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41. 发明授权

US07993799B2 Optical components made from photosensitive inorganic/organic hybrid materials 失效
标题翻译：由光敏无机/有机杂化材料制成的光学部件
公开(公告)号：US07993799B2
公开(公告)日：2011-08-09
申请号：US11721206
申请日：2005-12-19
申请人： Martin Mennig , Peter William Oliveira
发明人： Martin Mennig , Peter William Oliveira
IPC分类号： G03H1/02 , G02B3/00 , G02B6/18
CPC分类号： C08J5/005 , B82Y30/00 , G02B1/04 , G02B3/0087 , G11B7/251
摘要： An organic-inorganic hybrid material comprising (a) at least one soluble organic polymer, (b) at least one mono- or polynuclear metal complex having at least one ligand which comprises at least one photochemically and/or thermally polymerizable functional group and (c) surface-modified nanoscale particles. Also disclosed is an optical component which is made by using the hybrid material.
摘要翻译：一种有机 - 无机混合材料，其包含（a）至少一种可溶性有机聚合物，（b）至少一种具有至少一个配体的单 - 或多核金属络合物，其包含至少一种光化学和/或热聚合官能团和（c ）表面改性纳米级颗粒。还公开了通过使用混合材料制成的光学部件。

42. 发明申请

US20100203308A1 Production of a flexible, gas-tight,and transparent composite film 审中-公开
标题翻译：生产柔性，气密，透明的复合膜
公开(公告)号：US20100203308A1
公开(公告)日：2010-08-12
申请号：US12311563
申请日：2007-10-02
申请人： Martin Mennig , Peter Rogin , Markus Sauer
发明人： Martin Mennig , Peter Rogin , Markus Sauer
IPC分类号： B32B17/04 , C03B29/00
CPC分类号： B32B37/26 , B32B17/06 , B32B37/15 , B32B2305/80 , B32B2307/412 , B32B2315/08 , B32B2553/00
摘要： The invention relates to a method for the production of a flexible, gas-tight, and transparent composite film, comprising a transparent carrier layer made of plastic and a glass-like layer. The method comprises the following steps: a) a temperature-resistant substrate is coated with a lacquer comprising glass or glass-forming pre-stages by a wet chemical process, b) the coating is thermally compressed to form the glass-like layer, c) the transparent carrier layer made of plastic is applied onto the glass-like layer and bonded thereto, and d) the composite of the carrier layer and the glass-like layer is separated from the substrate. The composite films obtained in this way are suitable as encapsulation material or packing material, particularly for the use in displays, illumination and photovoltaics, for example for light-emitting diodes, solar cells, displays, or electronic circuits.
摘要翻译：本发明涉及一种用于制造柔性，气密且透明的复合膜的方法，其包括由塑料和玻璃状层制成的透明载体层。该方法包括以下步骤：a）耐温基材通过湿法化学工艺涂覆有包含玻璃或玻璃形成预成型漆的漆，b）将该涂层热压缩以形成玻璃状层，c ）将由塑料制成的透明载体层施加到玻璃状层上并结合到其上，d）将载体层和玻璃状层的复合物与基板分离。以这种方式获得的复合膜适合作为封装材料或包装材料，特别是用于显示器，照明和光伏，例如用于发光二极管，太阳能电池，显示器或电子电路。

43. 发明申请

US20100178491A1 ULTRA-HARD COMPOSITE LAYERS ON METAL SURFACES AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：金属表面上的超硬复合层及其制造方法
公开(公告)号：US20100178491A1
公开(公告)日：2010-07-15
申请号：US12666540
申请日：2008-06-26
申请人： Martin MENNIG , Helmut SCHMIDT
发明人： Martin MENNIG , Helmut SCHMIDT
IPC分类号： B32B5/16 , B32B5/00 , B05D3/02
CPC分类号： C23C18/1279 , C23C18/1212 , C23C18/1225 , C23C18/1241 , C23C18/1254 , C23C18/1266 , C23C18/1275 , Y10T428/24388 , Y10T428/249921 , Y10T428/25 , Y10T428/252 , Y10T428/256 , Y10T428/257 , Y10T428/258 , Y10T428/259 , Y10T428/265
摘要： The invention relates to a metal substrate comprising an ultra-hard composite layer consisting of an inorganic, vitreous matrix containing one or more abrasive fillers. According to the invention, the diameter of the filler particles or, if the filler particles have a platelet-type form, the thickness of the filler particles is less than the layer thickness of the composite layer.
摘要翻译：本发明涉及包含由含有一种或多种磨料填料的无机玻璃质基质组成的超硬复合层的金属基材。根据本发明，填料颗粒的直径，或者如果填料颗粒具有血小板形式，填料颗粒的厚度小于复合层的层厚度。

