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    • 31. 发明授权
    • Expansion temperature tolerant dry expandable sealant and baffle product
and method of preparing same
    • 膨胀耐温可膨胀密封剂和挡板产品及其制备方法
    • US6150428A
    • 2000-11-21
    • US407820
    • 1999-09-28
    • John L. Hanley, IVNorman E. Blank
    • John L. Hanley, IVNorman E. Blank
    • C08J9/10B60R13/08C08G59/40C08K3/00C08K7/20C08L63/00C08L101/00C09K3/10C08J9/00
    • B60R13/08C09K3/10C09K2200/047C09K2200/0607C09K2200/062C09K2200/0622C09K2200/0635C09K2200/0687
    • An expansion temperature tolerant, dry, expandable sealant and baffle is provided which is capable of undergoing a desired degree of full expansion when an automobile body containing the sealant and baffle product is conveyed through a conventional bake and/or curing oven. The sealant and baffle product is fully expandable over a wider temperature and time range than heretofore available expandable baffle products. The composition for preparation of a molded expandable sealant and baffle component includes a grafted anhydride polymer, an epoxide terminated additive polymer which are capable of reacting with the grafted anhydride polymer and a blowing agent. The anhydride polymer and the epoxide terminated polymer react to a limited degree in the absence of a catalyst when the baffle product is heated in the bake and/or curing oven, thus providing an improved networked and bridged backbone polymer which effectively entraps gas emanating from the blowing agent, without adversely affecting the flexibility and expansion characteristics of the sealant baffles.
    • 提供了一种膨胀耐温,干燥,可膨胀的密封剂和挡板,当含有密封剂和挡板产品的汽车车身通过常规的烘烤和/或固化炉输送时,其能够经历所需的充分膨胀程度。 密封剂和挡板产品在比迄今为止可用的可膨胀挡板产品更宽的温度和时间范围内完全可膨胀。 用于制备可模制的可膨胀密封剂和挡板组分的组合物包括能够与接枝的酸酐聚合物和发泡剂反应的接枝的酸酐聚合物,环氧化物封端的添加剂聚合物。 当在烘烤和/或固化炉中加热挡板产物时,酸酐聚合物和环氧化物封端的聚合物在不存在催化剂的情况下有一定程度的反应,从而提供改进的网络化和桥连骨架聚合物,其有效地捕集从 发泡剂,而不会不利地影响密封剂挡板的柔性和膨胀特性。