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    • 36. 发明授权
    • Bismuth generator method
    • 铋发生器方法
    • US5749042A
    • 1998-05-05
    • US789973
    • 1997-01-28
    • Lane Allan BrayJaquetta R. DesChane
    • Lane Allan BrayJaquetta R. DesChane
    • G21G4/08B01D15/04B01D59/30B01J20/22B01J20/26B01J41/04B01J49/00C01G29/00C01G30/00C22B30/06
    • C01G30/001C22B3/42C22B30/06Y02P10/234
    • A method for separating .sup.213 Bi from a solution of radionuclides wherein the solution contains a concentration of the chloride ions and hydrogen ions adjusted to allow the formation of a chloride complex. The solution is then brought into contact with an anion exchange resin, whereupon .sup.213 Bi is absorbed from the solution and adhered onto the anion exchange resin in the chloride complex. Other non-absorbing radionuclides such as .sup.225 Ra, .sup.225 Ac, and .sup.221 Fr, along with HCl are removed from the anion exchange resin with a scrub solution. The .sup.213 Bi is removed from the anion exchange resin by washing the anion exchange resin with a stripping solution free of chloride ions and with a reduced hydrogen ion concentration which breaks the chloride anionic complex, releasing the .sup.213 Bi as a cation. In a preferred embodiment of the present invention, the anion exchange resin is provided as a thin membrane, allowing for extremely rapid adherence and stripping of the .sup.213 Bi. A preferred stripping solution for purification of .sup.213 Bi for use in medical applications includes sodium acetate, pH 5.5. A protein conjugated with bifunctional chelating agents in vivo with the NaOAc, to receive the .sup.213 Bi as it is being released from the anion exchange resin.
    • 一种从放射性核素溶液中分离213Bi的方法,其中溶液含有氯离子和氢离子的浓度以调节以形成氯化物络合物。 然后使溶液与阴离子交换树脂接触,于是溶液中吸收213Bi并附着到氯化物络合物中的阴离子交换树脂上。 使用洗涤溶液从阴离子交换树脂中除去其它非吸收放射性核素如225Ra,225Ac和221Fr以及HCl。 通过用不含氯离子的剥离溶液洗涤阴离子交换树脂,并且以降低的氢离子浓度破坏氯化物阴离子络合物,从而将213Bi从阴离子交换树脂中除去,释放213Bi作为阳离子。 在本发明的一个优选实施方案中,阴离子交换树脂被提供为薄膜,允许极快速地粘附和剥离213Bi。 纯化用于医疗应用的213Bi的优选的汽提溶液包括乙酸钠,pH5.5。 与NaOAc一起体内与双功能螯合剂缀合的蛋白质,以便从阴离子交换树脂中释放出213Bi。
    • 37. 发明授权
    • Antimony pentafluoride
    • 五氟化锑
    • US5618503A
    • 1997-04-08
    • US671582
    • 1996-06-28
    • Alan JohnsonH. J. WoodsH. J. Connor
    • Alan JohnsonH. J. WoodsH. J. Connor
    • B01J27/12C01G30/00C01G28/00
    • B01J27/12C01G30/007
    • A method of preparing antimony pentafluoride comprising converting antimony compounds to hydroxonium fluoroantimonates by reaction of the antimony compounds with fluorinating material, such as hydrogen fluoride, in the presence of an oxidizing agent, such as hydrogen peroxide, removing water from the reaction product to concentrate the hydroxonium fluoroantimonates and reacting the hydroxonium fluoroantimonates with carbonyl difluoride to produce antimony pentafluoride. In one embodiment the hydroxonium fluoroantimonates are prepared by recovering the antimony from spent alkylation catalyst comprising SbF.sub.5 deposited on silica. The silica can also be recovered and recycled to produce a remanufactured alkylation catalyst.
