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31. 发明授权

US4999248A Amorphous copolymers of perfluoro-2,2-dimethyl-1,3-dioxole 失效
公开(公告)号：US4999248A
公开(公告)日：1991-03-12
申请号：US509409
申请日：1990-04-09
申请人： Edward N. Squire
发明人： Edward N. Squire
IPC分类号： C08F234/02 , H05K1/03 , H05K3/28
CPC分类号： C08F234/02 , H05K1/034 , H05K3/285 , Y10T428/31544
摘要： Articles made from amorphous dipolymers of perfluoro-2,2-dimethyl-1,3-dioxole with tetrafluoroethylene having high glass transition temperatures of 140.degree. C. or higher, low indices of refraction, and good physical properties, and low dielectric constants, include, among others, substrates for circuit boards, composites, sheets and films, optical lenses, and electronic current carrying devices.

32. 发明授权

US4985308A Amorphous copolymers of perfluoro-2,2-dimethyl-1,3-dioxole 失效
公开(公告)号：US4985308A
公开(公告)日：1991-01-15
申请号：US509410
申请日：1990-04-09
申请人： Edward N. Squire
发明人： Edward N. Squire
IPC分类号： C08F234/02 , H05K1/03 , H05K3/28
CPC分类号： C08F234/02 , H05K1/034 , H05K3/285 , Y10T428/31544 , Y10T428/31699
摘要： Articles made from amorphous dipolymers of perfluoro-2,2-dimethyl-1,3-dioxole with tetrafluoroethylene having high glass transition temperatures of 140.degree. C. or higher, low indices of refraction, and good physical properties, and low dielectric constants, include, among others, substrates for circuit boards, composites, sheets and films, optical lenses, and electronic current carrying devices.

33. 发明授权

US4977026A Amorphous copolymers of perfluoro-2,2-dimethyl-1,3-dioxole 失效
标题翻译：全氟-2,2-二甲基-1,3-二氧杂环戊烯的无定形共聚物
公开(公告)号：US4977026A
公开(公告)日：1990-12-11
申请号：US501116
申请日：1990-03-29
申请人： Edward N. Squire
发明人： Edward N. Squire
IPC分类号： C08F234/02 , H05K1/03 , H05K3/28
CPC分类号： C08F234/02 , H05K1/034 , H05K3/285 , Y10T428/31544 , Y10T428/31699
摘要： Amorphous copolymers of perfluoro-2,2-dimethyl-1,3-dioxole with at least one fluoro comonomer selected from one or more of ten defined classes having a recited minimum mole proportion of perfluoro-2,2-dimethyl-1,3-dioxole, in no event less than 65%, have high glass transition temperatures of 140.degree. C. or higher, low indices of refraction, and good physical properties, and low dielectric constants, which make them suitable for cladding optical fibers as well as for many electronics applications, including the manufacture of substrates for circuit boards. They all are soluble at room temperature in perfluoro(2-butyltetrahydrofuran), which makes it practical to apply them as coatings from solution.
摘要翻译：全氟-2,2-二甲基-1,3-二氧杂环戊烯与至少一种氟共聚单体的无定形共聚物，其选自一个或多个十个界定的类别，其具有所列的最大摩尔比例的全氟-2,2-二甲基-1,3-二氧杂环戊烯，二氧杂环戊烯在任何情况下不低于65％，玻璃化转变温度高于140℃或更高，折射率低，物理性能好，介电常数低，使其适用于包覆光纤以及许多电子应用，包括制造电路板的基板。它们都在室温下溶于全氟（2-丁基四氢呋喃），使其适用于溶液涂料。

34. 发明授权

US4975505A Amorphous copolymers of perfluoro-2,2-dimethyl-1,3-dioxole 失效
公开(公告)号：US4975505A
公开(公告)日：1990-12-04
申请号：US501112
申请日：1990-03-29
申请人： Edward N. Squire
发明人： Edward N. Squire
IPC分类号： C08F234/02 , H05K1/03 , H05K3/28
CPC分类号： C08F234/02 , H05K1/034 , H05K3/285
摘要： Amorphous copolymers of perfluoro-2,2-dimethyl-1,3-dioxole with at least one fluoro comonomer selected from one or more of ten defined classes having a recited minimum mole proportion of perfluoro-2,2-dimethyl-1,3-dioxole, in no event less than 65%, have high glass transition temperatures of 140.degree. C. or higher, low indices of refraction, and good physical properties, and low dielectric constants, which make them suitable for cladding optical fibers as well as for many electronics applications, including the manufacture of substrates for circuit boards. They all are soluble at room temperature in perfluoro(2-butyltetrahydrofuran), which makes it practical to apply them as coatings from solution.

