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    • 41. 发明授权
    • Treating hair with quaternized polymers
    • 用季铵化聚合物处理头发
    • US4197865A
    • 1980-04-15
    • US899467
    • 1978-04-24
    • Bernard JacquetGerard Lang
    • Bernard JacquetGerard Lang
    • A61K8/84A61Q5/00A61Q5/02A61Q5/04A61Q5/06A61Q5/10C08G73/02A45D7/00A61K7/06
    • A61K8/84A61Q5/00A61Q5/02A61Q5/04A61Q5/06A61Q5/10C08G73/0226A61K2800/5426Y10S424/01Y10S424/02
    • A quaternized polymer having recurring units of the formula ##STR1## wherein X.sup..crclbar. represents an anion derived from an organic or mineral acid;R'.sub.2 is an aliphatic radical having a maximum of 20 carbon atoms;R'.sub.1 is an aliphatic, alicyclic or arylaliphatic radical containing a minimum of 2 carbon atoms and a maximum of 20 carbon atoms, or R'.sub.1 and R'.sub.2 together with the nitrogen atom to which they are attached form a ring capable of containing a second heteroatom other than said nitrogen;A represents a divalent group of the formula ##STR2## wherein x, y and t are whole numbers ranging from 0 to 11 and being such that the sum (x+y+t) is greater than or equal to 0 and less than 18, and E and K represent hydrogen or an aliphatic radical having less than 18 carbon atoms;B represents a divalent group of the formula ##STR3## wherein D and G represent hydrogen or an aliphatic radical having less than 18 carbon atoms and v, z, and u are whole numbers ranging from 0 to 11, two of them being able to be simultaneously equal to 0 such that the sum (v+z+u) is greater than or equal to 1 and lower than 18, and such that the sum (v+z+u) is greater than 1 when the sum (x+y+t) is equal to 0, and n is a whole number equal to 2 or 3.The polymers are usefully employed in cosmetic compositions for application to the hair or skin.
    • 具有式“IMAGE”的重复单元的季铵化聚合物,其中X( - )表示衍生自有机或无机酸的阴离子; R'2是具有最多20个碳原子的脂族基团; R'1是含有最少2个碳原子和最多20个碳原子的脂族,脂环族或芳基脂族基团,或者R 1和R 2与它们所连接的氮原子一起形成能够含有 除所述氮之外的第二杂原子; A表示式(1)的二价基团,其中x,y和t为0〜11的整数,并且使(x + y + t)之和大于等于0且小于18, 并且E和K表示氢或具有少于18个碳原子的脂族基团; B表示下式的二价基团:其中D和G表示氢或具有少于18个碳原子的脂族基团,v,z和u为0至11的整数, 它们中的两个能够同时等于0,使得和(v + z + u)大于或等于1并且低于18,并且使得和(v + z + u)大于1 当总和(x + y + t)等于0,n是等于2或3的整数时。聚合物可用于化妆品组合物中以用于毛发或皮肤。
    • 42. 发明授权
    • Quaternized polymer for use as a cosmetic agent in cosmetic compositions
for the hair and skin
    • 用作头发和皮肤的化妆品组合物中的化妆品的季铵化聚合物
    • US4948579A
    • 1990-08-14
    • US545770
    • 1983-10-26
    • Bernard JacquetGerard Lang
    • Bernard JacquetGerard Lang
    • A01N33/12A61K8/04A61K8/41A61K8/84A61Q5/02A61Q5/04A61Q5/06A61Q5/08A61Q5/10A61Q15/00C08G73/02
