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31. 发明申请

US20010014724A1 Process for the manufacture of a composition comprising ethylene polymers 审中-公开
公开(公告)号：US20010014724A1
公开(公告)日：2001-08-16
申请号：US09809198
申请日：2001-03-16
申请人： SOLVAY POLYOLEFINS EUROPE-BELGIUM
发明人： Michel Promel , Bruno Moens
IPC分类号： C08F004/44
CPC分类号： F16L9/127 , C08F10/02 , C08F210/16 , C08L23/04 , C08L23/06 , C08F2/001 , C08L2666/04 , C08F210/08 , C08F2500/12 , C08F2500/07 , C08F2500/13 , C08F2500/26 , C08F210/14 , C08F4/6555
摘要： Process for the manufacture of a composition comprising ethylene polymers, in at least two polymerization reactors connected in series, according to which, in a first reactor, from 30 to 70% by weight with respect to the total weight of the composition of an ethylene homopolymer (A) having a melt flow index MI2 of 5 to 1000 g/10 min is formed and, in a subsequent reactor, from 30 to 70% by weight with respect to the total weight of the composition of a copolymer of ethylene and of hexene (B) having a melt flow index MI5 of 0.01 to 2 g/10 min is formed. The compositions obtained by this process exhibit a good compromise between the processing properties and the mechanical properties, which renders them capable of being used in the manufacture of articles shaped by extrusion and extrusion blow-molding, such as films and pipes.

32. 发明授权

US6100416A Asymmetric ethylene-bridged metallocenes useful as catalysts in the polymerization of olefins and process for preparing said metallocenes 失效
标题翻译：用作烯烃聚合中的催化剂的不对称乙烯桥连金属茂和制备所述金属茂的方法
公开(公告)号：US6100416A
公开(公告)日：2000-08-08
申请号：US87981
申请日：1998-06-01
申请人： Marvin D. Rausch , Emma J. Thomas , Serge Bettonville , Didier Grandfils
发明人： Marvin D. Rausch , Emma J. Thomas , Serge Bettonville , Didier Grandfils
IPC分类号： C07F7/00 , C07F17/00 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C07F17/00 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65912 , Y10S526/943
摘要： Novel asymmetric ethylene-bridged metallocenes useful as catalysts in the polymerization of olefins and process for preparing said metallocenes.The novel metallocenes are represented by the general formula: ##STR1## wherein M represents a transition metal selected from titanium, zirconium and hafnium and X and X' represent a halogen atom. Preferably, the transition metal is Zr and the halogen atoms are both chlorine.Process for producing the novel metallocenes of general formula (I) comprising the steps of:a) reacting fluorenyllithium with 1,2-dibromoethane to produce 1-(9-fluorenyl)-2-bromoethane,b) reacting the said 1-(9-fluorenyl)-2-bromoethane with 2,4,7-trimethylindenyllithium to produce 1-(9-fluorenyl)-2-[1-(2,4,7-trimethyl)indenyl]ethane precursor,c) reacting the said 1-(9-fluorenyl)-2-[1-(2,4,7-trimethyl)indenyl]ethane precursor with butyllithium to produce its dilithium salt andd) reacting the said dilithium salt with a transition metal halide selected from halides of Ti, Zr and Hf to produce the metallocenes.The novel metallocenes are useful as catalysts for the polymerization of olefins such as ethylene and propylene and, in particular, for the production of higly isotactic polypropylene.
摘要翻译：用于烯烃聚合中的催化剂的新型不对称乙烯桥连金属茂和制备所述金属茂的方法。新型茂金属由通式表示：其中M表示选自钛，锆和铪的过渡金属，X和X'表示卤素原子。优选地，过渡金属是Zr，并且卤素原子都是氯。制备通式（I）的新金属茂的方法，包括以下步骤：a）使芴基锂与1,2-二溴乙烷反应，生成1-（9-芴基）-2-溴乙烷，b）使所述1-（9 芴基）-2-溴乙烷与2,4,7-三甲基茚基锂反应，生成1-（9-芴基）-2- [1-（2,4,7-三甲基）茚基]乙烷前体，c）使所述1 - （9-芴基）-2- [1-（2,4,7-三甲基）茚基]乙烷前体与丁基锂反应生成其二锂盐，和d）使所述二锂盐与选自Ti ，Zr和Hf以产生金属茂。新型金属茂可用作烯烃如乙烯和丙烯的聚合催化剂，特别是用于生产高度全同立构聚丙烯的催化剂。

