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    • 46. 发明授权
    • Photopolymerizable compositions having combined photoinitiators
    • 具有组合光引发剂的光聚合组合物
    • US4259432A
    • 1981-03-31
    • US82361
    • 1979-10-05
    • Syunichi KondohAkihiro MatsufujiYuji OharaAkira Umehara
    • Syunichi KondohAkihiro MatsufujiYuji OharaAkira Umehara
    • C08F2/00C08F2/50C08F2/54G03F7/031G03F7/038G03C1/68
    • G03F7/031Y10S430/106Y10S430/117
    • In a photopolymerizable composition comprising (1) an addition-polymerizable compound having at least one ethylenically unsaturated double bond and (2) a photopolymerization initiator as essential components, the improvement which comprises that said photopolymerization initiator is a combination of (a) p-dialkylamino aromatic carbonyl compounds represented by the general formulae (1) to (4), (b) 5-isoxazolones represented by the general formula (5) and (c) 2,4,6-substituted-1,3,5-triazines represented by the general formula (6): ##STR1## where R.sup.1, R.sup.2 and R.sup.3 each represents an alkyl group or a substituted alkyl group, which may be the same or different from one another, X represents a substituent having a Hammett's .sigma. value in the range from -0.9 to 0.7, m represents 1 or 2, A.sup.1 and A.sup.2 each represents an alkyl group, a substituted alkyl group, an alkylcarbonyl group, an alkoxycarbonyl group, an aryl group, a substituted aryl group, an arylcarbonyl group or a hydrogen atom, which may be the same or different from each other, and R.sup.4, R.sup.5 and R.sup.6 each represents an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group or an aralkyl group, which may be the same or different from each other, but at least one of them represents a mono-, di- or trihalomethyl group.
    • 在包含(1)具有至少一个烯属不饱和双键的加成聚合性化合物和(2)光聚合引发剂作为必要成分的光聚合性组合物中,包括所述光聚合引发剂是(a)对二烷基氨基 由通式(1)至(4)表示的芳族羰基化合物,(b)由通式(5)和(c)表示的5-异恶唑酮,表示为2,4,6-取代的1,3,5-三嗪 (6)其中R1,R2和R3(6)表示:(1) 各自表示烷基或取代的烷基,其可以相同或不同,X表示哈米特σ值在-0.9至0.7范围内的取代基,m表示1或2,各自为A1和A2 表示烷基,取代的烷基,烷基羰基,烷氧基羰基,芳基,取代的a Ryl基,芳基羰基或氢原子,可以相同或不同,R4,R5和R6各自表示烷基,取代的烷基,芳基,取代的芳基或芳烷基 基团可以相同或不同,但其中至少一个表示一,二或三卤代甲基。