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41. 发明授权

US5786102A Device for converting invisible and visible radiation to visible light and/or UV radiation 失效
标题翻译：用于将不可见和可见辐射转换成可见光和/或UV辐射的装置
公开(公告)号：US5786102A
公开(公告)日：1998-07-28
申请号：US585657
申请日：1996-01-16
申请人： Gustavo R. Paz-Pujalt , James M. Chwalek , Anna L. Hrycin , Dilip K. Chatterjee , Liang-Sun Hung
发明人： Gustavo R. Paz-Pujalt , James M. Chwalek , Anna L. Hrycin , Dilip K. Chatterjee , Liang-Sun Hung
IPC分类号： C09K11/77 , C23C14/06 , F21K2/00 , B32B9/00
CPC分类号： C23C14/0694 , C09K11/7772 , C09K11/7773 , F21K2/005 , Y10S430/145 , Y10S430/146
摘要： An amorphous upconversion phosphor comprising barium fluoride a combination of rare-earth fluorides including yttrium and lanthanum and dopants, and a waveguide thereof on a substrate selected to have a refractive index lower than a thin film of the phosphor material or any other substrate with an appropriate buffer layer of lower refractive index that the film wherein infrared radiation and visible light are converted to ultraviolet and visible light. The amorphous upconversion phosphor is deposited at temperatures low enough to permit integration into semiconductor materials.
摘要翻译：一种无定形上变频荧光体，包括氟化钡，包括钇和镧和掺杂剂的稀土氟化物的组合，以及在其上的波导，其被选择为具有低于荧光体材料或任何其它基底的薄膜的折射率，其具有适当的其中红外辐射和可见光被转换成紫外线和可见光的膜的低折射率缓冲层。无定形上变频磷光体在足够低的温度下沉积以允许集成到半导体材料中。

42. 发明授权

US5525380A Method of making a device for converting infrared radiation 失效
标题翻译：制造用于转换红外辐射的装置的方法
公开(公告)号：US5525380A
公开(公告)日：1996-06-11
申请号：US432281
申请日：1995-05-01
申请人： Gustavo R. Paz-Pujalt , James M. Chwalek , Anna L. Hrycin , Dilip K. Chatterjee , Liang-Sun Hung
发明人： Gustavo R. Paz-Pujalt , James M. Chwalek , Anna L. Hrycin , Dilip K. Chatterjee , Liang-Sun Hung
IPC分类号： C09K11/77 , C23C14/06 , F21K2/00 , C23C8/00
CPC分类号： C23C14/0694 , C09K11/7772 , C09K11/7773 , F21K2/005 , Y10S430/145 , Y10S430/146
摘要： An amorphous upconversion phosphor comprising barium fluoride a combination of rare-earth fluorides including yttrium and lanthanum and dopants, and a waveguide thereof on a substrate selected to have a refractive index lower than a thin film of the phosphor material or any other substrate with an appropriate buffer layer of lower refractive index that the film wherein infrared radiation and visible light are convened to ultraviolet and visible light The amorphous upconversion phosphor is deposited at temperatures low enough to permit integration into semiconductor materials.
摘要翻译：一种无定形上变频荧光体，包括氟化钡，包括钇和镧和掺杂剂的稀土氟化物的组合及其波导，其选择为具有低于荧光体材料或任何其它基底的薄膜的折射率，其具有适当的其中红外辐射和可见光被聚合到紫外和可见光的膜的较低折射率的缓冲层无定形上变频荧光体在足够低的温度下沉积以允许集成到半导体材料中。