44. 发明申请

US20060057398A1 Plastic film with a multilayered interference coating 有权
标题翻译：塑料薄膜与多层干涉涂层
公开(公告)号：US20060057398A1
公开(公告)日：2006-03-16
申请号：US10508193
申请日：2003-03-14
申请人： Andreas Zimmermann , Furnio Kita , Anette Berni , Martin Mennig , Peter Oliveira , Helmut Schmidt , Takamasa Harada
发明人： Andreas Zimmermann , Furnio Kita , Anette Berni , Martin Mennig , Peter Oliveira , Helmut Schmidt , Takamasa Harada
IPC分类号： B32B17/06 , B32B9/00 , B32B19/00
CPC分类号： G02B5/0841 , B32B27/06 , C08J7/047 , C08J7/16 , G02B1/11 , Y10T428/24942 , Y10T428/256
摘要： The invention relates to a plastic film with an interference multilayer system applied thereon that comprises at least two layers. Said layers can be obtained by hardening and/or applying thermal treatment to a coating composition containing nanoscale inorganic solid particles having polymerizable and/or polycondensable organic surface groups, thereby forming a layer that is crosslinked by means of the polymerizable and/or polycondensable organic surface groups. The films can be used as optical laminating film.
摘要翻译：本发明涉及一种其上施加有干涉多层系统的塑料膜，其包括至少两层。所述层可以通过硬化和/或施加热处理获得，所述涂层组合物含有具有可聚合和/或可缩聚有机表面基团的纳米级无机固体颗粒，由此形成通过可聚合和/或可缩聚有机表面交联的层团体该膜可用作光学层压膜。

45. 发明申请

US20050101698A1 Nanocomposite material for the production of index of refraction gradient films 有权
$Nanocomposite material for the production of index of refraction gradient films$
标题翻译：用于生产折射率梯度膜的纳米复合材料
公开(公告)号：US20050101698A1
公开(公告)日：2005-05-12
申请号：US10500194
申请日：2003-01-03
申请人： Takamasa Harada , Fumio Kita , Andreas Zimmermann , Ulrike Dellwo , Martin Mennig , Peter Oliveira , Helmut Schmidt , Heike Schneider
发明人： Takamasa Harada , Fumio Kita , Andreas Zimmermann , Ulrike Dellwo , Martin Mennig , Peter Oliveira , Helmut Schmidt , Heike Schneider
IPC分类号： G03H1/02 , B32B27/18 , C08J7/04 , C08K3/00 , C08K9/04 , C08L83/04 , C08L101/00 , C09D4/02 , C09D7/12 , C09D163/00 , C09D183/06 , C09D183/07 , C09D201/00 , G02B1/04 , G02B3/00 , C08K9/10
CPC分类号： C08L83/06 , C08K3/013 , C09D183/06 , G02B1/04 , G03H2260/12 , C08L2666/04
摘要： The invention relates to solid or gel-type nanocomposite material which can be polymerised, containing a) 4.9 95.9 wt. % of a soluble polymer; b) 4-95 wt. % of a partially or totally condensed silane selected from the group of epoxyalkoxysilanes, alkoxysilanes and alkylalkoxysilanes, the silane having an inorganic condensation degree of between 33-100% and an organic conversion degree of between 0-95%; c) 0-60 wt. % of an acrylate; d) 0.1-50 wt. % of surface modified nanometric particles selected from the group of oxides, sulphides, selenides, tellurides, halogenides, carbides, arsenides, antimonides, nitrides, phosphides, carbonates, carboxylates, phosphates, sulphates, silicates, titanates, zirconates, aluminates, stannates, plumbates and a mixed oxides; e) 0-50 wt.-% of a plasticiser, f) 0-5 wt. % of a thermal or photochemical cross-linking initiator, sensitizer, auxiliary wetting agent, adhesive agent, antioxidant, stabiliser, colouring agent, photochrome material and thermochrome material in relation to the total weight (dry weight) of the nanocomposite material.
摘要翻译：本发明涉及可以聚合的固体或凝胶型纳米复合材料，其包含a）4.9 95.9wt。％的可溶性聚合物; b）4-95wt。选自环氧烷氧基硅烷，烷氧基硅烷和烷基烷氧基硅烷的部分或全部冷凝的硅烷的％，硅烷的无机缩合度在33-100％之间，有机转化度在0-95％之间; c）0-60wt。％的丙烯酸酯; d）0.1-50wt。选自氧化物，硫化物，硒化物，碲化物，卤化物，碳化物，砷化物，锑化物，氮化物，磷化物，碳酸盐，羧酸盐，磷酸盐，硫酸盐，硅酸盐，钛酸盐，锆酸盐，铝酸盐，锡酸盐，铅酸铅的表面改性纳米颗粒的％和混合氧化物; e）0-50重量％的增塑剂，f）0-5重量％相对于纳米复合材料的总重量（干重），热或光化学交联引发剂，敏化剂，辅助润湿剂，粘合剂，抗氧化剂，稳定剂，着色剂，感光材料和热变色材料的％。

