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    • 48. 发明申请
    • PROCESS FOR CRACKING AN OLEFIN-RICH HYDROCARBON FEEDSTOCK
    • 破碎富含烯烃原料的方法
    • US20080249344A1
    • 2008-10-09
    • US12123228
    • 2008-05-19
    • Jean-Pierre DathWalter Vermeiren
    • Jean-Pierre DathWalter Vermeiren
    • C10G11/16
    • C10G11/16C10G2400/20
    • A process for cracking an olefin-containing hydrocarbon feedstock which is selective towards light olefins in the effluent, the process comprising passing a hydrocarbon feedstock containing one or more olefins through a moving bed reactor containing a crystalline silicate catalyst selected from an MFI-type crystalline silicate having a silicon/aluminium atomic ratio of at least 180 and an MEL-type crystalline silicate having a silicon/aluminium atomic ration of from 150 to 800 which has been subjected to a steaming step, at an inlet temperature of from 500 to 600° C., at an olefin partial pressure of from 0.1 to 2 bars and the feedstock being passed over the catalyst at an LHSV of from 5 to 30 h−1 to produce an effluent with an olefin content of lower molecular weight than that of the feedstock, intermittently removing a first fraction of the catalyst from the moving bed reactor, regenerating the first fraction of the catalyst in a regenerator and intermittently feeding into the moving bed reactor a second fraction of the catalyst which has been regenerated in the regenerator, the catalyst regeneration rate being controlled whereby the propylene purity is maintained constant at a value corresponding to the average value observed in a fixed bed reactor using the same feedstock, catalyst and cracking conditions, for example at least 94 wt %.
    • 一种用于裂解对流出物中的轻质烯烃具有选择性的含烯烃的烃原料的方法,该方法包括使含有一种或多种烯烃的烃原料通过含有选自MFI型结晶硅酸盐的结晶硅酸盐催化剂的移动床反应器 具有至少180的硅/铝原子比和在500至600℃的入口温度下进行了蒸汽步骤的硅/铝原子比为150至800的MEL型结晶硅酸盐 在0.1至2巴的烯烃分压下,原料以5至30小时-1的LHSV通过催化剂以产生具有较低分子量的烯烃含量的流出物 重量比原料的重量,间歇地从移动床反应器中除去催化剂的第一部分,在再生器中再生催化剂的第一馏分并间歇地进料 在移动床反应器中,在再生器中再生的催化剂的第二部分,控制催化剂再生速率,由此丙烯纯度保持恒定在与使用相同原料的固定床反应器中观察到的平均值的值 ,催化剂和裂化条件,例如至少94重量%。
    • 50. 发明申请
    • Production of olefins
    • 生产烯烃
    • US20070027351A1
    • 2007-02-01
    • US10569240
    • 2004-08-12
    • Jean-Pierre DathWalter Vermeiren
    • Jean-Pierre DathWalter Vermeiren
    • C07C1/00
    • C07C1/20B01J29/40B01J2229/16B01J2229/36B01J2229/42C07C4/06C07C2529/40Y02P20/52Y02P30/42C07C11/06C07C11/04
    • A process for converting a hydrocarbon feedstock to provide an effluent containing light olefins, the process comprising passing a hydrocarbon feedstock comprising a mixture of a first portion, containing one or more olfeins of C4 or greater, and a second portion, containing at least one C1 to C6 aliphatic hetero compound selected from alcohols, ethers, carbonyl compounds and mixtures thereof, through a reactor containing a crystalline silicate catalyst to produce an effluent including propylene, the crystalline silicate being selected from at least one of an MFI-type crystalline silicate having a silicon/aluminium atomic ratio of at least 180 and an MEL-type crystalline silicate having a silicon/aluminium atomic ratio of from 150 to 800 which has been subjected to a steaming step.
    • 一种用于转化烃原料以提供含有轻质烯烃的流出物的方法,该方法包括使包含含有一种或多种C 4或更高的醇的第一部分的混合物的烃原料和 第二部分,通过含有结晶硅酸盐催化剂的反应器含有至少一种选自醇,醚,羰基化合物及其混合物的C 6脂族杂化合物的C 1至 产生包含丙烯的流出液,所述结晶硅酸盐选自硅/铝原子比至少为180的MFI型晶体硅酸盐和硅/铝原子比为150的MEL型结晶硅酸盐中的至少一种 至800,其已经经历了蒸汽步骤。