    • A61Q5/04A01N33/12A61K8/046A61K8/416A61K8/84A61Q15/00A61Q5/02A61Q5/06A61Q5/08A61Q5/10C08G73/02C08G73/0226C08G73/024C08G73/0253A61K2800/5426Y10S424/01Y10S424/02
    • A quaternized polymer for use as a cosmetic agent, has recurring units of the formula ##STR1## wherein R is lower alkyl or --CH.sub.2 --CH.sub.2 OH;R' is an aliphatic, alicyclic or arylaliphatic radical containing a maximum of 20 carbon atoms, or R and R' together with the nitrogen atom to which they are attached form a heterocycle capable of containing a heteroatom other than nitrogen;A is a divalent group selected from(1) o-, m- or p-xylylidene of the formula ##STR2## (2) ##STR3## wherein x, y and t are whole numbers ranging from 0 to 11 such that the sum (x+y+t) is greater than or equal to 0 and lower than 18, and E and K represent hydrogen or an aliphatic radical having less than 18 carbon atoms,(3) --(CH.sub.2).sub.n --S--(CH.sub.2).sub.n --,(4) --(CH.sub.2).sub.n --O--(CH.sub.2).sub.n --,(5) --(CH.sub.2).sub.n --S--S--(CH.sub.2).sub.n --,(6) --(CH.sub.2).sub.n --SO--(CH.sub.2).sub.n --,(7) --(CH.sub.2).sub.n --SO.sub.2 --(CH.sub.2).sub.n -- and(8) ##STR4## wherein n is equal to 2 or 3; B represents a divalent group selected from(1) o-, m- or p-xylylidene of the formula ##STR5## (2) ##STR6## wherein D and G represent hydrogen or an aliphatic radical having less than 18 carbon atoms and v, z, and u are whole numbers ranging from 0 to 11, with two of v, z and u simultaneously being capable of being 0, such that the sum (v+z+u) is greater than or equal to 1 and lower than 18 and such that the sum (v+z+u) is greater than 1 when the sum (x+y+t) is equal to 0,(3) ##STR7## and (4) --(CH.sub.2).sub.n --O--(CH.sub.2).sub.n -- wherein n is 2 or 3; andX.crclbar. is an anion derived from an organic or mineral acid. The quaternized polymer is employed in cosmetic compositions for the hair and skin.
    • 用作化妆剂的季铵化聚合物具有下式的重复单元:其中R是低级烷基或-CH 2 -CH 2 OH; R'是含有最多20个碳原子的脂族,脂环族或芳基脂族基团,或者R和R'与它们所连接的氮原子一起形成能够含有氮以外的杂原子的杂环; A是选自(1)式(2)的(1)邻 - ,间 - 或对 - 亚二甲苯基的二价基团,其中x,y和t是0至11的整数,使得 x + y + t)大于或等于0且低于18,并且E和K表示氢或具有少于18个碳原子的脂族基团,(3) - (CH2)nS-(CH2)n-, (4) - (CH2)nO-(CH2)n-,(5) - (CH2)nSS-(CH2)n-,(6) - (CH2)n-SO-(CH2)n-,(7) - (CH 2)n -SO 2 - (CH 2)n - 和(8)其中n等于2或3; B表示选自(1)式(2)的(1)邻 - ,间 - 或对 - 亚二甲苯基的二价基团,其中D和G表示氢或具有少于18个碳原子的v, z和u是从0到11的整数,v,z和u中的两个同时能够为0,使得和(v + z + u)大于或等于1并低于18 并且当和(x + y + t)等于0时,和(4) - (CH2)nO-(CH2)的和(v + z + u) 其中n为2或3; 而X( - )是衍生自有机或无机酸的阴离子。 季铵化聚合物用于头发和皮肤的化妆品组合物中。
    • 47. 发明授权
    • Hair dyeing compositions containing quaternized polymer
    • 含有季铵化聚合物的染发组合物
    • US4422853A
    • 1983-12-27
    • US163411
    • 1980-06-26
    • Bernard JacquetGerard Lang