43. 发明授权

US5472678A Sol-gel method for preparing an alkaline earth metal borate 失效
标题翻译：用于制备碱土金属硼酸盐的溶胶 - 凝胶法
公开(公告)号：US5472678A
公开(公告)日：1995-12-05
申请号：US244957
申请日：1994-06-15
申请人： Wenjiang Nie , Gustavo R. Paz-Pujalt , Christian Lurin
发明人： Wenjiang Nie , Gustavo R. Paz-Pujalt , Christian Lurin
IPC分类号： C01B35/12 , C23C18/12
CPC分类号： C01B35/126 , C23C18/1216 , C23C18/1225
摘要： The present invention concerns a method for preparing earth alkaline metal borates.The method comprises the steps of forming a mixture of an earth-alkaline metal alkoxide and a boron alkoxide, of hydrolysing this mixture to form a metal-borate precursor, and then coating the precursor onto a substrate and thermally treating it to form an inorganic film on the substrate.The method is especially useful to prepare beta barium borate layers which can serve in non-linear optical devices to produce second harmonics generation.
摘要翻译： PCT No.PCT / EP92 / 02838第 371日期1994年6月15日 102（e）日期1994年6月15日PCT提交1992年12月9日PCT公布。公开号WO93 / 12037 日期：1993年6月24日。本发明涉及一种制备碱土金属硼酸盐的方法。该方法包括以下步骤：形成碱土金属醇盐和硼醇盐的混合物，水解该混合物以形成金属硼酸盐前体，然后将前体涂覆在基材上并热处理形成无机膜在基板上。该方法对于制备可用于非线性光学器件以产生二次谐波产生的β硼酸钡层特别有用。

44. 发明授权

US5436919A Multiwavelength upconversion waveguide laser 失效
标题翻译：多波长上变频波导激光器
公开(公告)号：US5436919A
公开(公告)日：1995-07-25
申请号：US186068
申请日：1994-01-25
申请人： James M. Chwalek , Gustavo R. Paz-Pujalt , Jose M. Mir , William J. Grande
发明人： James M. Chwalek , Gustavo R. Paz-Pujalt , Jose M. Mir , William J. Grande
IPC分类号： G02F2/02 , C09K11/85 , H01S3/06 , H01S3/063 , H01S3/07 , H01S3/094 , H01S3/0941 , H01S3/16 , H01S3/17 , H01S3/23 , H01S5/00 , G02F1/23
CPC分类号： H01S3/063 , H01S3/0632 , H01S3/0635 , H01S3/094092 , H01S3/0941 , H01S3/1603 , H01S3/2383 , H01S3/2391
摘要： A multiwavelength upconversion waveguide laser producing visible or ultraviolet wavelength radiation comprising a semiconductor laser diode producing relatively long wavelength radiation, a channel waveguide having a thin film material which converts the relatively long wavelength radiation into visible or ultraviolet wavelength radiation, and a optical resonator which recirculates the visible or ultraviolet wavelength radiation. The optical resonator may use an output optical coating or one or more Bragg grating reflectors as an output coupler. One or more optical resonators may be used to produce one or more visible or ultraviolet radiation wavelengths. One or more independently controllable lightwave modulators are used to modulate the visible or ultraviolet wavelength radiation.
摘要翻译：产生可见光或紫外线波长的多波长上变频波导激光，其包括产生较长波长辐射的半导体激光二极管，具有将相对较长波长辐射转换成可见光或紫外线波长辐射的薄膜材料的通道波导，以及再循环可见光或紫外线波长辐射。光学谐振器可以使用输出光学涂层或一个或多个布拉格光栅反射器作为输出耦合器。可以使用一个或多个光学谐振器来产生一个或多个可见光或紫外辐射波长。一个或多个可独立控制的光波调制器用于调制可见光或紫外线波长的辐射。

45. 发明授权

US5283083A Metalorganic decomposition method for preparing a metal borate 失效
标题翻译：用于制备金属硼酸盐的金属有机分解方法
公开(公告)号：US5283083A
公开(公告)日：1994-02-01
申请号：US954994
申请日：1992-10-01
申请人： Gustavo R. Paz-Pujalt , Wenjiang Nie
发明人： Gustavo R. Paz-Pujalt , Wenjiang Nie
IPC分类号： C23C18/12 , B05D3/02
CPC分类号： C23C18/1216
摘要： The present invention concerns a method for preparing metal borate.The method consists in forming a metal ligand and a boron alkoxide and to react them to form a metal-borate precursor, which is then thermally treated to form an inorganic film on a substrate.The method is especially useful to prepare beta barium borate layers which can serve in non-linear optical devices to produce second harmonics generation.
摘要翻译：本发明涉及一种制备金属硼酸盐的方法。该方法包括形成金属配体和硼醇盐并使其反应形成金属硼酸盐前体，然后将其热处理以在基材上形成无机膜。该方法对于制备可用于非线性光学器件以产生二次谐波产生的β硼酸钡层特别有用。