46. 发明授权

US06863923B1 Method and compositions for printing substrates 失效
标题翻译：用于印刷基材的方法和组合物
公开(公告)号：US06863923B1
公开(公告)日：2005-03-08
申请号：US10088794
申请日：2000-09-28
申请人： Axel Kalleder , Rainer Kreutzer , Martin Mennig , Helmut Schmidt
发明人： Axel Kalleder , Rainer Kreutzer , Martin Mennig , Helmut Schmidt
IPC分类号： H01B1/20 , B41M1/12 , B41M1/26 , B41M1/28 , B41M1/30 , B41M1/34 , B41M7/00 , C03C17/00 , C08L83/04 , H01B13/00 , H01L21/48 , H05K1/09 , B05D3/02
CPC分类号： H01L21/4867 , B41M1/12 , B41M1/26 , B41M1/28 , B41M1/30 , B41M1/34 , B41M7/009 , C03C17/007 , C03C17/008 , C03C2217/445 , C03C2217/475 , C03C2217/479 , C03C2217/485 , C03C2218/113 , C08G77/04 , C08G77/045 , C08G77/16 , C08L83/04 , H05K1/092 , H05K1/095 , Y10T428/31663 , C08L2666/54
摘要： Processes and compositions for printing substrates. A printing paste containing a matrix-forming precondensate containing polyorganosiloxanes obtained by a sol-gel process and at least one coloring, luminescent, conductive and/or catalytically active filler is applied imagewise to the substrate and is densified by heat treatment at a temperature below the glass transition temperature of the matrix being formed. The processes and printing pastes are suitable, for example, for the production of conductor tracks and decorative patterns.
摘要翻译：用于印刷基材的方法和组合物。将含有通过溶胶 - 凝胶法和至少一种着色，发光，导电和/或催化活性填料获得的含有聚有机硅氧烷的基质形成预缩合物的印刷浆料成像施加到基材上，并通过在低于形成基体的玻璃化转变温度。工艺和印刷浆料适用于例如生产导体轨迹和装饰图案。

47. 发明授权

US06790532B1 Coating composition, based on organically modified inorganic condensates 失效
标题翻译：涂料组合物，基于有机改性无机缩合物
公开(公告)号：US06790532B1
公开(公告)日：2004-09-14
申请号：US10111175
申请日：2002-04-18
申请人： Andreas Gier , Martin Mennig , Helmut Schmidt
发明人： Andreas Gier , Martin Mennig , Helmut Schmidt
IPC分类号： B32B904
CPC分类号： C09D183/08 , C03C17/30 , C09D183/14 , Y10T428/31663
摘要： A coating composition comprises a polycondensate obtained by reacting a prehydrolysate based on at least on epoxide-containing hydrolysable silane; at least one amine component selected from a prehydrolysate based on at least one amino-containing hydrolysable silane and an amine compound containing at least two amino groups; and an amino group protective reagent. The coating composition is particulary suitable for coating glass, glass ceramic, ceramic, and plastic, and permits an increase in strength and protection against damage.
摘要翻译：涂料组合物包含通过基于至少含有环氧化物的可水解硅烷使预水解产物反应获得的缩聚物; 至少一种胺组分，其选自基于至少一种含氨基的可水解硅烷的预水解产物和含有至少两个氨基的胺化合物; 和氨基保护试剂。涂料组合物特别适用于涂覆玻璃，玻璃陶瓷，陶瓷和塑料，并且允许增加强度和防止损坏。

