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31. 发明授权

US3579360A Lyophilising a carbon dioxide solution 失效
标题翻译：二氧化碳解决方案
公开(公告)号：US3579360A
公开(公告)日：1971-05-18
申请号：US3579360D
申请日：1967-07-06
申请人： NESTLE SA
发明人： REY LOUISRENE , DOUSSET MONICK , CHAUFFARD FRANCOISE
IPC分类号： A21D6/00 , A21D13/08 , A23F5/32 , A23F5/48 , A23L3/44 , C07F5/00 , C08J9/40 , F26B5/06 , A23F1/06
CPC分类号： C08J9/40 , A21D6/001 , A21D6/008 , A21D13/80 , A23F5/32 , A23F5/48 , A23F5/486 , A23L3/44 , C07F5/006 , F26B5/06
摘要： POROUS COMPOSITE MATERIALS, CONSISTING OF A CONTINUOUS PHASE AND A DISPERSE PHASE IN INTIMATE ASSOCIATION WITH THE CONTINUOUS PHASE MAY BE OBTAINED BY THE APPLICATION OF FREEZE-DRYING TECHNIQUES. THE MATERIALS MAY BE PREPARED EITHER BY FREE-DRYING A FIRST SOLUTION, IMPREGNATING THE DRY MATERIAL WITH A SECOND SOLUTION AND AGAIN FREEZEDRYING, OR BY FREEZE-DRYING A SYSTEM CONSISTING OF TWO SOLUTES DISSOLVED IN DIFFERENT SOLVENTS WHICH MAY BE IMMISIBLE. FREEZE-DRYING OF BOTH AQUEOUS AND NON-AQUEOUS SYSTEMS IS ENVISAGED.

32. 发明授权

US3448127A Method of producing onium-salt complex compounds 失效
标题翻译：生产盐复合化合物的方法
公开(公告)号：US3448127A
公开(公告)日：1969-06-03
申请号：US3448127D
申请日：1964-03-27
申请人： SIEMENS AG
发明人： DOTZER RICHARD
IPC分类号： C07C395/00 , C07F3/00 , C07F5/00 , C07F5/06 , C07F9/00 , C07F9/54 , C07F9/90 , C25C3/00 , C25D3/02 , C25D3/44 , C25D3/66 , H01G9/02 , H01G9/022 , H01G9/028
CPC分类号： H01G9/028 , C07C395/00 , C07F3/00 , C07F5/00 , C07F5/006 , C07F5/062 , C07F9/00 , C07F9/5456 , C07F9/90 , C07F9/904 , C07F9/908 , C25C3/00 , C25D3/02 , C25D3/44 , C25D3/66 , H01G9/022
摘要： Onium salts having a complex anion are prepared by the reaction of (a) an electron donor compound of formula R1kHlkY, (b) a electron acceptor compound of formula MR11nX1mn and (c) an organic compound RX, wherein R, R1 and R11 are alkyl or aryl groups, X is halogen, pseudohalogen or an acid residue, X1 is halogen or hydrogen, Y is N, P, As, Sb, Bi, S, Se or Te, M is Be, Zn, Cd, B, Al, In, Ga, Tl, Si, Ge, Pb or Sn, l and m are integers representing the capacities of Y and M respectively to combine with hydrogen, and k and n are 0 or an integer from 1 to l or m respectively. The reaction in its simplest form may be represented by:-D + A + RX --> [DR]+[AX]-wherein D represents the electron donor and A the electron acceptor, but compounds formed by the reaction of two molecules of acceptor with one each of donor and RX ar also disclosed. The reaction may be carried out by first forming a co-ordination compound between donor and acceptor and reacting this with RX, or an adduct or mixture may be formed from the acceptor and RX which is then reacted with the donor, or the donor and RX may be first mixed and then reacted with the acceptor. Trimethylammonium triethylchloroaluminate obtained by first passing triethylamine gas into triethylaluminium to form a 1 : 1 complex and passing methyl chloride into the product. By passing further methyl chloride there is obtained the complex Triethylpropylstibonium triethylbromoindanate is prepared by reacting methylantimony and triethylindium under an inert gas and adding N :propyl bromide to the product. Further examples are indicated by the equations:- The complex onium salts may be degraded by such methods as solvolysis with methanol or water, oxidative cleavage or displacement with a stronger complexing agent for the acceptor compound to give the simple onium salt (DR)+X- where D represents the donor compound. For example, tetraethylstibonium triethyl bromoaluminate in solution in dichloromethane is added to methanol, ethane is evolved and aluminium methoxide removed by decantation, and the residue worked up to yield tetraethylstibonium bromide.