33. 发明授权

US6083866A Catalytic system which can be used for the stereospecific polymerisation of .alpha.-olefins, process for this polymerisation and polymers obtained 失效
标题翻译：可用于α-烯烃的立体有择聚合的催化体系，该聚合的方法和获得的聚合物
公开(公告)号：US6083866A
公开(公告)日：2000-07-04
申请号：US796574
申请日：1997-02-06
申请人： Jean-Louis Costa , Sabine Pamart , Herve Collette , Serge Bettonville
发明人： Jean-Louis Costa , Sabine Pamart , Herve Collette , Serge Bettonville
IPC分类号： C08F4/655 , C08K13/00 , B01J31/14 , C08F4/60 , C08F4/64 , C08F4/642 , C08F4/658 , C08F10/00 , C08F10/06 , C08F110/06 , C08L23/00 , B01J31/00
CPC分类号： C08F10/00 , Y02P20/52
摘要： Catalytic system which can be used for the polymerisation of .alpha.-olefins comprising:a solid based on complexed titanium trichloride of .delta. crystalline form;an organoaluminium compound;an organic oxygenated silicon compound; characterised in that the organoaluminium compound is a non-halogenated compound.
摘要翻译：可用于α-烯烃聚合的催化体系，包括：基于络合的三角晶态三氯化钛的固体; 有机铝化合物; 有机氧化硅化合物; 其特征在于有机铝化合物是非卤代化合物。

34. 发明授权

US6077922A Hollow bodies made of ethylene polymer and method of making same 失效
标题翻译：由乙烯聚合物制成的空心体及其制造方法
公开(公告)号：US6077922A
公开(公告)日：2000-06-20
申请号：US943152
申请日：1997-10-03
申请人： Paul Johnson , Abel Grosjean , Benoit Koch
发明人： Paul Johnson , Abel Grosjean , Benoit Koch
IPC分类号： C08F4/22 , C08F4/24 , C08F4/69 , C08F10/02 , C08F110/02 , C08F210/16
CPC分类号： C08F10/02 , C08F110/02
摘要： An ethylene polymer having a density greater than 959 kg/m3 and a resistance to slow cracking greater than 23 hours. A composition containing this polymer, hollow bodies obtained using at least one such ethylene polymer, and a process for the manufacture of said polymer.
摘要翻译：密度大于959kg / m 3的乙烯聚合物和大于23小时的缓慢开裂性。含有该聚合物的组合物，使用至少一种这样的乙烯聚合物获得的中空体，以及制造所述聚合物的方法。

35. 发明授权

US5948547A Composition based on statistical propylene copolymers, process for their manufacture and multilayer heat-sealable sheets containing them 失效
标题翻译：基于统计丙烯共聚物的组合物，其制造方法和含有它们的多层可热封片材
公开(公告)号：US5948547A
公开(公告)日：1999-09-07
申请号：US763443
申请日：1996-12-11
申请人： Raymond Mikielski , Veerle Deblauwe , Mathieu Wilkin
发明人： Raymond Mikielski , Veerle Deblauwe , Mathieu Wilkin
IPC分类号： C08J5/18 , B32B27/32 , B65D1/00 , C08F297/08 , C08L23/00 , C08L23/12 , C08L23/14 , C09J123/14 , C08L23/10 , C08L23/18 , B32B27/00 , B32B27/08
CPC分类号： C08L23/142 , B32B27/32 , C09J123/142 , C08L2205/02 , C08L23/14 , Y10T428/31913
摘要： Compositions based on propylene polymers (compositions (C)) comprising:from 68 to 80% by weight of a statistical propylene copolymer (copolymer (A)) which contains from 12 to 20% by weight of units derived from 1-butene and from 0 to 2% by weight of units derived from ethylene, andfrom 20 to 32% by weight of a statistical propylene copolymer (copolymer (B)) which contains from 0 to 15% by weight of units derived from 1-butene and from 1 to 8% by weight of units derived from ethylene.
摘要翻译：基于丙烯聚合物（组合物（C））的组合物，其包含：68至80重量％的统计丙烯共聚物（共聚物（A）），其含有12至20重量％的衍生自1-丁烯的单元和0 至2重量％的衍生自乙烯的单元，以及20至32重量％的统计丙烯共聚物（共聚物（B）），其含有0至15重量％的衍生自1-丁烯的单元和1至 8重量％衍生自乙烯的单元。

