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    • 43. 发明授权
    • Process for producing acetic acid
    • 生产乙酸的方法
    • US09162958B2
    • 2015-10-20
    • US13995102
    • 2011-12-01
    • Masahiko ShimizuRyuji SaitoHiroyuki Miura
    • Masahiko ShimizuRyuji SaitoHiroyuki Miura
    • C07C51/12C07C51/44
    • C07C51/12C07C51/44C07C53/08
    • Acetic acid is produced while inhibiting increased concentrations of hydrogen iodide and acetic acid in an acetaldehyde distillation column.A production process of acetic acid comprises a step for allowing methanol to react with carbon monoxide; a step for feeding a flasher with the reaction mixture to separate a volatile component (2A) and a low-volatile component (2B); a step for feeding a distillation column with the volatile component (2A), and separating an overhead (3A) containing methyl iodide, acetic acid, methyl acetate, water, acetaldehyde, and hydrogen iodide, and a stream (3B) containing acetic acid to collect acetic acid; and a separation step for feeding an acetaldehyde distillation column with at least part of the overhead (3A) and separating a liquid object to be treated containing the overhead (3A) into a lower boiling point component (4A) containing acetaldehyde and a higher boiling point component (4B); wherein, in the separation step, the liquid object contains methanol and/or dimethyl ether in a concentration of 0.1 to 50% by weight is subjected to distillation.
    • 产生乙酸,同时抑制乙醛蒸馏塔中碘化氢和乙酸的浓度增加。 乙酸的生产方法包括使甲醇与一氧化碳反应的步骤; 用反应混合物进料闪蒸器以分离挥发性组分(2A)和低挥发性组分(2B)的步骤; 将蒸馏塔与挥发性成分(2A)进料的工序,将含有甲基碘,乙酸,乙酸甲酯,水,乙醛,碘化氢的塔顶馏出物(3A)和含有乙酸的物流(3B)分离成 收集乙酸; 以及分离步骤,用于向塔顶(3A)的至少一部分进料乙醛蒸馏塔并将含有塔顶馏出物(3A)的待处理液体分离成含有乙醛和较高沸点的低沸点组分(4A) 组分(4B); 其中,在分离步骤中,液体物质含有浓度为0.1至50重量%的甲醇和/或二甲醚进行蒸馏。
    • 44. 发明授权
    • Process for producing acetic acid
    • 生产乙酸的方法
    • US09073843B2
    • 2015-07-07
    • US13994275
    • 2011-12-01
    • Masahiko ShimizuRyuji SaitoHiroyuki MiuraTakashi UenoHidehiko Nakajima
    • Masahiko ShimizuRyuji SaitoHiroyuki MiuraTakashi UenoHidehiko Nakajima
    • C07C51/12B01J23/46B01J27/13C07C51/44
    • C07C51/12B01J23/464B01J27/13C07C51/44C07C53/08
    • A process for producing acetic acid by: a reaction step for continuously allowing methanol to react with carbon monoxide in the presence of a catalyst system comprising a metal catalyst, an ionic iodide, and methyl iodide in a carbonylation reactor, a flash distillation step for continuously feeding a flasher with a reaction mixture from the reactor and evaporating a volatile component at least containing product acetic acid, methyl acetate, and methyl iodide by flash distillation to separate the volatile component and a liquid catalyst mixture at least containing the metal catalyst and the ionic iodide, and an acetic acid collection step for separating a stream containing acetic acid from the volatile component to collect acetic acid; wherein, in the flash distillation step, the flash distillation is conducted under the condition that the concentration of methyl acetate in the liquid catalyst mixture is not less than 0.6% by weight.