    • Bernard JacquetGerard Lang
    • A01N33/12A61K8/04A61K8/41A61K8/84A61Q5/02A61Q5/04A61Q5/06A61Q5/08A61Q5/10A61Q15/00C08G73/02A61K7/09A61K7/11D06P3/14
    • C08G73/02A01N33/12A61K8/046A61K8/416A61K8/84A61Q15/00A61Q5/02A61Q5/04A61Q5/06A61Q5/08A61Q5/10C08G73/0226C08G73/024C08G73/0253A61K2800/5426Y10S424/01Y10S424/02
    • A quaternized polymer for use as a cosmetic agent, has recurring units of the formula ##STR1## wherein R is lower alkyl or -CH.sub.2 -CH.sub.2 OH;R' is an aliphatic, alicyclic or arylaliphatic radical containing a maximum of 20 carbon atoms, or R and R' together with the nitrogen atom to which they are attached form a heterocycle capable of containing a heteroatom other than nitrogen;A is a divalent group selected from(1) o-, m- or p-xylylidene of the formula ##STR2## wherein x, y and t are whole numbers ranging from 0 to 11 such that the sum (x+y+t) is greater than or equal to 0 and lower than 18, and E and K represent hydrogen or an aliphatic radical having less than 18 carbon atoms,(3) --(CH.sub.2).sub.n --S--(CH.sub.2).sub.n --,(4) --(CH.sub.2).sub.n --O--(CH.sub.2).sub.n --,(5) --(CH.sub.2).sub.n --S--S--(CH.sub.2 (.sub.n --,(6) --(CH.sub.2).sub.n --SO--(CH.sub.2).sub.n --,(7) --(CH.sub.2).sub.n --SO.sub.2 --(CH.sub.2).sub.n --and ##STR3## wherein n is equal to 2 or 3; B represents a divalent group selected from(1) o-, m- or p-xylylidene of the formula ##STR4## wherein D and G represent hydrogen or an aliphatic radical having less than 18 carbon atoms and v, z and u are whole numbers ranging from 0 to 11, with two of v, z and u simultaneously being capable of being 0, such that the sum (v+z+u) is greater than or equal to 1 and lower than 18 and such that the sum (v+z+u) is greater than 1 when the sum (x+y+t) is equal to 0, ##STR5## (4) --(CH.sub.2).sub.n --O--(CH.sub.2).sub.n -- wherein n is 2 or 3; andX.sup..crclbar. is an anion derived from an organic or mineral acid. The quaternized polymer is employed in cosmetic compositions for the hair and skin.
    • 用作化妆剂的季铵化聚合物具有下式的重复单元:其中R是低级烷基或-CH 2 -CH 2 OH; R'是含有最多20个碳原子的脂族,脂环族或芳基脂族基团,或者R和R'与它们所连接的氮原子一起形成能够含有氮以外的杂原子的杂环; A是选自(1)式(1)的O-,m-或对 - 亚二甲苯基的二价基团,其中x,y和t是0至11的整数,使得(x + y) (3) - (CH 2)n -S-(CH 2)n - ,(4)表示氢或低于18个碳原子的脂族基团, - (CH 2)n O-(CH 2)n - ,(5) - (CH 2)nSS-(CH 2(n - ,(6) - (CH 2)n -SO-(CH 2)n - ,(7) - )n-SO 2 - (CH 2)n - 和< IMAGE>其中n等于2或3; B表示选自(1)O-,m-或对 - 亚二甲苯基的二价基团, >其中D和G表示氢或具有少于18个碳原子的脂族基团,v,z和u是0至11的整数,其中v,z和u中的两个同时能够为0,使得 sum(v + z + u)大于或等于1且小于18,并且当和(x + y + t)之和等于0时,和(v + z + u)大于1, (4) - (CH2)nO-(CH2)n-其中n是2或3; d X( - )是衍生自有机或无机酸的阴离子。 季铵化聚合物用于头发和皮肤的化妆品组合物中。
    • 50. 发明授权
