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    • 43. 发明申请
    • Method for Producing Polycarbonate Copolymer
    • 生产聚碳酸酯共聚物的方法
    • US20080221295A1
    • 2008-09-11
    • US10587974
    • 2005-02-17
    • Yasuhiro IshikawaKoichi SugaYoshio IkedaMasatoshi Saitou
    • Yasuhiro IshikawaKoichi SugaYoshio IkedaMasatoshi Saitou
    • C08G64/20C07C69/76C07C67/00
    • C08G64/183C08G63/64C08G64/24
    • The invention provides a method for producing a PC copolymer having a specific structure from a diester diol serving as a starting material, which method attains enhanced productivity.The method for producing a polycarbonate copolymer through interfacial polymerization, the copolymer having structural repeating units represented by formulas (I) and (II), wherein a phenol-modified diol having a hydroxybenzoic acid content of 500 ppm by mass or less is employed as a starting material. In formulas (I) and (II), each of R1 and R2 represents a C1 to C6 alkyl group; X represents a single bond, a C1 to C8 alkylene group, a C2 to C8 alkylidene group, a C5 to C15 cycloalkylene group, a C5 to C15 cycloalkylidene group, —S—, —SO—, —SO2—, —O—, —CO—, etc. Each of R3 and R4 represents a C1 to C3 alkyl group; Y represents a C2 to C15 linear-chain or branched alkylene group; a to d are integers of 0 to 4; and n is an integer of 2 to 450.
    • 本发明提供了从作为原料的二酯二醇制备具有特定结构的PC共聚物的方法,该方法提高了生产率。 通过界面聚合制备聚碳酸酯共聚物的方法,该共聚物具有由式(I)和(II)表示的结构重复单元,其中使用羟基苯甲酸含量为500质量ppm以下的苯酚改性二醇作为 起始材料 在式(I)和(II)中,R 1和R 2各自表示C 1至C 6烷基; X表示单键,C1至C8亚烷基,C2至C8亚烷基,C5至C15亚环烷基,C5至C15环烷叉基,-S-,-SO-,-SO2, R 3,O,-CO-等。R 3和R 4各自表示C 1至C 3烷基; Y表示C2〜C15直链或支链亚烷基; a至d为0至4的整数; n为2〜450的整数。
    • 46. 发明授权
    • Process for the production of polyarylene sulfide resins
    • 聚芳硫醚树脂生产工艺
    • US07317072B2
    • 2008-01-08
    • US10530027
    • 2003-10-02
    • Minoru SengaKoichi SugaTomio Ohno
    • Minoru SengaKoichi SugaTomio Ohno
    • C08F6/00
    • C08F228/04C08G75/0213C08G75/0254C08G75/0277C08G75/0281
    • The present invention is a process for the production of polyarylene sulfide based resin, wherein in washing a polyarylene sulfide based resin with a mixed solvent of an aprotic organic solvent and water in a softened or molten state, the polyarylene sulfide based resin partially dissolved in the washing liquid is recovered, to be specific, the polyarylene sulfide based resin dissolved in the washing liquid is precipitated, separated and recovered by cooling the washing liquid after washing and/or adding water to the washing liquid, and it is reused. According to the present invention, capable of being provided is a process for the production of polyarylene sulfide based resin in which the polyarylene sulfide based resin formed by polymerization is scarcely lost in washing the above resin with a solvent.
    • 本发明是一种聚芳硫醚系树脂的制造方法,其中,在软化或熔融状态下用非质子性有机溶剂和水的混合溶剂洗涤聚芳硫醚系树脂时,聚芳硫醚系树脂部分溶解于 特别地回收洗涤液,溶解在洗涤液中的聚芳硫醚系树脂通过在洗涤和/或向洗涤液中添加水后冷却洗涤液而分离和回收,并重复使用。 根据本发明,能够提供一种制备聚芳硫醚类树脂的方法,其中通过聚合形成的聚芳硫醚基树脂在用溶剂洗涤上述树脂时几乎不失去。
    • 47. 发明申请
    • Process for the production of polyarylene sulfide resins
    • 聚芳硫醚树脂生产工艺
    • US20060128819A1
    • 2006-06-15
    • US10530027
    • 2003-10-02
    • Minoru SengaKoichi SugaTomio Ohno
    • Minoru SengaKoichi SugaTomio Ohno
    • C08J11/04
    • C08F228/04C08G75/0213C08G75/0254C08G75/0277C08G75/0281
    • The present invention is a process for the production of polyarylene sulfide based resin, wherein in washing a polyarylene sulfide based resin with a mixed solvent of an aprotic organic solvent and water in a softened or molten state, the polyarylene sulfide based resin partially dissolved in the washing liquid is recovered, to be specific, the polyarylene sulfide based resin dissolved in the washing liquid is precipitated, separated and recovered by cooling the washing liquid after washing and/or adding water to the washing liquid, and it is reused. According to the present invention, capable of being provided is a process for the production of polyarylene sulfide based resin in which the polyarylene sulfide based resin formed by polymerization is scarcely lost in washing the above resin with a solvent.
    • 本发明是一种聚芳硫醚系树脂的制造方法,其中,在软化或熔融状态下用非质子性有机溶剂和水的混合溶剂洗涤聚芳硫醚系树脂时,聚芳硫醚系树脂部分溶解于 特别地回收洗涤液,溶解在洗涤液中的聚芳硫醚系树脂通过在洗涤和/或向洗涤液中添加水后冷却洗涤液而分离和回收,并重新使用。 根据本发明,能够提供一种制备聚芳硫醚类树脂的方法,其中通过聚合形成的聚芳硫醚基树脂在用溶剂洗涤上述树脂时几乎不失去。