under heavy load to improve discharge characteristics, and having high reliability in safety in case of short circuit. In the positive electrode, a calcium compound having a content of iron element of 150 ppm or less is added in an amount of 0.1 to 10 mol % with respect to a positive electrode active material, a nickel oxyhydroxide powder having 2.95 or more of an average nickel valence and 8 to 18 μm of an average particle diameter is used, the weight ratio of the nickel oxyhydroxide powder and a manganese dioxide powder is in the range of 20:80 to 90:10. A zinc or zinc alloy powder used as negative electrode active material includes a first powder having a particle diameter more than 75 μm and 425 μm or less, and a second powder having a particle diameter more than 5 μm and 75 μm or less, and the weight ratio of the first powder and the second powder is in the range of 65:35 to 75:25, and the concentration of a potassium hydroxide solution is 33 to 35% by weight.
摘要翻译：本发明提供一种碱性干电池，其能够抑制重负载下的脉冲放电中的极化，以改善放电特性，并且在短路的情况下具有高的安全可靠性。在正极中，相对于正极活性物质，以铁元素含量为150ppm以下的钙化合物的添加量为0.1〜10摩尔％，羟基氧化镍粉末的平均值为2.95以上使用镍价和8〜18μm的平均粒径，羟基氧化镍粉末和二氧化锰粉末的重量比在20:80〜90:10的范围内。用作负极活性物质的锌或锌合金粉末包括粒径大于75μm和425μm或更小的第一粉末和粒径大于5μm和75μm或更小的第二粉末，并且第一粉末和第二粉末的重量比在65:35〜75:25的范围内，氢氧化钾溶液的浓度为33〜35重量％。

42. 发明申请

US20080070114A1 Alkaline Battery 审中-公开
标题翻译：碱性电池
公开(公告)号：US20080070114A1
公开(公告)日：2008-03-20
申请号：US11630335
申请日：2005-06-16
申请人： Fumio Kato , Katsuya Sawada , Yasuo Mukai , Shigeto Noya
发明人： Fumio Kato , Katsuya Sawada , Yasuo Mukai , Shigeto Noya
IPC分类号： H01M6/02
CPC分类号： H01M4/26 , C01G53/00 , C01P2002/52 , C01P2002/78 , C01P2006/10 , C01P2006/12 , C01P2006/40 , H01M4/50 , H01M4/52 , H01M4/625 , H01M2004/021 , H01M2010/4292
摘要： An alkaline battery including a positive electrode, a negative electrode and an alkaline electrolyte, wherein the positive electrode includes a positive electrode material mixture including nickel oxyhydroxide, electrolytic manganese dioxide and expanded graphite, the expanded graphite has an average particle diameter on a volume basis of 5 to 25 μm, a BET specific surface area of 4 to 10 m2/g, and a bulk specific gravity (apparent density) measured by a static method of 0.03 to 0.10 g/cm3, the nickel oxyhydroxide has an average nickel valence of not less than 3.05, and a content of the expanded graphite in a total amount of the nickel oxyhydroxide, the electrolytic manganese dioxide and the expanded graphite that are included in the positive electrode material mixture of 3 to 15 wt %.
摘要翻译：一种包括正极，负极和碱性电解质的碱性电池，其中所述正极包括包含羟基氧化镍，电解二氧化锰和膨胀石墨的正极材料混合物，所述膨胀石墨的平均粒径基于 5〜25μm，BET比表面积为4〜10m 2 / g，静态法测定的体积比重（表观密度）为0.03〜0.10g / cm 2， 3，氢氧化正镍的平均镍价不小于3.05，膨胀石墨的含量在正极中包含的氢氧化正镍，电解二氧化锰和膨胀石墨的总量电极材料混合物为3〜15重量％。