48. 发明授权

US06378599B1 Foundry binder 有权
标题翻译：铸造粘合剂
公开(公告)号：US06378599B1
公开(公告)日：2002-04-30
申请号：US09297572
申请日：1999-05-03
申请人： Helmut Schmidt , Martin Mennig , Gerhard Jonschker
发明人： Helmut Schmidt , Martin Mennig , Gerhard Jonschker
IPC分类号： B22C116
CPC分类号： C09C3/12 , C01P2004/64 , C03C17/007 , C03C2217/445 , C03C2217/475 , C09D183/04 , C08L2666/54
摘要： A foundry binder is obtainable by surface modification of a) colloidal inorganic particles with b) one or more silanes of the general formula (I) Rx—Si—A4−x (I) where the radicals A are identical or different and are hydroxyl groups or groups which can be removed hydrolytically, except methoxy, the radicals R are identical or different and are groups which cannot be removed hydrolytically and x is 0, 1, 2 or 3, where x≧1 in at least 50 mol % of the silanes; under the conditions of the sol-gel process with a below-stoichiometric amount of water, based on the hydrolysable groups which are present, with formation of a nanocomposite sol, and further hydrolysis and condensation of the nanocomposite sol, if desired, before it is brought into contact with the foundry sand.
摘要翻译：一种铸造粘结剂可以通过a）胶体无机颗粒的表面改性获得，b）一种或多种通式（I）的硅烷，其中基团A相同或不同，并且是羟基或水解除外的基团，除了甲氧基，基团R相同或不同，并且是不能被水解除去的基团，x是0,1,2或3，其中在至少50mol％的硅烷中x> = 1;在溶胶 - 凝胶法与基于存在的可水解基团，形成纳米复合溶胶的低于化学计算量的水，并且如果需要，在与铸造砂接触之前，进一步水解和缩合纳米复合溶胶。

49. 发明授权

US06255477B1 Particles having a magnetic core and outer glass layer for separating biological material 失效
标题翻译：具有用于分离生物材料的磁芯和外部玻璃层的颗粒
公开(公告)号：US06255477B1
公开(公告)日：2001-07-03
申请号：US08952969
申请日：1998-03-11
申请人： Jörg Kleiber , Thomas Walter , Herbert Harttig , Christoph Lesniak , Martin Mennig , Michael Riedling , Helmut Schmidt
发明人： Jörg Kleiber , Thomas Walter , Herbert Harttig , Christoph Lesniak , Martin Mennig , Michael Riedling , Helmut Schmidt
IPC分类号： C12N1500
CPC分类号： C03C3/111 , B03C1/01 , B82Y25/00 , C03C3/078 , C03C3/083 , C03C3/085 , C03C3/087 , C03C3/089 , C03C3/091 , C03C3/102 , C03C3/105 , C03C3/108 , C07H21/00 , C12N15/1013 , C12Q1/6804 , C12Q1/6806 , C12Q1/6834 , H01F1/0063 , H01F1/112 , H01F1/36 , Y10S428/90 , Y10S435/814 , Y10T428/2996
摘要： Magnetic glass particles are prepared containing a magnetic core coated with a glass layer having a substantially pore-free glass surface. The particles are used for separating biological material such as nucleic acids. A preferred process of preparing the particles is by forming a mixture of magnetic cores with a sol formed from an alcohol and a metal alkoxide, spray-drying the mixture to coat the cores with a layer of gelled sol, and heating the coated cores to obtain the magnetic glass particles. Preferably, the particles have an average particle size of less than 100 &mgr;m and any pores of the glass surface have a diameter of less than 10 nm. The magnetic core may be a composite material containing a mica core and magnetite particles immobilized on the mica core, and the glass layer may contain boron oxide. Magnetic core materials include magnetite (Fe3O4) and Fe2O3. In using the magnetic glass particles to separate a biological material, the particles are contacted with a fluid containing the biological material such that the biological material binds to the glass surface, and the bound biological material is separated from the fluid such as by using a magnetic field. Before applying a magnetic field, the magnetic particles may sediment when contacted with the biological material.
摘要翻译：制备磁性玻璃颗粒，其包含涂覆有具有基本无孔玻璃表面的玻璃层的磁芯。颗粒用于分离生物材料如核酸。制备颗粒的优选方法是通过用由醇和金属醇盐形成的溶胶形成磁芯的混合物，喷雾干燥混合物以用一层凝胶溶胶涂覆芯，并加热涂覆的芯以获得磁性玻璃颗粒。优选地，颗粒的平均粒度小于100μm，并且玻璃表面的任何孔具有小于10nm的直径。磁芯可以是包含固定在云母芯上的云母芯和磁铁矿颗粒的复合材料，并且玻璃层可以含有氧化硼。磁芯材料包括磁铁矿（Fe3O4）和Fe2O3。在使用磁性玻璃颗粒分离生物材料时，颗粒与包含生物材料的流体接触，使得生物材料结合到玻璃表面，并且结合的生物材料与流体分离，例如通过使用磁性领域。在施加磁场之前，当与生物材料接触时，磁性颗粒可能沉淀。