35. 发明授权

US4399264A Perfluorodioxole and its polymers 失效
公开(公告)号：US4399264A
公开(公告)日：1983-08-16
申请号：US323096
申请日：1981-11-19
申请人： Edward N. Squire
发明人： Edward N. Squire
IPC分类号： B01J27/08 , C01G30/00 , C07B61/00 , C07D317/42 , C08F14/20 , C08F34/00 , C08F34/02 , C08F214/20 , C08F214/26 , C08F234/02 , C08F14/18 , C08F14/22 , C08F14/26
CPC分类号： C08F34/02 , C07D317/42 , C08F214/262
摘要： Perfluoro-1,3-dioxole is a useful monomer, which polymerizes to either amorphous or liquid homopolymers and copolymerizes with tetrafluoroethylene as well as with other monomers to both crystalline and amorphous copolymers having one or more such comonomers incorporated therein. Amorphous homopolymers and copolymers of perfluoro-1,3-dioxole are useful in such applications as glazing for reactors for hydrogen fluoride reactions. Amorphous homopolymers and amorphous or crystalline copolymers form self-supporting films and can be used for coatings and linings which are inert to most chemicals and are stain and weather resistant and as dielectrics for electrical and electronic equipment. Liquid homopolymers can be used as hydraulic fluids and heat exchange media.

36. 发明授权

US4384094A 3-Substituted- 7-dialkylamino-spiro(2H-1-benzopyran-2,3'-(3H)-naphtha(2,1-b)pyrans) 失效
标题翻译： 3-取代的7-二烷基氨基螺（2H-1-苯并吡喃-2,3' - （3H） - 萘（2,1-b）吡喃）
公开(公告)号：US4384094A
公开(公告)日：1983-05-17
申请号：US313731
申请日：1981-10-22
申请人： John E. Herweh , Thomas B. Garrett , Alan B. Magnusson
发明人： John E. Herweh , Thomas B. Garrett , Alan B. Magnusson
IPC分类号： C07D493/10 , C08F24/00 , C08F234/02 , C07D311/96
CPC分类号： C07D493/10 , C08F24/00
摘要： Substituted spiro 2H-1-benzopyran-2,3'-(3H)-naphtho(2,1-b)pyrans particularly suitable for use as precursors to stable colored pyrylium salts are disclosed.
摘要翻译：公开了特别适合用作稳定着色的吡喃鎓盐的前体的取代的螺H 1 - 苯并吡喃-2,3' - （3H） - 萘（2,1-b）pyrans。

37. 发明授权

US4136246A Thermoplastic acrylonitrile copolymers 失效
标题翻译：热塑性丙烯腈共聚物
公开(公告)号：US4136246A
公开(公告)日：1979-01-23
申请号：US736889
申请日：1976-10-29
申请人： George S. Li
发明人： George S. Li
IPC分类号： C08F12/00 , C08F32/00 , C08F34/00 , C08F220/00 , C08F220/42 , C08F232/02 , C08F234/02 , C08F212/34 , C08F220/48 , C08F244/00
CPC分类号： C08F220/42
摘要： Thermoplastic polymeric compositions having high heat-distortion temperatures and good processability and handling characteristics which function as gas and vapor barrier materials which are composed of an olefinically unsaturated nitrile, such as acrylonitrile, indene and a polyolefinic monomer, such as divinyl benzene, are described.