43. 发明申请

US20070166614A1 Alkaline battery 审中-公开
标题翻译：碱性电池
公开(公告)号：US20070166614A1
公开(公告)日：2007-07-19
申请号：US10588036
申请日：2005-06-16
申请人： Fumio Kato , Katsuya Sawada , Tadaya Okada , Yasuo Mukai , Shigeto Noya
发明人： Fumio Kato , Katsuya Sawada , Tadaya Okada , Yasuo Mukai , Shigeto Noya
IPC分类号： H01M4/52 , H01M4/50
CPC分类号： H01M4/32 , C01G53/04 , C01P2004/61 , C01P2006/11 , C01P2006/12 , C01P2006/40 , H01M4/364 , H01M4/50 , H01M4/52 , H01M2004/021
摘要： Disclosed is an alkaline battery including a positive electrode, a negative electrode and an alkaline electrolyte, (1) the positive electrode having a positive electrode material mixture containing electrolytic manganese doxide and nickel oxyhydroxide, (2) the nickel oxyhydroxide having a crystal in which at least Mg is dissolved, and (3) the nickel oxyhydroxide having a tap density determined after 500 taps of not less than 2 g/cm3, an average particle size based on volume of 8 to 20 μm, and an average nickel valence of 2.95 to 3.05.
摘要翻译：公开了一种包括正极，负极和碱性电解质的碱性电池，（1）正极具有含有电解锰氧化锰和氢氧化正镍的正极材料混合物，（2）具有晶体的氢氧化正镍，溶解最少量的Mg，（3）在500次抽头后测定的振实密度不小于2g / cm 3的氢氧化正镍，基于体积为8〜20μm的平均粒径，平均镍价为2.95〜3.05。

44. 发明申请

US20060257742A1 Alkaline battery and positive electrode material for alkaline battery 失效
标题翻译：碱性电池和碱性电池正极材料
公开(公告)号：US20060257742A1
公开(公告)日：2006-11-16
申请号：US10554356
申请日：2004-11-04
申请人： Fumio Kato , Katsuya Sawada , Hidekatsu Izumi , Yasuo Mukai , Shigelo Noya
发明人： Fumio Kato , Katsuya Sawada , Hidekatsu Izumi , Yasuo Mukai , Shigelo Noya
IPC分类号： H01M4/32 , H01M4/62 , C01G53/04
CPC分类号： H01M4/50 , C01G53/00 , C01G53/04 , C01P2002/72 , C01P2002/74 , C01P2004/51 , C01P2004/61 , C01P2006/11 , C01P2006/12 , C01P2006/40 , C01P2006/82 , H01M4/06 , H01M4/364 , H01M4/52 , H01M6/04 , H01M2004/021
摘要： There is disclosed an alkaline battery including a positive electrode material mixture, a negative electrode, a separator interposed between the positive electrode material mixture and the negative electrode, and an alkaline electrolyte, wherein the positive electrode material mixture includes a first active material comprising nickel oxyhydroxide and a second active material comprising manganese dioxide, the nickel oxyhydroxide includes a γ-type crystal structure, the content of nickel in the nickel oxyhydroxide is not less than 45 wt %, and the average particle diameter on a volume basis of the nickel oxyhydroxide measured with a laser diffraction particle size distribution analyzer is 3 to 20 μm.
摘要翻译：公开了一种碱性电池，其包括正极材料混合物，负极，夹在正极材料混合物和负极之间的隔板和碱性电解质，其中正极材料混合物包括含有氢氧化正镍的第一活性材料和包含二氧化锰的第二活性材料，羟基氧化镍包括γ型晶体结构，羟基氧化镍中的镍含量不小于45重量％，并且测量基于氢氧化镍的体积的平均粒径激光衍射粒度分布分析仪为3〜20毫米。

45. 发明申请

US20050271942A1 Alkaline dry battery and method of producing the same 审中-公开
标题翻译：碱性干电池及其制造方法
公开(公告)号：US20050271942A1
公开(公告)日：2005-12-08
申请号：US11146286
申请日：2005-06-07
申请人： Hidekatsu Izumi , Michiko Fujiwara , Yasuo Mukai , Shigeto Noya
发明人： Hidekatsu Izumi , Michiko Fujiwara , Yasuo Mukai , Shigeto Noya
IPC分类号： H01M2/08 , H01M4/06 , H01M4/24 , H01M4/26 , H01M4/36 , H01M4/52 , H01M6/08 , H01M10/04 , H01M10/28 , H01M4/50
CPC分类号： H01M4/362 , H01M2/08 , H01M4/244 , H01M4/26 , H01M4/50 , H01M4/52 , H01M10/28 , H01M2004/028 , Y10T29/4911
摘要： The alkaline dry battery of the present invention has a battery case accommodating a positive electrode including manganese dioxide and nickel oxyhydroxide, a negative electrode including zinc, and an alkaline electrolyte; a sealing plate for sealing an opening of the battery case; and a sealing member disposed in between the battery case and the sealing plate. And the alkaline dry battery has a sealant layer including a blown asphalt and polybutene in between the battery case and the sealing member.
摘要翻译：本发明的碱性干电池具有容纳包含二氧化锰和氢氧化正镍的正极的电池壳，包含锌的负极和碱性电解质; 用于密封电池壳体的开口的密封板; 以及设置在电池壳体和密封板之间的密封构件。并且碱性干电池在电池壳体和密封构件之间具有包括吹塑沥青和聚丁烯的密封剂层。