33. 发明授权

US3442807A Novel boron esters and stabilization of oxidizable organic substances therewith 失效
标题翻译：新型硼酸盐和可氧化有机物质的稳定化
公开(公告)号：US3442807A
公开(公告)日：1969-05-06
申请号：US3442807D
申请日：1966-12-19
申请人： MOBIL OIL CORP
发明人： LAW DEREK A
IPC分类号： C07F5/00 , C07F5/04 , C09K15/30 , C09K15/32 , B01J1/16 , C10M1/54 , C10M5/28
CPC分类号： C10M1/08 , C07F5/006 , C07F5/04 , C09K15/30 , C09K15/328 , C10M2205/00 , C10M2207/04 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2207/34 , C10M2209/00 , C10M2209/02 , C10M2209/10 , C10M2209/103 , C10M2209/108 , C10M2227/062 , C10M2229/02 , C10M2229/05 , C10N2250/10

34. 发明授权

US3365282A Process for preparing amino derivatives of polyhedral boron compounds 失效
标题翻译：制备聚氧化硼化合物的氨基衍生物的方法
公开(公告)号：US3365282A
公开(公告)日：1968-01-23
申请号：US3365282D
申请人： DU PONT
发明人： RAASCH MAYNARD S
IPC分类号： C06B47/10 , C07F5/00
CPC分类号： C06B47/10 , C07F5/006

35. 发明授权

US3342814A Adducts of metal borohydrides and organic polynitrogen compounds 失效
标题翻译：金属硼氢化物和有机多氮化合物的加合物
公开(公告)号：US3342814A
公开(公告)日：1967-09-19
申请号：US16800562
申请日：1962-01-15
申请人： UNION CARBIDE CORP
发明人： HOGSETT JOHN N , ALBERT KHURI , SCHULZ HELMUT W
IPC分类号： C06B47/10 , C07F5/00 , C07F5/06 , C10L1/30
CPC分类号： C10L1/303 , C06B47/10 , C07F5/006 , C07F5/069

36. 发明授权

US3305555A Preparation of tertiary amine boranes including pyridyl boranes 失效
标题翻译：制备包括吡啶基硼烷在内的叔胺硼烷
公开(公告)号：US3305555A
公开(公告)日：1967-02-21
申请号：US35158364
申请日：1964-03-09
申请人： AMERICAN CYANAMID CO
发明人： FRANK STAFIEJ STANLEY , ANDREW TAKACS EDWARD
IPC分类号： C06B47/10 , C07F5/00
CPC分类号： C06B47/10 , C07F5/006

37. 发明授权

US3254954A Process for preparing diborane 失效
公开(公告)号：US3254954A
公开(公告)日：1966-06-07
申请号：US26985063
申请日：1963-03-29
申请人： ETHYL CORP
发明人： ASHBY EUGENE C
IPC分类号： C01B6/10 , C07F5/00
CPC分类号： C01B6/10 , C07F5/006