46. 发明授权

US5073410A Thin films of metal phosphates and the method of their formation 失效
标题翻译：金属磷酸盐薄膜及其形成方法
公开(公告)号：US5073410A
公开(公告)日：1991-12-17
申请号：US421889
申请日：1989-10-16
申请人： Gustavo R. Paz-Pujalt
发明人： Gustavo R. Paz-Pujalt
IPC分类号： C23C18/12
CPC分类号： C23C18/1204 , C23C18/1291
摘要： The invention is generally accomplished by mixing non-phosphorous containing metal coordination complexes and phosphorous coordination complexes, forming a coating of the mixture on a substrate and heating the mixture to recover a thin film coating of metal phosphate. The metal coordination complexes and phosphorous coordination complexes are defined as metal-ligand compounds where the ligand is thermally separable. The preferred ligands are carboxylates, alcoholates, and acetylacetonates. The heating decomposes the metal phosphate precursor coating materials to yield a metal phosphate. The phosphorous coordination complex may comprise an alkyl phosphate, arylphosphate, or a carboxylate substituted alkyl or aryl phosphate. The substituting carboxylic acids may be pure, such as 2-ethylhexanoic acid, mixtures of acids, such as neodecanoic acid, and naturally occurring acids, such as rosin (abietic acid). The metal coordination complex may be a metal carboxylate, a carboxylate substituted alkoxide, or carboxylate substituted acetylacetonate. Typical metals are the alkali metals, alkaline earths, titanium, zirconium, and aluminum.
摘要翻译：本发明通常通过混合不含磷的金属配位络合物和磷配位络合物，在基材上形成混合物的涂层并加热混合物以回收金属磷酸盐的薄膜涂层。金属配位络合物和磷配位络合物被定义为金属配体化合物，其中配体是可热分离的。优选的配体是羧酸盐，醇盐和乙酰丙酮化物。加热分解金属磷酸盐前体涂料，得到金属磷酸盐。磷配位络合物可以包括磷酸烷基酯，磷酸芳基酯或羧酸酯取代的烷基或芳基磷酸酯。取代的羧酸可以是纯的，例如2-乙基己酸，酸的混合物，例如新癸酸和天然存在的酸，例如松香（松香酸）。金属配位络合物可以是金属羧酸盐，羧酸盐取代的醇盐或羧酸酯取代的乙酰丙酮化物。典型的金属是碱金属，碱土金属，钛，锆和铝。

47. 发明授权

US5051278A Method of forming metal fluoride films by the decomposition of metallo-organic compounds in the presence of a fluorinating agent 失效
标题翻译：在氟化剂存在下通过金属有机化合物的分解形成金属氟化物膜的方法
公开(公告)号：US5051278A
公开(公告)日：1991-09-24
申请号：US377646
申请日：1989-07-10
申请人： Gustavo R. Paz-Pujalt
发明人： Gustavo R. Paz-Pujalt
IPC分类号： C03C17/22
CPC分类号： C03C17/22 , C03C2217/285 , C03C2218/111 , C03C2218/116
摘要： A method of forming a film of metal fluoride in which there is combined a metallo-organic compound solvent solution and an organic fluoride to form a casting liquid. The casting liquid is then coated by a method such as dip coating or spin coating to form a coating on a substrate. The coated substrate is then heated to decompose the metallo-organic compound and organic fluoride resulting in recovery of a metal fluoride coated substrate. The metal fluorides formed may be fluorides of lithium, sodium, potassium, magnesium, calcium, strontium, or barium, lanthanum, yttrium, or the oxifluoride of europium, erbium and other rare earths.
摘要翻译：一种形成金属氟化物的膜的方法，其中组合了金属有机化合物溶剂溶液和有机氟化物以形成浇铸液体。然后通过诸如浸涂或旋涂的方法涂覆浇铸液体以在基材上形成涂层。然后将涂覆的基底加热以分解金属有机化合物和有机氟化物，导致金属氟化物涂覆的基底的回收。形成的金属氟化物可以是锂，钠，钾，镁，钙，锶或钡的镧，镧，钇或铕，铒等稀土的氟化物。