46. 发明授权

US06295807B1 System for detecting deterioration of catalyst for purifying exhaust gas 有权
标题翻译：用于检测废气净化催化剂的劣化的系统
公开(公告)号：US06295807B1
公开(公告)日：2001-10-02
申请号：US09564534
申请日：2000-05-04
申请人： Hisayo Douta , Masaaki Nakayama , Yasuo Mukai
发明人： Hisayo Douta , Masaaki Nakayama , Yasuo Mukai
IPC分类号： F01N300
CPC分类号： F01N11/007 , F01N2550/02 , F01N2900/0422 , Y02T10/47
摘要： In a system for detecting deterioration of an exhaust catalyst, when a catalyst temperature exceeds 150° C., the changing widths of the output voltage of an oxygen sensor downstream of the catalyst are integrated for a predetermined sampling period to determine data &Sgr;V reflecting the amount of purified gas component, and the deviation of the air/fuel ratio detected by an air/fuel ratio sensor upstream of the catalyst, and a target A/F and an exhaust gas flow rate or an intake flow rate are multiplied so that data &Sgr;A/F&Circlesolid;Q of the fluctuation of the gas component flowing into the catalyst are determined by integrating the multiplied values. At the instant when the catalyst temperature reaches 550° C., the data &Sgr;V, as integrated till then, are compared with a deterioration determining value, as set according to the data &Sgr;A/F&Circlesolid;Q, to determine whether the catalyst is deteriorated.
摘要翻译：在用于检测排气催化剂的劣化的系统中，当催化剂温度超过150℃时，将催化剂下游的氧传感器的输出电压的变化宽度整合为预定的采样周期，以确定反映量的净化气体成分，并且由催化剂上游的空气/燃料比传感器检测到的空气/燃料比的偏差和目标A / F和排气流量或进气流量相乘，使得数据SIGMAA / F＆Circlef;流入催化剂的气体成分的波动的Q通过对相乘值进行积分来确定。在催化剂温度达到550℃的时刻，将与之结合的数据SIGMAV与根据数据SIGMAA / F＆Circlef; Q设定的劣化判定值进行比较，以确定催化剂是否劣化。

47. 发明授权

US06073440A System for detecting deterioration of catalyst for purifying exhaust gas 失效
标题翻译：用于检测废气净化催化剂的劣化的系统
公开(公告)号：US06073440A
公开(公告)日：2000-06-13
申请号：US828181
申请日：1997-03-18
申请人： Hisayo Douta , Masaaki Nakayama , Yasuo Mukai
发明人： Hisayo Douta , Masaaki Nakayama , Yasuo Mukai
IPC分类号： F02D45/00 , F01N3/20 , F01N11/00 , F02D41/14 , F01N3/00
CPC分类号： F01N11/007 , F01N2550/02 , F01N2900/0422 , Y02T10/47
摘要： In a system for detecting deterioration of an exhaust catalyst, when a catalyst temperature exceeds 150.degree. C., the changing widths of the output voltage of an oxygen sensor downstream of the catalyst are integrated for a predetermined sampling period to determine data .SIGMA.V reflecting the amount of purified gas component, and the deviation of the air/fuel ratio detected by an air/fuel ratio sensor upstream of the catalyst, and a target A/F and an exhaust gas flow rate or an intake flow rate are multiplied so that data .SIGMA.A/F .cndot.Q of the fluctuation of the gas component flowing into the catalyst are determined by integrating the multiplied values. At the instant when the catalyst temperature reaches 550.degree. C., the data .SIGMA.V, as integrated till then, are compared with a deterioration determining value, as set according to the data .SIGMA.A/F.cndot.Q, to determine whether the catalyst is deteriorated.
摘要翻译：在用于检测排气催化剂的劣化的系统中，当催化剂温度超过150℃时，催化剂下游的氧传感器的输出电压的变化宽度被集成预定的采样周期，以确定反映净化气体成分的量，以及由催化剂上游的空气/燃料比传感器检测到的空气/燃料比的偏差，目标A / F和废气流量或进气流量相乘，使得数据通过积分相乘值来确定流入催化剂的气体成分的波动的SIGMA A / F .Q。在催化剂温度达到550℃的时刻，将与之结合的数据SIGMA V与根据数据SIGMA A / F.Q设定的劣化判定值进行比较，以确定催化剂是否劣化。

