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    • 36. 发明申请
    • ORGANIC ELECTROLUMINESCENCE DEVICE
    • US20200207748A1
    • 2020-07-02
    • US16646980
    • 2018-09-04
    • HODOGAYA CHEMICAL CO., LTD.
    • Kazuyuki SURUGATakeshi YAMAMOTOKouki KASEShunji MOCHIZUKI
    • C07D413/10C07D413/04C07D413/14C07D417/10C07D417/04C07D417/14C07C211/54C07C211/58C07D263/57C07D277/66C07D209/82C07D307/91C07D333/76H01L51/42H01L51/00
    • [Object] It is an object of the present invention to provide an organic EL device in which various materials for an organic EL device, which is excellent in hole injection/transport performance, electron injection/transport performance, electron blocking performance, stability in a thin film state, and durability, are combined so that properties of each of the materials can be effectively expressed, thereby achieving (1) high light emission efficiency and power efficiency, (2) a low light emission start voltage, (3) a low practical driving voltage, and particularly (4) a long lifetime.[Solving Means] There is provided an organic EL device, including at least an anode, a hole transport layer, a light-emitting layer, an electron transport layer, and a cathode in the stated order, the organic EL device being characterized in that the hole transport layer contains an arylamine compound represented by the following general formula (1), and the electron transport layer contains a compound having a benzoazole ring structure represented by the following general formula (2). (In the formula, Ar1 to Ar5 may be the same or different from each other, and represent a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a substituted or unsubstituted fused polycyclic aromatic group. Ar6 to Ar8 may be the same or different from each other, and represent a hydrogen atom, a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a substituted or unsubstituted fused polycyclic aromatic group. n1 represents 0, 1, or 2. Ar3 and Ar4 may form a ring with a single bond or may be bonded to each other via a substituted or unsubstituted methylene group, an oxygen atom, or a sulfur atom to form a ring. Ar3 or Ar4 may form a ring with a benzene ring to which Ar3Ar4—N group is bonded, with a single bond or may be bonded to each other via a substituted or unsubstituted methylene group, an oxygen atom, or a sulfur atom to form a ring.) (In the formula, Ar9 and Ar10 may be the same or different from each other, and represent a hydrogen atom, a deuterium atom, a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, a substituted or unsubstituted fused polycyclic aromatic group, or a substituted or unsubstituted alkyl group. Y1 represents a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, a substituted or unsubstituted fused polycyclic aromatic group, or a substituted or unsubstituted alkyl group. X represents an oxygen atom or a sulfur atom. Z1 and Z2 may be the same or different from each other, and represent a carbon atom or a nitrogen atom.)