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31. 发明申请

US20150105236A1 HYBRID FISCHER-TROPSCH CATALYSTS 有权
标题翻译：混合式螯合催化剂
公开(公告)号：US20150105236A1
公开(公告)日：2015-04-16
申请号：US14574741
申请日：2014-12-18
申请人： Kandaswamy Jothimurugesan , Robert James Saxton
发明人： Kandaswamy Jothimurugesan , Robert James Saxton
IPC分类号： B01J29/80 , B01J29/76
CPC分类号： B01J29/80 , B01J29/7669 , B01J35/006 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0009 , B01J37/0201 , B01J37/04 , B01J2229/186 , C10G2/33 , C10G2/332 , C10G2/333 , C10G2/334
摘要： Disclosed are hybrid Fischer-Tropsch catalysts containing cobalt deposited on hybrid supports. The hybrid supports contain an acidic zeolite component and a silica-containing material. It has been found that the use of the hybrid Fischer-Tropsch catalysts in synthesis gas conversion reactions results in high C5+ productivity, high CO conversion rates and low olefin formation.
摘要翻译：公开了含有沉积在混合载体上的钴的混合费 - 托催化剂。杂化载体含有酸性沸石组分和含二氧化硅的材料。已经发现，在合成气转化反应中使用混合费 - 托催化剂导致高的C5 +生产率，高CO转化率和低烯烃形成。

32. 发明申请

US20150099913A1 METHANOL CONVERSION PROCESS 审中-公开
标题翻译：甲醇转化过程
公开(公告)号：US20150099913A1
公开(公告)日：2015-04-09
申请号：US14046548
申请日：2013-10-04
申请人： Luc Roger Marc MARTENS , David M. MARCUS , Teng XU
发明人： Luc Roger Marc MARTENS , David M. MARCUS , Teng XU
IPC分类号： C07C1/22
CPC分类号： C07C1/22 , B01J29/40 , B01J29/70 , B01J29/90 , C07C1/20 , C07C2523/10 , C07C2529/40 , C10G2/33 , C10G2/334 , C10G2400/02 , C10G2400/20 , C10G2400/22 , Y02P20/52 , Y02P20/584 , Y02P30/20 , C07C11/02
摘要： A methanol conversion process comprises contacting a feedstream comprising methanol, optionally with dimethyl ether or other oxygenates with a catalyst comprising a physical mixture of a molecular sieve, preferably an intermediate or small pore size zeolite such as an MFI zeolite, with a basic metal oxide to provide extended catalyst cycle life by reducing the incidence of coke formation. The process may be applied to the methanol-to-gasoline (MTG), methanol to distillate (MOD), methanol-to-olefins (MTO), methanol-to-chemicals (MTC) and combination processes such as the MTO/OCP Process.
摘要翻译：甲醇转化方法包括使包含甲醇，任选地与二甲醚或其它含氧化合物的进料流与包含分子筛，优选中等或小孔尺寸沸石如MFI沸石的物理混合物与碱性金属氧化物反应的催化剂接触，通过减少焦炭形成的发生率来提供延长的催化剂循环寿命。该方法可应用于甲醇 - 汽油（MTG），甲醇 - 馏出物（MOD），甲醇 - 烯烃（MTO），甲醇 - 化学物质（MTC）和MTO / OCP方法。