38. 发明授权

US3215491A Production of alkali metal borohydrides 失效
标题翻译：生产碱金属硼氢化物
公开(公告)号：US3215491A
公开(公告)日：1965-11-02
申请号：US5436760
申请日：1960-09-07
申请人： BAYER AG
发明人： FRIEDRICH SCHUBERT , KONRAD LANG
IPC分类号： C01B6/00 , C07F5/00
CPC分类号： C07F5/006 , C01B6/00
摘要： Alkali metal borohydrides are produced by reacting an alkali metal hydride with a boron trihalide or an addition compound thereof in the presence of an amino borane catalyst of the formula RnB(NR1R11)3-n where R is hydrogen or an alkyl or an aryl radical, R1 is hydrogen or an aliphatic or aryl radical, R11 is an aliphatic or aryl radical, n is an integer from 0 to 2, and the catalyst is present in amounts of from 0,5 to 50% by weight of the alkali metal hydride. The process is carried out in a high boiling (above 180 DEG C.) inert suspension agent such as aliphatic and aromatic hydrocarbons, or inert oils such as tetra alkyl silanes, ethers, and polyethers, and at a temperature between 30 DEG C. and the decomposition temperature of the alkali metal borohydride formed. The boron trihalide addition compounds may be those with di lower alkyl ethers, cyclic alkyl ethers, tri-lower alkyl amines, tertiary mixed lower alkyl aryl amines and pyridine, or it may be Na2O.4BF3. The catalyst may be produced in situ by reacting an amine (R1R11NH) with an N-alkyl borazane selected from pyridine borane, N-tri-lower alkyl borazanes and N-di-lower alkyl borazanes; or R1R11NH with an alkali metal borohydride and a boron halide compound; or R1R11NH with a hydrocarbon substituted diborane of the formula (RnBH3-n)2 where n = 1 or 2. A co-catalyst may be added to the reaction mixture, which is a tertiary alkyl or aryl amine or an alkyl ether capable of forming addition compounds with boron trihalides. The co-catalyst may be present in amounts of 0,5 to 50% by weight of the alkali metal hydride. Examples are given in which boron trifluoride-tetrahydrofuranate is reacted with sodium hydride in the presence of (C3H7)2BN(C4H9)2, acid trisanilide, boric acid trisanilide with a cocatalyst triethylamine, N-triethylborazane with a co-catalyst dibutylamine. Numerous examples of R, R1 and R11 and also of the boron trihalide addition compounds are given.ALSO:Amino boranes of formula RnB(NR1R11)3,n where R represents hydrogen, alkyl or aryl group, R1 represents hydrogen, aliphatic or aryl group, R11 represents an aliphatic or aryl radical, n is 0, 1 or 2 are produced by reacting an amine R1R11NH with an N-alkyl borazane selected from pyridine borane, N-tri C1-C4 alkyl borazanes, N-di-C1-C4 alkyl borazanes. Alternatively the amine R1R11NH may be reacted with a mixture of alkali metal borohydride and boron trihalide or addition compound thereof, or it may be reacted with a hydrocarbon substituted diborane (RnBH3-n)2 where n=1 or 2.

39. 发明授权

US3205239A Sodium decaborane-tetrahydrofuran adduct and method for preparing same 失效
标题翻译：十硼烷 - 四氢呋喃加合物及其制备方法
公开(公告)号：US3205239A
公开(公告)日：1965-09-07
申请号：US78665559
申请日：1959-01-13
申请人： OLIN MATHIESON
发明人： KEEFER EDWARD H
IPC分类号： C01B6/00 , C06B47/10 , C07F5/00
CPC分类号： C07F5/006 , C01B6/00 , C06B47/10

40. 发明授权

US3161469A Preparation of boron hydrides 失效
标题翻译：硼氢化物的制备
公开(公告)号：US3161469A
公开(公告)日：1964-12-15
申请号：US74881358
申请日：1958-07-16
申请人： ETHYL CORP
发明人： ASHBY EUGENE C , PODALL HAROLD E
IPC分类号： C07F5/00
CPC分类号： C01B6/00 , C01B35/026 , C07F5/006
摘要： Hydrides of boron, particularly diborane, are prepared by reacting an organic ester of boric acid with aluminium metal and hydrogen at elevated temperatures. Suitable esters are listed, examples being triphenyl borate, trimethyl borate, tri-(t-butyl) borate, tricyclohexyl borate, tribenzyl borate and tri-(p-chlorophenyl) borate. Tertiary amines which form complexes with the boron hydrides may be present as diluents, examples of which are triethylamine, trimethylamine, and triphenylamine; diborane is obtained from these complexes by acidification with hydrochloric acid or boron trichloride at room temperature. Other diluents are specified, including alkyl, cycloalkyl and aromatic hydrocarbons and ethers. The aluminium is preferably in finely divided form and may have been activated by treatment with triethyl-aluminium and hydrogen at 140 DEG C. and 1000 lbs. per sq. inch pressure or by recycling excess aluminium from a previous run. Reaction temperature may be 120-300 DEG C., 140-180 DEG C. being preferred in the absence of a tertiary amine and 200-250 DEG C. when a tertiary amine is present. Hydrogen pressures of 500 to 5000 lbs. per sq. inch may be employed. The reaction may be catalyzed by trialkyl aluminium or boron compounds or by aluminium halides, especially aluminium chloride. The boron hydride or its complex with the tertiary amine is removed from the product by distillation; by-product aluminium alcoholate may be recovered and hydrolysed to form the alcohol which is reacted with boric oxide to produce boron alcoholate for re-use in the process.

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