50. 发明授权

US6162498A Method for providing a metal surface with a vitreous layer 有权
标题翻译：提供具有玻璃质层的金属表面的方法
公开(公告)号：US6162498A
公开(公告)日：2000-12-19
申请号：US402742
申请日：1999-10-08
申请人： Martin Mennig , Gerhard Jonschker , Helmut Schmidt
发明人： Martin Mennig , Gerhard Jonschker , Helmut Schmidt
IPC分类号： C03C1/00 , C23C18/12 , B05D3/02
CPC分类号： C03C1/008 , C03C2207/00 , C03C2207/04 , C03C2207/08 , C23C18/1212 , C23C18/1225 , C23C18/1241 , C23C18/127 , C23C18/1295 , Y02T50/67
摘要： Disclosed is a process for providing a metallic surface with a vitreous layer which is both decorative and scratch resistant and corrosion inhibiting. Said process is characterized in that a coating composition which is obtainable by a process comprising the hydrolysis and polycondensation of one or more silanes of the general formula (I)R.sub.n SiX.sub.4-n (I)wherein the groups X, the same or different from each other, are hydrolyzable groups or hydroxyl groups, the radicals R, the same or different from each other, represent hydrogen, alkyl, alkenyl or alkynyl groups having up to 12 carbon atoms and aryl, aralkyl and alkaryl groups having 6 to 10 carbon atoms, and n is 0, 1 or 2, provided that at least one silane with n=1 or 2 is employed, or oligomers derived therefrom, in the presence ofa) nanoscaled SiO.sub.2 particles and/orb) at least one compound selected from the group consisting of the oxides and hydroxides of the alkali and alkaline earth metals;is applied onto said metallic surface and the resulting coating is thermally densified to form a vitreous layer.
摘要翻译： PCT No.PCT / EP98 / 02076 Sec。 371 1999年10月8日第 102（e）1999年10月8日PCT PCT 1998年4月9日PCT公布。公开号WO98 / 45502 日期1998年10月15日公开是为金属表面提供玻璃质层的方法，其具有装饰性和耐刮擦性和腐蚀抑制性。所述方法的特征在于，通过包括通式（I）的R 1 SiX 4-n（I）的一种或多种硅烷的水解和缩聚的方法获得的涂料组合物，其中基团X彼此相同或不同是可水解基团或羟基，基团R彼此相同或不同，表示具有至多12个碳原子的氢，烷基，烯基或炔基和具有6至10个碳原子的芳基，芳烷基和烷芳基，以及 n是0,1或2，条件是在a）纳米尺度的SiO 2颗粒和/或b）存在下，使用至少一种n = 1或2的硅烷或由其衍生的低聚物，或b）至少一种选自以下的化合物由碱金属和碱土金属的氧化物和氢氧化物组成; 施加到所述金属表面上，并将所得涂层热致密化以形成玻璃质层。

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