33. 发明申请

US20150065338A1 Novel catalysts and process for liquid hydrocarbon fuel production 审中-公开
标题翻译：新型催化剂和液体烃燃料生产工艺
公开(公告)号：US20150065338A1
公开(公告)日：2015-03-05
申请号：US14533977
申请日：2014-11-05
申请人： Mississippi State University
发明人： Mark G. White , Shetian Liu
IPC分类号： B01J29/78 , B01J29/08 , B01J23/28 , B01J29/48
CPC分类号： B01J29/7815 , B01J23/28 , B01J29/0341 , B01J29/076 , B01J29/084 , B01J29/166 , B01J29/26 , B01J29/48 , B01J29/78 , B01J29/7876 , B01J37/0201 , B01J2229/18 , C10G2/334 , C10L1/08 , C10L3/12
摘要： The present invention provides a novel process and system in which a mixture of carbon monoxide and hydrogen synthesis gas, or syngas, is converted into hydrocarbon mixtures composed of high quality gasoline components, aromatic compounds, and lower molecular weight gaseous olefins in one reactor or step. The invention utilizes a novel molybdenum-zeolite catalyst in high pressure hydrogen for conversion, as well as a novel rhenium-zeolite catalyst in place of the molybdenum-zeolite catalyst, and provides for use of the novel catalysts in the process and system of the invention.
摘要翻译：本发明提供了一种新的方法和系统，其中一氧化碳和氢气合成气或合成气的混合物在一个反应器或步骤中被转化为由优质汽油组分，芳族化合物和低分子量气态烯烃组成的烃混合物。本发明在高压氢气中使用新的钼 - 沸石催化剂转化，以及代替钼 - 沸石催化剂的新型铼 - 沸石催化剂，并提供了本发明方法和系统中新型催化剂的用途。

34. 发明授权

US08802741B1 Hybrid fischer-tropsch catalysts and processes for use 有权
标题翻译：混合费 - 托催化剂和使用方法
公开(公告)号：US08802741B1
公开(公告)日：2014-08-12
申请号：US13750089
申请日：2013-01-25
申请人： Kandaswamy Jothimurugesan , Robert James Saxton
发明人： Kandaswamy Jothimurugesan , Robert James Saxton
IPC分类号： C07C27/00 , C07C1/04 , B01J29/76
CPC分类号： C07C1/0435 , B01J29/7661 , B01J37/0009 , B01J37/0203 , B01J2229/20 , B01J2229/42 , C07C9/00 , C10G2/332 , C10G2/333 , C10G2/334 , C10G2300/1022
摘要： Disclosed are hybrid Fischer-Tropsch catalysts containing cobalt and ZSM-48 zeolite. The hybrid Fischer-Tropsch catalysts can contain cobalt deposited on ZSM-48 extrudate supports. Alternatively, the Fischer-Tropsch catalysts can contain cobalt deposited on supports mixed with ZSM-48 particles. It has surprisingly been found that the use of hybrid Fischer-Tropsch catalysts containing ZSM-48 zeolite in synthesis gas conversion reactions results in improved C5+ productivity and catalyst activity, as well as a desirable product distribution including low formation of methane and C21+.
摘要翻译：公开了含有钴和ZSM-48沸石的混合费 - 托催化剂。混合费 - 托催化剂可以含有沉积在ZSM-48挤出物载体上的钴。或者，费 - 托催化剂可以含有沉积在与ZSM-48颗粒混合的载体上的钴。令人惊奇地发现，在合成气转化反应中使用含有ZSM-48沸石的混合费 - 托催化剂导致提高的C5 +生产率和催化剂活性，以及包括低甲烷和C21 +形成的理想产物分布。

35. 发明申请

US20140088206A1 CATALYSTS 有权
标题翻译：催化剂
公开(公告)号：US20140088206A1
公开(公告)日：2014-03-27
申请号：US13984104
申请日：2012-02-07
申请人： Frank Daly , Laura Richard , Sreekala Rugmini
发明人： Frank Daly , Laura Richard , Sreekala Rugmini
IPC分类号： B01J23/89 , C10G3/00
CPC分类号： C10G2/332 , B01J21/063 , B01J21/08 , B01J23/005 , B01J23/75 , B01J23/8896 , B01J23/8913 , B01J23/8986 , B01J35/002 , B01J35/006 , B01J35/023 , B01J35/1042 , B01J35/1061 , B01J37/0201 , B01J37/0205 , B01J37/16 , C10G2/333 , C10G2/334 , C10G3/45 , C10G2300/703 , Y02P30/20
摘要： The invention relates to improvements in the design of Fischer-Tropsch catalysts comprising a support and cobalt on the support. A first aspect is the modification of the silica support with at least 11 wt % titania to prevent the formation of cobalt silicates, thereby limiting the deactivation resulting from the silicate formation. A second aspect is the provision of C03O4 particles highly dispersed on the catalyst support with an average particle diameter of the cobalt oxide particle of less than 12 nm in order to improve catalytic activity and selectivity. A third aspect is the deposition of the catalyst precursor on the support by contact with a solution or suspension comprising the catalyst metal precursors and a carboxylic acid, preferably an alpha-hydroxy carboxylic acid in order to minimize the fracturing and fragmentation of the catalyst precursor during the following steps of drying and calcining, thereby preventing the formation of smaller catalyst particles, which should be removed by screening in order to limit pressure drop in the reactor.
摘要翻译：本发明涉及在载体上包含载体和钴的费 - 托催化剂设计的改进。第一方面是用至少11重量％的二氧化钛改性二氧化硅载体以防止形成硅酸钴，从而限制由硅酸盐形成引起的失活。第二方面是为了提高催化活性和选择性，提供高度分散在催化剂载体上的氧化钴颗粒的平均粒径小于12nm的C03O4颗粒。第三方面是通过与包含催化剂金属前体和羧酸（优选α-羟基羧酸）的溶液或悬浮液的接触将催化剂前体沉积在载体上，以便最小化催化剂前体的断裂和断裂干燥和煅烧的以下步骤，从而防止形成较小的催化剂颗粒，其应通过筛选除去以限制反应器中的压降。

