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    • 44. 发明授权
    • Reversible electrode material
    • 可逆电极材料
    • US5324599A
    • 1994-06-28
    • US826000
    • 1992-01-27
    • Noboru OyamaKatsuhiko NaoiTadashi SotomuraHiroshi UemachiYoshiko SatoTeruhisa KanbaraKenichi Takeyama
    • Noboru OyamaKatsuhiko NaoiTadashi SotomuraHiroshi UemachiYoshiko SatoTeruhisa KanbaraKenichi Takeyama
    • H01M4/60H01M10/052H01M10/0565H01M6/18
    • H01M10/052H01M10/0565H01M4/60
    • The present invention provides an electrode material comprising a combination of a compound having a disulfide group and a conductive polymer, or a conductive polymer having a disulfide group, wherein an S-S bond of the disulfide group is cleaved by the electrolytic reduction to form a sulfur-metal ion bond or a sulfur-proton bond, and the sulfur-metal ion bond or the sulfur-proton bond re-forms an S-S bond by the electrolytic oxidation. The present invention also provides a lithium rechargeable battery comprising a cathode, a solid electrolyte, and an anode, wherein the cathode is made of a composition containing as its main components lithium thiolate having a sulfur-lithium ion bond capable of forming a disulfide bond by the electrolytic oxidation and a .pi. electron conjugated conductive polymer; or a composition containing as its main component a .pi. electron conjugated conductive polymer having a sulfur-lithium ion bond capable of forming a disulfide bond by electrolytic oxidation; the solid electrolyte is a composition containing a salt containing lithium, or a polymer containing the salt; and the anode is made of a composition containing as its main components aluminium or an alloy containing aluminium, and carbon.
    • 本发明提供了包含具有二硫化物的化合物和导电性聚合物的组合的电极材料或具有二硫键的导电性聚合物,其中通过电解还原将二硫键的SS键切割,形成硫 - 金属离子键或硫质子键,硫金属离子键或硫质子键通过电解氧化而重新形成SS键。 本发明还提供一种锂可再充电电池,其包含阴极,固体电解质和阳极,其中阴极由含有能够形成二硫键的硫 - 锂离子键的硫醇锂的组成的组合物制成 电解氧化和π电子共轭导电聚合物; 或含有通过电解氧化形成二硫键的具有硫 - 锂离子键的π电子共轭导电聚合物作为其主要成分的组合物; 固体电解质是含有含锂的盐或含有该盐的聚合物的组合物; 并且阳极由含有铝或含有铝的合金和碳的主要成分的组合物制成。
    • 48. 发明授权
    • Polymer electrolyte fuel cell and production method of the same
    • 聚合物电解质燃料电池及其制备方法相同
    • US07316860B2
    • 2008-01-08
    • US10372945
    • 2003-02-26
    • Eiichi YasumotoAkihiko YoshidaMakoto UchidaJunji MoritaYasushi SugawaraTeruhisa Kanbara
    • Eiichi YasumotoAkihiko YoshidaMakoto UchidaJunji MoritaYasushi SugawaraTeruhisa Kanbara
    • H01M4/90H01M4/86
    • H01M8/1004H01M4/8605H01M4/8807H01M4/8821H01M4/8828H01M4/92H01M4/926H01M2300/0082Y02P70/56
    • A polymer electrolyte fuel cell comprising: a hydrogen ion-conductive polymer electrolyte membrane; an anode and a cathode with the electrolyte membrane interposed therebetween; an anode-side conductive separator having a gas flow channel for supply of a fuel gas to the anode; and a cathode-side conductive separator having a gas flow channel for supply of an oxidant gas to the cathode, wherein each of the anode and the cathode comprises at least a catalyst layer in contact with the electrolyte membrane and a gas diffusion layer in contact with the catalyst layer and the separator, and at least one of the anode and the cathode contains a compound represented by the formula (I): R1—O—{(C2H4O)n—(C3H6O)m}—R2   (I) where R1 and R2 are independent of each other and each represents a hydrogen atom or an alkyl group having not less than 5 and not more than 15 carbon atoms, n and m are integers which satisfy 0≦n≦5, 0≦m≦5 and 1≦n+m≦5, and when neither n nor m is 0, at least one of the ethylene oxide group and at least one of the propylene oxide group are arranged in a random fashion.
    • 一种聚合物电解质燃料电池,包括:氢离子导电聚合物电解质膜; 阳极和阴极,其间插入电解质膜; 阳极侧导电隔板,具有用于向阳极供给燃料气体的气体流路; 以及具有用于向阴极供给氧化剂气体的气体流路的阴极侧导电性隔板,其中阳极和阴极中的至少一个包括至少与电解质膜接触的催化剂层和与电解质膜接触的气体扩散层 催化剂层和隔板,并且阳极和阴极中的至少一个包含由式(I)表示的化合物:<?in-line-formula description =“In-line Formulas”end =“lead”?> R 1 -O - {(C 2 H 4 O)n - (C 3 H 3) (I)<βin-line-formula description =“在线公式 “end =”tail“?>其中R 1和R 2彼此独立,各自表示氢原子或不少于5的烷基 大于15个碳原子,n和m是满足0 <= n <= 5,0 <= m <= 5和1 <= n + m <= 5的整数,当n和m都不为0时,至少 一个环氧乙烷基团和至少一个丙烯 氧化烯基团以随机方式排列。
    • 50. 发明授权
    • Electrolyte for driving electrolytic capacitor and the electrolytic
capacitor
    • 用于驱动电解电容器和电解电容器的电解液
    • US5485346A
    • 1996-01-16
    • US127547
    • 1993-09-28
    • Teruhisa KanbaraYuichiro Tsubaki
    • Teruhisa KanbaraYuichiro Tsubaki
    • H01G9/02H01G9/022
    • H01G9/022
    • An electrolyte for driving an electrolytic capacitor comprising an organic solvent, at least one ammonium carboxylate and, at least one solute selected from the group consisting of quaternary ammonium borates and quaternary ammonium phosphates. An electrolyte further containing a polymer is disclosed. The polymer includes a polyether polyol represented by the following formula: ##STR1## where, 1.sub.1, 1.sub.2, 1.sub.3, m.sub.1, m.sub.2, m.sub.3, n.sub.1, n.sub.2, and n.sub.3 are positive integers, and 2.ltoreq.(1.sub.1 +m.sub.1).times.n.sub.1 .ltoreq.50, 2.ltoreq.(1.sub.2 +m.sub.2).times.n.sub.2 .ltoreq.50 and 2.ltoreq.(1.sub.3 +m.sub.3).times.n.sub.3 .ltoreq.50, andR.sub.1, R.sub.2 and R.sub.3 independently represents a hydrogen atom, which may be substituted one another by the same or different isocyanate residue or acrylic residue, wherein each end of the isocyanate residue or acrylic residue may be three-dimensionally linked.
    • 一种用于驱动包括有机溶剂,至少一种羧酸铵和至少一种选自季铵硼酸盐和季铵磷酸盐的溶质的电解电容器的电解质。 公开了还含有聚合物的电解质。 聚合物包括由下式表示的聚醚多元醇:其中,11,12,13,m1,m2,m3,n1,n2和n3为正整数,2为(11 + m1)xn1