    • 一种制备五氟化锑的方法,其包括在氧化剂如过氧化氢存在下,通过锑化合物与氟化物等氟化物质的反应,将锑化合物转化成氟代异头翁酸,从反应产物中除去水 氟代异羟肟酸酯,并使氟代异羟肟酸羟基与二氟化碳羰基反应,生成五氟化锑。 在一个实施方案中,通过从沉积在二氧化硅上的包含SbF 5的废烷基化催化剂回收锑来制备氟代异头物。 二氧化硅也可回收再循环,生产再制烷基化催化剂。
    • 38. 发明授权
    • Process for preparing fine powder of perovskite-type compound
    • 钙钛矿型化合物细粉的制备方法
    • US5445806A
    • 1995-08-29
    • US845670
    • 1992-03-04
    • Masanori KinugasaNaoto TsubomotoOsamu Kobayashi
    • Masanori KinugasaNaoto TsubomotoOsamu Kobayashi
    • C01B13/36C01G23/00C01G25/00C01G30/00C01G30/02C01G33/00C01G49/00C01F5/00C01F11/00
    • C01G33/00C01B13/363C01G23/003C01G23/006C01G25/006C01G30/00C01G30/026C01G49/009C01P2002/34C01P2002/72C01P2002/77C01P2004/03C01P2004/52C01P2004/62C01P2006/32C01P2006/80
    • A process for preparing a fine powder of perovskite-type compounds having an average particle size of at most 0.3 .mu.m and uniform particle sizes, which comprises subjecting to a reaction an aqueous solution of a mixture of at least one compound selected from group A element compounds comprising alkaline earth metal elements and/or bivalent metal elements with at least one compound selected from group B element compounds comprising tetravalent metal elements such as Ti, Zr, Hf and Sn and/or composite metal elements composed of a bivalent or trivalent metal element such as Zn, Ni, Co, Mg, Fe or Sb and a pentavalent metal element such as Nb or Sb in an A/B atomic ratio of more than 1, calcining the resulting powdery reaction product at a temperature which is lower than the temperature at which the growth of particles takes place and which is higher than the temperature at which the growth of particles takes place when A/B is 1, and cleaning the calcined product with an acid solution to remove the excess group A elements. The process provides fine powders of perovskite-type compounds having a good crystallinity, particularly tetragonal barium titanate, which are useful particularly as raw materials of ceramics for electronic devices.
    • 一种平均粒径为0.3μm以上且平均粒径的钙钛矿型化合物的微细粉末的制造方法,其特征在于,将至少一种选自A族元素的化合物的混合物的水溶液 包含碱土金属元素和/或二价金属元素的化合物与至少一种选自包含四价金属元素如Ti,Zr,Hf和Sn的B族元素化合物和/或由二价或三价金属元素组成的复合金属元素 例如Zn,Ni,Co,Mg,Fe或Sb以及A / B原子比大于1的Nb或Sb的五价金属元素,在低于温度的温度下煅烧所得粉末状反应产物 当A / B为1时,发生颗粒的生长并且高于发生颗粒生长的温度,并且用酸溶液将煅烧产物清洗成r 排除多余的A组元素。 该方法提供具有良好结晶度的钙钛矿型化合物的细粉末,特别是四方晶系钛酸钡,其特别用作电子器件用陶瓷的原料。
    • 40. 发明授权
    • Process for hydrometallurgical treatment of an indium chloride solution
    • 氯化铟溶液湿法冶金处理工艺
    • US5019363A
    • 1991-05-28
    • US391531
    • 1989-07-19
    • Yves Le QuesnePaolo Fossi
    • Yves Le QuesnePaolo Fossi
    • C01G15/00C01G19/00C01G30/00C22B3/38C22B58/00
    • C22B58/00C01G15/003C01G19/003C01G30/001C22B3/0068Y02P10/234
    • A process for the hydrometallurgical treatment of an indium chloride solution and at least one element selected from the group consisting of tin and antimony comprises the following steps: a) adjustment of the free chloride ion content by addition of alkaline or alkaline earth chloride or a mixture thereof and of their acidity by the addition of hydrochloric acid; b) bringing said indium chloride solution into contact with an organic phase containing dry trialkyl phosphate; c) extraction of said organic phase by bringing the latter into contact with a 0.1 to 3 N hydrochloric acid solution to obtain an indium chloride solution; d) basic extraction using an alkaline metal hydroxyde. Application to extractive metallurgy and recovery of indium and accompanying elements.
    • PCT No.PCT / FR88 / 00573 Sec。 371日期:1989年7月19日 102(e)日期1989年7月19日PCT提交1988年11月24日PCT公布。 出版物WO89 / 04877 日期:1989年6月1日。用于对氯化铟溶液和选自锡和锑的至少一种元素进行湿法冶金处理的方法包括以下步骤:a)通过加入碱来调节游离氯离子含量 或碱土金属氯化物或其混合物,并通过加入盐酸使其酸度; b)使所述氯化铟溶液与含有干燥的三烷基磷酸酯的有机相接触; c)通过使所述有机相与0.1至3N盐酸溶液接触以提取所述有机相,得到氯化铟溶液; d)使用碱金属氢氧化物进行碱性萃取。 应用于萃取冶金和铟和伴生元素的回收。