36. 发明申请

US20140045952A1 CATALYSTS 有权
标题翻译：催化剂
公开(公告)号：US20140045952A1
公开(公告)日：2014-02-13
申请号：US14114477
申请日：2011-04-28
申请人： Albertus Jacobus Sandee , Robert Johan Andreas Maria Terorde
发明人： Albertus Jacobus Sandee , Robert Johan Andreas Maria Terorde
IPC分类号： B01J23/89 , B01J23/72 , B01J23/755
CPC分类号： B01J23/8986 , B01J23/06 , B01J23/28 , B01J23/34 , B01J23/462 , B01J23/72 , B01J23/745 , B01J23/75 , B01J23/755 , B01J23/8913 , B01J23/892 , B01J35/0013 , B01J35/006 , B01J37/0201 , B01J37/0205 , B01J37/0207 , B01J37/0219 , B01J37/18 , C10G2/332 , C10G2/334 , C10G49/04 , C10G49/08
摘要： A process for preparing a catalyst precursor includes forming a slurry of particles of an insoluble metal compound, where the metal of the insoluble metal compound is an active catalyst component, with particles and/or one or more bodies of a pre-shaped catalyst support in a carrier liquid. The particles of the insoluble metal compound are thus contacted with the particles and/or the one or more bodies of the pre-shaped catalyst support. A treated catalyst support is thereby produced. Carrier liquid is removed from the slurry to obtain a dried treated catalyst support, which either directly constitutes the catalyst precursor, or is optionally calcined to obtain the catalyst precursor.
摘要翻译：制备催化剂前体的方法包括：将不溶性金属化合物的金属作为活性催化剂组分的不溶性金属化合物的颗粒与颗粒和/或预成型催化剂载体的一个或多个体形成淤浆载液。因此，不溶性金属化合物的颗粒与颗粒和/或预成形催化剂载体的一个或多个体接触。由此产生经处理的催化剂载体。将载体液体从浆料中除去，得到干燥处理的催化剂载体，其直接构成催化剂前体，或任选地煅烧以获得催化剂前体。