    • Quaternized polymer for use as a cosmetic agent in cosmetic compositions
for the hair and skin
    • 用作头发和皮肤的化妆品组合物中的化妆品的季铵化聚合物
    • US4217914A
    • 1980-08-19
    • US849657
    • 1977-11-08
    • Bernard JacquetGerard Lang
    • Bernard JacquetGerard Lang
    • A01N33/12A61K8/04A61K8/41A61K8/84A61Q5/02A61Q5/04A61Q5/06A61Q5/08A61Q5/10A61Q15/00C08G73/02A45D7/00A61K7/09A61K7/11
    • C08G73/02A01N33/12A61K8/046A61K8/416A61K8/84A61Q15/00A61Q5/02A61Q5/04A61Q5/06A61Q5/08A61Q5/10C08G73/0226C08G73/024C08G73/0253A61K2800/5426Y10S424/01Y10S424/02
    • A quaternized polymer for use as a hair or skin cosmetic agent, has recurring units of the formula ##STR1## wherein R is lower alkyl or --CH.sub.2 --CH.sub.2 OH;R' is an aliphatic, alicyclic or arylaliphatic radical containing up to 20 carbon atoms, or R and R' together with the nitrogen atom to which they are attached form a heterocycle capable of containing a heteroatom other than nitrogen;A is(1) o-, m- or p-xylylidene of the formula ##STR2## ##STR3## wherein x, y and t are whole numbers ranging from 0 to 11 so the sum (x+y+t) is greater than or equal to 0 and lower than 18, and E and K represent hydrogen or an aliphatic radical having less than 18 carbon atoms,(3) --(CH.sub.2).sub.n --S--(CH.sub.2).sub.n --,(4) --(CH.sub.2).sub.n --O--(CH.sub.2).sub.n --,(5) --(CH.sub.2).sub.n --S--S--(CH.sub.2).sub.n --,(6) --(CH.sub.2).sub.n --SO--(CH.sub.2).sub.n --,(7) --(CH.sub.2).sub.n --SO.sub.2 --(CH.sub.2).sub.n --or ##STR4## wherein n is equal to 2 or 3; B represents(1) o-, m- or p-xylylidene of the formula ##STR5## ##STR6## wherein D and G represent hydrogen or an aliphatic radical having less than 18 carbon atoms and v, z and u are whole numbers ranging from 0 to 11, with two of v, z and u simultaneously being capable of being 0, so the sum (v+z+u) is greater than or equal to 1 and lower than 18 and so the sum (v+z+u) is greater than 1 when the sum (x+y+t) is equal to 0,(3) ##STR7## or (4) --(CH.sub.2).sub.n --O--(CH.sub.2).sub.n -- wherein n is 2 or 3; andX.sup..crclbar. is an anion derived from an organic or mineral acid.
    • 用作毛发或皮肤美容剂的季铵化聚合物具有下式的重复单元:其中R是低级烷基或-CH 2 -CH 2 OH; R'是含有至多20个碳原子的脂族,脂环族或芳基脂族基团,或者R和R'与它们所连接的氮原子一起形成能够含有氮以外的杂原子的杂环; A是式(1)式,其中x,y和t是0到11的整数,所以和(x + y + t)的和(x + y + t)大于 或等于0且低于18,并且E和K表示氢或具有少于18个碳原子的脂族基团,(3) - (CH 2)n -S-(CH 2)n + 13,(4) - (CH 2)n O - (CH2)n-,(5) - (CH2)nSS-(CH2)n-,(6) - (CH2)n-SO-(CH2)n-,(7) - (CH2) (CH 2)n - 或其中n等于2或3; B表示式(1)式,其中D和G表示氢或具有少于18个碳原子的脂族基团,v,z和u的整数为 0至11,其中v,z和u中的两个同时能够为0,因此和(v + z + u)大于或等于1并且低于18,因此和(v + z + u) (x + y + t)等于0,(3)或(4) - (CH2)nO-(CH2)n-,其中n为2或3; 而X( - )是衍生自有机或无机酸的阴离子。