38. 发明授权

US4091199A Acrylonitrile-vinyl ether-indene or coumarone polymers 失效
标题翻译：丙烯腈 - 乙烯基醚 - 茚或香豆酮聚合物
公开(公告)号：US4091199A
公开(公告)日：1978-05-23
申请号：US752162
申请日：1976-12-20
申请人： George S. Li , Gary W. Dirks
发明人： George S. Li , Gary W. Dirks
IPC分类号： C08F16/00 , C08F16/16 , C08F20/00 , C08F20/42 , C08F32/00 , C08F34/00 , C08F216/18 , C08F220/00 , C08F220/42 , C08F232/02 , C08F234/02 , C08F214/14 , C08F214/18 , C08F222/30 , C08F244/00
CPC分类号： C08F220/42
摘要： Polymer resins which are relatively high softening and function as gas and vapor barrier materials are composed of an olefinically unsaturated nitrile, such as acrylonitrile, a vinyl ether, such as butyl vinyl ether, and indene or coumarone.
摘要翻译：相对高的软化作用并且作为气体和蒸气阻隔材料起作用的聚合物树脂由烯属不饱和腈如丙烯腈，乙烯基醚如丁基乙烯基醚和茚或香豆酮组成。

39. 发明授权

US3997709A Polymerizates of olefinic nitriles 失效
标题翻译：烯属腈的聚合物
公开(公告)号：US3997709A
公开(公告)日：1976-12-14
申请号：US644123
申请日：1975-12-24
申请人： Walid Y. Aziz , Lawrence E. Ball , George S. Li
发明人： Walid Y. Aziz , Lawrence E. Ball , George S. Li
IPC分类号： C08F20/00 , C08F20/42 , C08F220/42 , C08F234/02
CPC分类号： C08F220/42
摘要： Polymeric resins which are high softening and function as gas and vapor barrier materials are composed of an olefinically unsaturated nitrile, such as acrylonitrile, isobutylene, and indene.
摘要翻译：具有高软化性和作为气体和蒸气阻隔材料起作用的聚合树脂由烯属不饱和腈如丙烯腈，异丁烯和茚组成。

40. 发明授权

US3985942A Regulation of the degree of polymerization of vinyl or vinylidene monomers with 2,5-dihydrofurans 失效
标题翻译：乙烯基或亚乙烯基单体与2,5-二氢呋喃的聚合度的调节
公开(公告)号：US3985942A
公开(公告)日：1976-10-12
申请号：US541272
申请日：1975-01-15
申请人： Masayasu Suzuki , Mitsuru Hoshino , Masaki Ohya
发明人： Masayasu Suzuki , Mitsuru Hoshino , Masaki Ohya
IPC分类号： C08F2/00 , C08F2/38 , C08F234/02
CPC分类号： C08F2/38
摘要： A process for producing vinyl or vinylidene polymers comprising polymerizing vinyl or vinylidene monomers in the presence of 0.1 to 5.0 % by weight of at least one compound represented by the following formula based upon the total weight of monomers, wherein the degree of polymerization of the vinyl or vinylidene polymers is controlled, ##EQU1## wherein R.sub.1 is --CR.sub.5 R.sub.6).sub.n wherein R.sub.5 and R.sub.6 are hydrogen atoms or alkyl groups containing 1 to 4 carbon atoms and n is an integer of 1 or more; R.sub.2 is a hydrogen atom or an alkyl group containing 1 to 4 carbon atoms; and R.sub.3 and R.sub.4 are hydrogen atoms or alkyl groups containing 1 to 4 carbon atoms may be combined to form a ring.
摘要翻译：一种生产乙烯基或亚乙烯基聚合物的方法，包括在基于单体总重量的0.1至5.0重量％的至少一种由下式表示的化合物存在下聚合乙烯基或亚乙烯基单体，其中乙烯基或亚乙烯基单体的聚合度或亚乙烯基聚合物被控制，其中R 1是-CR 5 R 6）n其中R 5和R 6是氢原子或含有1至4个碳原子的烷基，n是整数1或更多; R2是氢原子或含有1至4个碳原子的烷基; 并且R 3和R 4是氢原子或可以组合含有1至4个碳原子的烷基以形成环。

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