37. 发明申请

US20140031194A1 Integral Synthesis Gas Conversion Catalyst Extrudates and Methods For Preparing and Using Same. 审中-公开
标题翻译：积分合成气转化催化剂挤出物及其制备方法。
公开(公告)号：US20140031194A1
公开(公告)日：2014-01-30
申请号：US14041074
申请日：2013-09-30
申请人： Kandaswamy Jothimurugesan , Robert James Saxton , Howard Steven Lacheen , Tapan Kumar Das
发明人： Kandaswamy Jothimurugesan , Robert James Saxton , Howard Steven Lacheen , Tapan Kumar Das
IPC分类号： B01J29/76
CPC分类号： B01J29/7669 , B01J23/8913 , B01J29/043 , B01J29/044 , B01J29/045 , B01J29/7469 , B01J35/0006 , B01J37/0009 , B01J37/035 , B01J2229/186 , B01J2229/42 , C10G2/334 , C10G2/341 , Y02E60/324
摘要： Methods for preparing integral synthesis gas conversion catalyst extrudates including an oxide of a Fischer-Tropsch (FT) metal component and a zeolite component are disclosed. The oxide of the FT metal component is precipitated from a solution into crystallites having a particle size between about 2 nm and about 30 nm. The oxide of the FT metal component is combined with a zeolite powder and a binder material, and the combination is extruded to form integral catalyst extrudates. The oxide of the FT metal component in the resulting catalyst is in the form of reduced crystallites located outside the zeolite channels. No appreciable ion exchange of FT metal occurs within the zeolite channels. The acid site density of the integral catalyst extrudate is at least about 80% of the zeolite acid site density.
摘要翻译：公开了制备包含费 - 托（FT）金属组分和沸石组分的氧化物的整体合成气转化催化剂挤出物的方法。 FT金属成分的氧化物从溶液中沉淀成粒径在约2nm至约30nm之间的微晶。将FT金属成分的氧化物与沸石粉末和粘合剂材料组合，将其组合挤出成一体的催化剂挤出物。所得催化剂中FT金属组分的氧化物为位于沸石通道外部的微晶形式。在沸石通道内不发生明显的FT金属离子交换。整体催化剂挤出物的酸性位点密度为沸石酸性位点密度的至少约80％。

38. 发明授权

US08435457B2 Synthesis of hydrocarbons via catalytic reduction of CO2 有权
标题翻译：通过CO 2的催化还原合成烃
公开(公告)号：US08435457B2
公开(公告)日：2013-05-07
申请号：US13181566
申请日：2011-07-13
申请人： Nick E Tran , Dennis R Hardy , Samuel G Lambrakos , John G. Michopoulos
发明人： Nick E Tran , Dennis R Hardy , Samuel G Lambrakos , John G. Michopoulos
IPC分类号： B01J8/02 , B01J19/00
CPC分类号： C10G2/50 , B01J8/0285 , B01J8/067 , B01J2208/00044 , B01J2208/0007 , B01J2208/00176 , C01B3/042 , C01B2203/062 , C10G2/00 , C10G2/32 , C10G2/332 , C10G2/334 , Y02E60/364 , Y02P20/142
摘要： A method of: introducing hydrogen and a feed gas containing at least 50 vol % carbon dioxide into a reactor containing a Fischer-Tropsch catalyst; and heating the hydrogen and carbon dioxide to a temperature of at least about 190° C. to produce hydrocarbons in the reactor. An apparatus having: a reaction vessel for containing a Fischer-Tropsch catalyst, capable of heating gases to at least about 190° C.; a hydrogen delivery system feeding into the reaction vessel; a carbon dioxide delivery system for delivering a feed gas containing at least 50 vol % carbon dioxide feeding into the reaction vessel; and a trap for collecting hydrocarbons generated in the reaction vessel.
摘要翻译：一种将含有至少50体积％二氧化碳的氢气和进料气体引入含有费 - 托催化剂的反应器中的方法; 并将氢气和二氧化碳加热到至少约190℃的温度以在反应器中产生烃。一种装置，具有：用于容纳费 - 托催化剂的反应容器，其能够将气体加热至至少约190℃; 供给到反应容器中的氢输送系统; 用于将含有至少50体积％二氧化碳的进料气体输送到反应容器中的二氧化碳输送系统; 以及用于收集在反应容器中产生的烃的捕集阱。

