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    • 39. 发明授权
    • Reactions with undesirable components in a coking process
    • 在焦化过程中与不合需要的组分反应
    • US09187701B2
    • 2015-11-17
    • US14074150
    • 2013-11-07
    • Roger G. Etter
    • Roger G. Etter
    • C10B57/12C10B55/00C10G11/14C10G9/00C10G11/00F17D3/00C10B55/02C10B55/04
    • C10G11/14C10B55/00C10B57/12C10G9/005C10G11/00C10G2300/1059C10G2300/1096C10G2300/701C10G2300/708C10G2300/80C10G2300/805C10G2300/807C10G2400/02C10G2400/04C10G2400/06C10G2400/08F17D3/00Y10T137/0318
    • Undesirable components of traditional coking processes are selectively cracked or coked in the coking vessel by injecting an additive into the vapors in the coking vessel. The additive contains catalyst(s), seeding agent(s), excess reactant(s), quenching agent(s), carrier(s), or any combination thereof to modify reaction kinetics to preferentially crack (or coke) these undesirable components that typically have a high propensity to coke, and are often precursors to coke in the coking process. These undesirable components can also be very problematic in downstream catalytic cracking processes, significantly contributing to coke on catalyst and catalyst deactivation. Exemplary embodiments of the present invention also provide methods to (1) decrease coke production, (2) increase liquid transportation fuels, (3) control the coke crystalline structure, and (4) control the quantity and quality of volatile combustible materials (VCMs) in the resulting coke. Pet coke from this process may have unique characteristics with substantial utility.
    • 传统焦化工艺中不合需要的组分通过将焦化容器中的蒸气注入添加剂中而在焦化容器中选择性裂化或焦化。 添加剂含有催化剂,接种剂,过量反应物,猝灭剂,载体或其任何组合以改善反应动力学以优先裂化(或焦化)这些不期望的组分, 通常具有很高的焦炭倾向,并且通常在焦化过程中焦炭的前体。 这些不合需要的组分在下游催化裂化过程中也是非常有问题的,显着地促进了催化剂上的焦炭和催化剂失活。 本发明的示例性实施例还提供了(1)减少焦炭生产的方法,(2)增加液体运输燃料,(3)控制焦炭结晶结构,以及(4)控制挥发性可燃材料(VCM)的数量和质量, 在所产生的焦炭中。 来自该过程的宠物焦炭可能具有独特的特征,具有实用性。