    • 一种生产乙酸的方法,该方法是:在羰基化反应器中,在包含金属催化剂,离子碘化物和甲基碘的催化剂体系的存在下,连续使甲醇与一氧化碳反应的反应步骤,连续的闪蒸步骤 用来自反应器的反应混合物进料闪蒸器并通过闪蒸蒸发至少含有产物乙酸,乙酸甲酯和甲基碘的挥发性组分,以分离挥发性组分和至少含有金属催化剂和离子的液体催化剂混合物 碘化物和乙酸收集步骤,用于从含挥发性成分中分离含有乙酸的物流以收集乙酸; 其中,在闪蒸步骤中,在液体催化剂混合物中乙酸甲酯的浓度不小于0.6重量%的条件下进行闪蒸。
    • 45. 发明申请
    • PROCESS FOR PRODUCING ACETIC ACID
    • 生产乙酸的方法
    • US20130281735A1
    • 2013-10-24
    • US13995102
    • 2011-12-01
    • Masahiko ShimizuRyuji SaitoHiroyuki Miura
    • Masahiko ShimizuRyuji SaitoHiroyuki Miura
    • C07C51/12
    • C07C51/12C07C51/44C07C53/08
    • Acetic acid is produced while inhibiting increased concentrations of hydrogen iodide and acetic acid in an acetaldehyde distillation column.A production process of acetic acid comprises a step for allowing methanol to react with carbon monoxide; a step for feeding a flasher with the reaction mixture to separate a volatile component (2A) and a low-volatile component (2B); a step for feeding a distillation column with the volatile component (2A), and separating an overhead (3A) containing methyl iodide, acetic acid, methyl acetate, water, acetaldehyde, and hydrogen iodide, and a stream (3B) containing acetic acid to collect acetic acid; and a separation step for feeding an acetaldehyde distillation column with at least part of the overhead (3A) and separating a liquid object to be treated containing the overhead (3A) into a lower boiling point component (4A) containing acetaldehyde and a higher boiling point component (4B); wherein, in the separation step, the liquid object contains methanol and/or dimethyl ether in a concentration of 0.1 to 50% by weight is subjected to distillation.
    • 产生乙酸,同时抑制乙醛蒸馏塔中碘化氢和乙酸的浓度增加。 乙酸的生产方法包括使甲醇与一氧化碳反应的步骤; 用反应混合物进料闪蒸器以分离挥发性组分(2A)和低挥发性组分(2B)的步骤; 将蒸馏塔与挥发性成分(2A)进料的工序,将含有甲基碘,乙酸,乙酸甲酯,水,乙醛,碘化氢的塔顶馏出物(3A)和含有乙酸的物流(3B)分离成 收集乙酸; 以及分离步骤,用于向塔顶(3A)的至少一部分进料乙醛蒸馏塔并将含有塔顶馏出物(3A)的待处理液体分离成含有乙醛和较高沸点的低沸点组分(4A) 组分(4B); 其中,在分离步骤中,液体物质含有浓度为0.1至50重量%的甲醇和/或二甲醚进行蒸馏。
    • 46. 发明申请
    • PROCESS FOR PRODUCING ACETIC ACID
    • 生产乙酸的方法
    • US20130261334A1
    • 2013-10-03
    • US13994275
    • 2011-12-01
    • Masahiko ShimizuRyuji SaitoHiroyuki MiuraTakashi UenoHidehiko Nakajima
    • Masahiko ShimizuRyuji SaitoHiroyuki MiuraTakashi UenoHidehiko Nakajima
    • C07C51/12
    • C07C51/12B01J23/464B01J27/13C07C51/44C07C53/08
    • A process for producing acetic acid by: a reaction step for continuously allowing methanol to react with carbon monoxide in the presence of a catalyst system comprising a metal catalyst, an ionic iodide, and methyl iodide in a carbonylation reactor, a flash distillation step for continuously feeding a flasher with a reaction mixture from the reactor and evaporating a volatile component at least containing product acetic acid, methyl acetate, and methyl iodide by flash distillation to separate the volatile component and a liquid catalyst mixture at least containing the metal catalyst and the ionic iodide, and an acetic acid collection step for separating a stream containing acetic acid from the volatile component to collect acetic acid; wherein, in the flash distillation step, the flash distillation is conducted under the condition that the concentration of methyl acetate in the liquid catalyst mixture is not less than 0.6% by weight.
