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    • 31. 发明授权
    • Multilayer silver halide photographic material and process for preparing the same
    • 多层卤化银照相材料及其制备方法
    • US06436621B1
    • 2002-08-20
    • US10078439
    • 2002-02-21
    • Hieronymus AndriessenFreddy Henderickx
    • Hieronymus AndriessenFreddy Henderickx
    • G03C146
    • G03C1/46G03C1/0051G03C1/0053G03C1/035G03C5/17G03C2001/03511G03C2001/03517G03C2001/03541G03C2200/01G03C2200/03Y10S430/166Y10S430/167
    • A multilayer light-sensitive silver halide photographic negative image type material and a method to prepare said material has been described, said material comprising on at least one side of a support a multilayer composition of at least two layers of negative image type silver halide emulsions adjacent to each other, wherein the emulsion layer closest to the said support comprises tabular emulsion crystals selected from the group consisting of silver chloride, silver chlorobromide, silver chloroiodide and silver chlorobromoiodide having a {111} crystal habit and silver chloride, silver chlorobromide, silver chloroiodide and silver chlorobromoiodide having a {100} crystal habit and wherein the adjacent layer(s) farther from the said support comprise(s) essentially cubic emulsion crystals selected from the group consisting of silver chloride, silver chlorobromide and silver bromide, wherein the essentially cubic grains are less sensitive than the tabular grains and wherein the said tabular emulsion crystals having {111} or {100} major faces have at least 50 mole % of chloride.
    • 已经描述了多层感光卤化银照相底片型材料和制备所述材料的方法,所述材料在载体的至少一侧上包含相邻的至少两层负型卤化银乳剂的多层组合物 其中最靠近所述载体的乳剂层包含选自氯化银,氯溴化银,氯氯化银和氯化银氯氯碘化银和氯化银,氯溴化银,氯碘酸银的片状乳液晶体 和具有{100}晶体习惯的氯氯代碘银,并且其中离所述载体更远的相邻层包含选自氯化银,氯溴化银和溴化银的基本上立方体的乳液晶体,其中基本上为立方 颗粒比片状颗粒更不敏感,并且其中所述突片 具有{111}或{100}主面的微乳液具有至少50摩尔%的氯化物。
    • 35. 发明授权
    • High chloride silver halide elements containing activated precursors to thiolic stabilizers
    • 高氯化物卤化银元素含有硫醇稳定剂的活化前体
    • US06280922B1
    • 2001-08-28
    • US09533744
    • 2000-03-23
    • Roger Lok
    • Roger Lok
    • G03C110
    • G03C1/346G03C1/035G03C2001/03517
    • This invention relates to a silver halide photographic element comprising a reflective support having situated thereon a non-tabular silver halide emulsion layer, said emulsion layer being predominantly silver chloride and being in reactive association with a thiolic compound represented by Formula I: wherein Ar represents a substituted or unsubstituted aromatic or heteroaromatic ring; and EW represents an electron withdrawing group; and with a mercapto azole compound represented by Formula II: wherein Q represents the atoms necessary to form a substituted or unsubstituted five or six-membered heterocyclic ring containing at least one nitrogen atom, and M is a cation.
    • 本发明涉及一种卤化银照相元件,其包括反射载体,其上设置有非平板状卤化银乳剂层,所述乳剂层主要为氯化银,并与由式I表示的硫醇化合物反应结合:其中Ar表示 取代或未取代的芳族或杂芳族环; EW代表吸电子基团; 和由式II表示的巯基吡唑化合物:其中Q表示形成取代或未取代的含有至少一个氮原子的五元或六元杂环所必需的原子,M是阳离子。
    • 37. 发明授权
    • Method for processing silver halide photographic material
    • 卤化银照相材料的处理方法
    • US06200739B1
    • 2001-03-13
    • US08998431
    • 1997-12-24
    • Kazuki Yamazaki
    • Kazuki Yamazaki
    • G03C529
    • G03C5/305G03C1/035G03C1/061G03C1/09G03C1/12G03C1/127G03C1/18G03C1/22G03C1/26G03C2001/03517G03C2001/097G03C2001/098
    • A processing method comprising the steps of: imagewise exposing a silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer; and developing the exposed photographic material, wherein said development is carried out in the presence of a compound represented by formula (I): wherein D and E each represents a —CH═ group, a —C(R0)═ group or a nitrogen atom wherein R0 represents a substituent; and R1, R2 and R3, which may be the same or different, each represents a hydrogen atom, a halogen atom or a substituent bonded to the ring by any of a carbon atom, a nitrogen atom, an oxygen atom, a sulfur atom or a phosphorus atom, provided that at least one of R1, R2, R3 and R0 has an —SM group (wherein M represents an alkali metal atom, a hydrogen atom or an ammonium group), and when only one of E and D represents a nitrogen atom, E represents a nitrogen atom, D represents a —CH═ group or a —C(R0)═ group, and neither R2 nor R3 represents a hydroxyl group, and wherein the silver halide emulsion in said photographic material is spectrally sensitized with a specific dye.