48. 发明授权

US5528898A Apparartus for detecting deterioration of catalysts 失效
标题翻译： Apparartus用于检测催化剂的劣化
公开(公告)号：US5528898A
公开(公告)日：1996-06-25
申请号：US524446
申请日：1995-09-06
申请人： Masaaki Nakayama , Yasuo Mukai
发明人： Masaaki Nakayama , Yasuo Mukai
IPC分类号： F02D45/00 , F01N3/20 , F01N11/00 , F02D41/14 , F01N3/28
CPC分类号： F01N11/007 , F01N2550/02 , F01N2900/0421 , F01N2900/0422 , Y02T10/47
摘要： A catalyst deterioration determination is performed in two stages. In the first stage of determination, an amplitude of an output signal from a downstream oxygen sensor is detected and this amplitude is compared with a reference value in order to determine possible deterioration in a catalyst. When correct performance is expected, while taking into account variations (amplitude and response) in the upstream and downstream oxygen sensors, then the detection in a second stage is omitted. However when possible catalyst deterioration may be present, the determination at the seconds stage is performed. After adjusting the response of the upstream oxygen sensor to the characteristic of the slowest response, the total response delay time of the downstream sensor is obtained within a specified amount of time, and this sum then is compared with a reference value indicating catalyst deterioration. A final determination is made as to whether catalyst deterioration is present.
摘要翻译：催化剂劣化确定分两个阶段进行。在确定的第一阶段，检测来自下游氧传感器的输出信号的幅度，并将该振幅与参考值进行比较，以确定催化剂的可能劣化。当预期正确的性能时，考虑到上游和下游氧传感器的变化（振幅和响应），则省略在第二级中的检测。然而，当可能的催化剂劣化可能存在时，执行在秒级的确定。在将上游氧传感器的响应调整到最慢响应的特性之后，在规定的时间内获得下游传感器的总响应延迟时间，然后将该和与表示催化剂劣化的参考值进行比较。最后确定是否存在催化剂劣化。

49. 发明授权

US4526836A Magnetic recording media comprising a reaction product of a specific type of fluorine resin and a curing polymer material as a binder in the magnetic layer thereof 失效
标题翻译：磁性记录介质包括特定类型的氟树脂的反应产物和作为粘合剂的固化聚合物材料在其磁性层中
公开(公告)号：US4526836A
公开(公告)日：1985-07-02
申请号：US650672
申请日：1984-09-13
申请人： Yasuo Mukai , Yosuke Takazawa
发明人： Yasuo Mukai , Yosuke Takazawa
IPC分类号： C09D5/23 , C09D127/10 , C09D127/12 , C09D161/04 , C09D175/00 , C09D175/04 , G11B5/702 , G11B5/68
CPC分类号： G11B5/702 , Y10S428/90 , Y10T428/3154 , Y10T428/31544 , Y10T428/31609
摘要： Magnetic recording media which comprise a non-magnetic support and a magnetic layer formed on at least one side thereof, in which the magnetic layer is made of a magnetic composition which comprises magnetic particles dispersed throughout a resin binder consisting essentially of a reaction product of a fluorine resin having at least two hydroxyl groups in one molecule of the resin and a curing polymer material having functional groups capable of reaction with the fluorine resin through the at least two hydroxyl groups.
摘要翻译：磁性记录介质包括在其至少一个侧面上形成的非磁性载体和磁性层，其中磁性层由磁性组合物制成，该磁性组合物包含分散在整个树脂粘合剂中的磁性颗粒，该树脂粘合剂基本上由在一分子树脂中具有至少两个羟基的氟树脂和具有能够通过至少两个羟基与氟树脂反应的官能团的固化聚合物材料。

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