    • 一种生产乙酸的方法,该方法是:在羰基化反应器中,在包含金属催化剂,离子碘化物和甲基碘的催化剂体系的存在下,连续使甲醇与一氧化碳反应的反应步骤,连续的闪蒸步骤 用来自反应器的反应混合物进料闪蒸器并通过闪蒸蒸发至少含有产物乙酸,乙酸甲酯和甲基碘的挥发性组分,以分离挥发性组分和至少含有金属催化剂和离子的液体催化剂混合物 碘化物和乙酸收集步骤,用于从含挥发性成分中分离含有乙酸的物流以收集乙酸; 其中,在闪蒸步骤中,在液体催化剂混合物中乙酸甲酯的浓度不小于0.6重量%的条件下进行闪蒸。
    • 48. 发明授权
    • Process for producing carboxylic acid
    • 制备羧酸的方法
    • US07678940B2
    • 2010-03-16
    • US11922339
    • 2006-07-11
    • Hiroyuki MiuraHidetaka Kojima
    • Hiroyuki MiuraHidetaka Kojima
    • C07C51/42
    • C07C51/44C07C53/08C07C53/122
    • A process for producing a purified carboxylic acid having “n+1” carbon atoms comprises feeding a carboxylic acid stream containing a carboxylic acid having “n+1” carbon atoms, a hydrogen halide, a lower boiling point (bp) component, a higher bp component, and others to a first distillation column; separating a lower bp fraction containing part of the lower bp component and a higher bp fraction containing part of the higher bp component in the first column; withdrawing a side stream containing at least the carboxylic acid by side cut from the first column; feeding the side stream to a second distillation column; separating a lower bp fraction containing part of the lower bp component and a higher bp fraction containing part of the higher bp component in the second column; and withdrawing a side stream containing the carboxylic acid by side cut from the second column to recover a purified carboxylic acid; and the process further comprises feeding at least one first component (A) selected from the group consisting of an alcohol, corresponding to the carboxylic acid, having “n” carbon atom(s), and an ester of the alcohol with the carboxylic acid to the first column, and if necessary water. Such a process ensures reduction of the concentration of the hydrogen halide in the purified carboxylic acid.
    • 制备具有“n + 1”个碳原子的精制羧酸的方法包括进料含有具有“n + 1”个碳原子的羧酸的羧酸流,卤化氢,低沸点(bp)组分,较高沸点 bp组分,其他至第一蒸馏塔; 分离含有部分低级bp组分的较低bp级分和含有第一列中较高bp组分部分的较高bp级分; 通过从第一塔侧面切割来抽出至少含有羧酸的侧流; 将侧流进料到第二蒸馏塔; 分离含有部分低级bp组分的较低bp级分和含有第二列中较高bp成分部分的较高bp级分; 通过从第二塔侧面切断含有羧酸的侧流,以回收纯化的羧酸; 该方法进一步包括将至少一种选自由对应于具有“n”个碳原子的羧酸的醇和醇与羧酸的醇组成的组中的至少一种第一组分加入到 第一列,如果需要的话。 这样的方法确保了精制羧酸中卤化氢浓度的降低。
    • 50. 发明申请
    • Process For Producing Carboxylic Acid
    • 生产羧酸的方法
    • US20090036710A1
    • 2009-02-05
    • US11922339
    • 2006-07-11
    • Hiroyuki MiuraHidetaka Kojima
    • Hiroyuki MiuraHidetaka Kojima
    • C07C51/42
    • C07C51/44C07C53/08C07C53/122
    • A process for producing a purified carboxylic acid having “n+1” carbon atoms comprises feeding a carboxylic acid stream containing a carboxylic acid having “n+1” carbon atoms, a hydrogen halide, a lower boiling point (bp) component, a higher bp component, and others to a first distillation column; separating a lower bp fraction containing part of the lower bp component and a higher bp fraction containing part of the higher bp component in the first column; withdrawing a side stream containing at least the carboxylic acid by side cut from the first column; feeding the side stream to a second distillation column; separating a lower bp fraction containing part of the lower bp component and a higher bp fraction containing part of the higher bp component in the second column; and withdrawing a side stream containing the carboxylic acid by side cut from the second column to recover a purified carboxylic acid; and the process further comprises feeding at least one first component (A) selected from the group consisting of an alcohol, corresponding to the carboxylic acid, having “n” carbon atom(s), and an ester of the alcohol with the carboxylic acid to the first column, and if necessary water. Such a process ensures reduction of the concentration of the hydrogen halide in the purified carboxylic acid.
    • 制备具有“n + 1”个碳原子的精制羧酸的方法包括进料含有具有“n + 1”个碳原子的羧酸的羧酸流,卤化氢,低沸点(bp)组分,较高沸点 bp组分,其他至第一蒸馏塔; 分离含有部分低级bp组分的较低bp级分和含有第一列中较高bp组分部分的较高bp级分; 通过从第一塔侧面切割来抽出至少含有羧酸的侧流; 将侧流进料到第二蒸馏塔; 分离含有部分低级bp组分的较低bp级分和含有第二列中较高bp成分部分的较高bp级分; 通过从第二塔侧面切断含有羧酸的侧流,以回收纯化的羧酸; 该方法进一步包括将至少一种选自由对应于具有“n”个碳原子的羧酸的醇和醇与羧酸的醇组成的组中的至少一种第一组分加入到 第一列,如果需要的话。 这样的方法确保了精制羧酸中卤化氢浓度的降低。