    • 一种处理方法,包括以下步骤:成像曝光包含其上具有至少一个感光卤化银乳剂层的载体的卤化银照相材料; 并显影所述曝光的照相材料,其中所述显影在式(I)表示的化合物存在下进行:其中D和E各自表示-CH =基团,-C(R 0)=基团或氮原子 其中R 0表示取代基; 可以相同或不同的R 1,R 2和R 3各自表示氢原子,卤素原子或通过碳原子,氮原子,氧原子,硫原子中的任一个键接到环的取代基 磷原子,条件是R1,R2,R3和R0中的至少一个具有-SM基团(其中M表示碱金属原子,氢原子或铵基),并且当E和D中仅一个表示 氮原子,E表示氮原子,D表示-CH =基团或-C(R 0)=基团,R2和R3均不表示羟基,并且其中所述照相材料中的卤化银乳剂通过光谱增感 一种特定的染料。
    • 38. 发明授权
    • Silver halide photographic emulsion and method for producing the same
    • 卤化银照相乳剂及其制备方法
    • US5972588A
    • 1999-10-26
    • US779081
    • 1997-01-08
    • Toshiyuki Nabeta
    • Toshiyuki Nabeta
    • G03C1/015G03C1/005G03C1/035G03C1/09G03C1/10G03C1/08
    • G03C1/0051G03C1/0053G03C1/09G03C1/10G03C2001/0056G03C2001/03511G03C2001/03517G03C2001/03558G03C2001/0854G03C2001/091G03C2001/095G03C2001/097G03C2200/43
    • There is disclosed a silver halide photographic emulsion, which comprises silver halide tabular grains that have {100} planes as principal planes and have the following features, the emulsion being subjected to chemical sensitization: (a) 50% or more of the projected areas of the tabular grains is attributed to tabular grains having an aspect ratio of 2 or more, (b) each of the tabular grains has a mixed crystal region containing, in addition to main halide ions, different halide ions in an amount of 0.01 mol % or more, but 25 mol % or less, in the nucleus part and/or in part of the growth part or in the whole of the grown part, and (c) when the principal planes of the tabular grains are observed using a transmission-type electron microscope, one or more, but ten or less, dislocation lines are observed on the principal planes of each grain of 50% or more of the tabular grains. The photographic emulsion, in which dislocation is fixed in grains even after the growth and post-ripening processes, is high in aspect ratio and monodispersibility of grains.
    • 公开了一种卤化银照相乳剂,其包含具有{100}面作为主面并具有以下特征的卤化银片状颗粒,所述乳液经受化学增感:(a)50%或更多的投影面积 片状颗粒归因于纵横比为2以上的片状颗粒,(b)每个片状颗粒具有混合晶体区域,除了主卤离子之外,还含有0.01摩尔%的不同的卤离子,或 在细胞核部分和/或生长部分或部分生长部分或整个生长部分中更多,但25mol%或更少,和(c)当使用透射型观察片状颗粒的主平面 在50%以上的片状颗粒的主晶面上观察到一个或多个但是十个以下的位错线。 即使在生长和后熟化过程之后,位错固定在颗粒中的照相乳剂的高宽比和晶粒的单分散性也很高。