39. 发明授权

US08178467B2 Metal nitrate conversion method 失效
标题翻译：金属硝酸盐转化法
公开(公告)号：US08178467B2
公开(公告)日：2012-05-15
申请号：US12158854
申请日：2006-11-17
申请人： Jelle Rudolf Anne Sietsma , Adrianus jacobus Van Dillen , Petra Elisabeth De Jongh , Krijn Pieter De Jong
发明人： Jelle Rudolf Anne Sietsma , Adrianus jacobus Van Dillen , Petra Elisabeth De Jongh , Krijn Pieter De Jong
IPC分类号： B01J21/00
CPC分类号： C01G1/02 , B01J21/04 , B01J21/08 , B01J23/70 , B01J23/75 , B01J23/755 , B01J29/0333 , B01J35/006 , B01J35/0066 , B01J37/088 , B01J37/12 , B01J37/16 , B82Y30/00 , C01B13/18 , C01G3/02 , C01G3/08 , C01G49/02 , C01G51/04 , C01G53/04 , C01P2002/72 , C01P2004/04 , C01P2004/64 , C01P2006/12 , C01P2006/14 , C10G2/332 , C10G2/333 , C10G2/334 , C10G3/45 , C10G3/46 , C10G45/48 , C11C3/123 , Y02P30/20
摘要： A method for converting a supported metal nitrate into the corresponding supported metal oxide comprises heating the metal nitrate to effect its decomposition under a gas mixture that contains nitric oxide and has an oxygen content of
摘要翻译：将负载的金属硝酸盐转化为相应的负载金属氧化物的方法包括加热金属硝酸盐，以在含有一氧化氮并且氧含量<5体积％的气体混合物下进行分解。该方法在支撑材料上提供非常高度分散的金属氧化物。金属氧化物可用作催化剂或催化剂前体。

40. 发明授权

US08097555B2 Process for the production of hybrid catalysts for fischer-tropsch synthesis and hybrid catalyst produced according to said process 有权
标题翻译：用于生产费托合成的杂化催化剂和根据所述方法制备的混合催化剂的方法
公开(公告)号：US08097555B2
公开(公告)日：2012-01-17
申请号：US12260123
申请日：2008-10-29
申请人： Alexandre de Figueiredo Costa , Agustin Martines Feliu , Joan Rollán Martinez , Henrique Soares Cerqueira , Joberto Ferreira Dias Junior , Eduardo Falabella Sousa Aguiar
发明人： Alexandre de Figueiredo Costa , Agustin Martines Feliu , Joan Rollán Martinez , Henrique Soares Cerqueira , Joberto Ferreira Dias Junior , Eduardo Falabella Sousa Aguiar
IPC分类号： B01J23/00 , B01J21/00 , B01J20/00
CPC分类号： B01J35/0006 , B01J21/08 , B01J23/6527 , B01J23/745 , B01J23/75 , B01J23/8913 , B01J29/0308 , B01J29/068 , B01J29/126 , B01J29/7415 , B01J37/0201 , C10G2/33 , C10G2/332 , C10G2/334
摘要： Process for the production of hybrid catalysts formed by mixing two catalysts; one active in Fischer-Tropsch synthesis, the other being bifunctional. Such hybrid catalyst thus formed is active both in hydrocracking and in hydroisomerization reactions. The present invention in addition provides obtainment of a hybrid catalyst and application thereof conjointly with FT catalysts in Fischer-Tropsch synthesis reactions. The hybrid catalyst of the present invention is capable of producing in conditions typically such as those utilized in Fischer-Tropsch synthesis branched hydrocarbons in diverse bands relating to the products thereof (for example naphtha and diesel), reducing or even eliminating necessity for a subsequent hydrotreatment stage in such synthesis reactions. Utilization of such hybrid catalysts of the present invention prolongs the operational efficiency and working life of conventional Fischer-Tropsch synthesis catalysts, reducing substantially encapsulation of particles thereof by waxes produced in the hydroprocessing reactions.
摘要翻译：通过混合两种催化剂形成的混合催化剂的生产方法; 一种在费 - 托合成中活跃，另一种是双功能的。如此形成的这种杂化催化剂在加氢裂化和加氢异构化反应中都是有活性的。本发明另外提供了一种混合催化剂的获得及其在费 - 托合成反应中与FT催化剂的联合应用。本发明的混合催化剂能够在与其产物（例如石脑油和柴油）相关的不同条件下通常用于费 - 托合成支链烃中的那些条件下生产，减少甚至消除后续加氢处理的必要性这种合成反应的阶段。本发明的这种混合催化剂的利用延长了常规费 - 托合成催化剂的操作效率和使用寿命，减少了在加氢反应中产生的蜡的颗粒的基本包封。

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