48. 发明授权

US5041417A Conductive articles and intermediates containing heavy pnictide mixed alkaline earth oxide layers 失效
标题翻译：导电制品和含有重质混合碱土金属氧化物层的中间体
公开(公告)号：US5041417A
公开(公告)日：1991-08-20
申请号：US325816
申请日：1989-03-20
申请人： John A. Agostinelli , Gustavo R. Paz-Pujalt , Arun K. Mehrotra , Liang-sun Hung
发明人： John A. Agostinelli , Gustavo R. Paz-Pujalt , Arun K. Mehrotra , Liang-sun Hung
IPC分类号： B32B18/00 , C04B35/45 , C30B13/00 , H01L39/12 , H01L39/24
CPC分类号： C30B29/225 , C04B35/4521 , C30B13/00 , H01L39/126 , H01L39/2425 , H01L39/2454 , H01L39/2458 , H01L39/2464 , Y10S428/901 , Y10S428/93 , Y10S505/701 , Y10S505/702 , Y10S505/703 , Y10S505/704 , Y10T428/24917 , Y10T428/24926 , Y10T428/31678
摘要： Articles are disclosed in which an electrically conductive layer on a substrate exhibits a superconducting transistion temperature in excess of 90.degree. K. Conductive layers are disclosed comprised of a crystalline heavy pnictide mixed alkaline earth copper oxide. Processes of preparing these articles are disclosed in which a mixed oxide precursor composition is coated and heated to its thermal decomposition temperature to create an amorphous mixed metal oxide layer. The amorphous layer is then heated to its crystallization temperature.
摘要翻译：公开了其中衬底上的导电层表现出超过90℃的超导转移温度的制品。公开了由结晶重掺杂的碱土金属氧化铜组成的导电层。公开了制备这些制品的方法，其中将混合氧化物前体组合物涂覆并加热至其热分解温度以产生无定形混合金属氧化物层。然后将非晶层加热至其结晶温度。

49. 发明授权

US5032221A Etching indium tin oxide 失效
标题翻译：蚀刻氧化铟锡
公开(公告)号：US5032221A
公开(公告)日：1991-07-16
申请号：US520486
申请日：1990-05-07
申请人： Paul L. Roselle , Gustavo R. Paz-Pujalt , Ronald M. Wexler
发明人： Paul L. Roselle , Gustavo R. Paz-Pujalt , Ronald M. Wexler
IPC分类号： G02F1/1343 , C04B41/53 , C04B41/91 , H01L21/302 , H01L21/3065 , H01L27/146 , H01L31/18
CPC分类号： C04B41/009 , C04B41/5346 , C04B41/91 , H01L31/1884 , C04B2111/00844 , Y02E10/50
摘要： ITO is etched by a plasma containing CH.sub.3. gas.
摘要翻译： ITO被含有CH3的等离子体蚀刻。加油站。

50. 发明授权

US4950643A Metalorganic deposition process for preparing heavy pnictide superconducting oxide films 失效
标题翻译：用于制备重型超导氧化物膜的金属有机沉积工艺
公开(公告)号：US4950643A
公开(公告)日：1990-08-21
申请号：US359306
申请日：1989-05-31
申请人： John A. Agostinelli , Gustavo R. Paz-Pujalt , Arun K. Mehrotra , Liang-Sun Hung
发明人： John A. Agostinelli , Gustavo R. Paz-Pujalt , Arun K. Mehrotra , Liang-Sun Hung
IPC分类号： B32B18/00 , C04B35/45 , C30B13/00 , H01L39/12 , H01L39/24
CPC分类号： C30B29/225 , C04B35/4521 , C30B13/00 , H01L39/126 , H01L39/2425 , H01L39/2454 , H01L39/2458 , H01L39/2464 , Y10S505/725 , Y10S505/734
摘要： A metalorganic deposition method is disclosed for manufacturing a heavy pnictide superconducting oxide film on a substrate, in which a mixed metalorganic precursor is coated and heated to its thermal decomposition temperature to create an amorphous mixed metal oxide layer. The amorphous layer is then converted to a crystalline coating by further heating followed by cooling in the presence of oxygen.
摘要翻译：公开了一种金属有机沉积方法，用于在衬底上制造重的pnictide超导氧化物膜，其中将混合的金属有机前体涂覆并加热至其热分解温度以产生无定形混合金属氧化物层。然后通过进一步加热然后在氧气存在下冷却将非晶层转化为结晶涂层。

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