36. 发明授权

US5849852A Support for catalysts, process for the manufacture of a precursor gel of a support for catalysts, catalyst for the polymerization of olefins and process for the polymerization of olefins by means of this catalyst 失效
标题翻译：对催化剂的支持，用于制备催化剂载体的前体凝胶的方法，用于烯烃聚合的催化剂和通过该催化剂聚合烯烃的方法
公开(公告)号：US5849852A
公开(公告)日：1998-12-15
申请号：US553326
申请日：1996-01-29
申请人： Benoit Koch , Andre Rulmont , Fabienne Wijzen
发明人： Benoit Koch , Andre Rulmont , Fabienne Wijzen
IPC分类号： B01J21/04 , B01J21/08 , B01J21/12 , B01J23/26 , B01J27/16 , B01J32/00 , B01J35/10 , B01J37/03 , C08F4/02 , C08F4/22 , C08F4/24 , C08F4/42 , C08F4/645 , C08F4/69 , C08F4/78 , C08F10/00 , C08F10/02
CPC分类号： B01J37/036 , B01J21/12 , B01J27/16 , B01J35/10 , B01J37/033 , C08F10/00 , B01J35/1019 , B01J35/1023 , B01J35/1047
摘要： Support for catalysts, containing at least two constituents chosen from silica, alumina and aluminium phosphate, having a specific surface of 100 to 800 m.sup.2 /g, a crystallization temperature greater than or equal to 700.degree. C. and a pore volume of 1.5 to 4 cm.sup.3 /g, the specific surface (SS) and the pore volume (PV) corresponding to the relationship: SS
摘要翻译： PCT No.PCT / EP94 / 01513 Sec。 371日期1996年1月29日 102（e）日期1996年1月29日PCT提交1994年5月10日PCT公布。公开号WO94 / 26790 日期1994年11月24日载体，含有选自二氧化硅，氧化铝和磷酸铝的至少两种成分，比表面积为100-800m2 / g，结晶温度大于或等于700℃的催化剂，体积为1.5至4cm 3 / g，比表面积（SS）和孔体积（PV）对应于SS <（PVx564-358）的关系。制备这种载体的方法，根据该方法，水，硅烷氧化物和酸的混合条件使得防止二氧化硅凝胶化或沉淀，向其中加入铝化合物的酸性溶液和/或磷酸根离子源的溶液，向其中加入胶凝剂，回收凝胶，用水洗涤，然后用有机液体将凝胶干燥直到获得粉末，并将粉末煅烧。如上所述，在载体上含有铬的催化剂存在下烯烃的聚合。

37. 发明授权

US5824754A Process for the polymerisation of alpha-olefins using a cocatalytic composition 失效
标题翻译：使用助催化组合物聚合α-烯烃的方法
公开(公告)号：US5824754A
公开(公告)日：1998-10-20
申请号：US606499
申请日：1996-02-23
申请人： Paul Fiasse , Herve Collette
发明人： Paul Fiasse , Herve Collette
IPC分类号： B01J31/38 , B01J31/14 , B01J31/22 , C08F4/60 , C08F4/64 , C08F4/642 , C08F4/649 , C08F10/00
CPC分类号： C08F10/00
摘要： Cocatalytic composition resulting from bringing an organoaluminium halide (A) into contact with an electron-donating organic compound (ED) selected from esters, amides and ketones, the organoaluminium halide (A) possessing an atomic ratio halogen (X)/aluminium (Al) of greater than 1 and less than 1.3, the halide (A) and the compound (ED) being employed in a mole ratio halide (A)/compound (ED) of greater than 20. Catalytic systems which are usable for the polymerization of alpha-olefins, comprising such a cocatalytic composition and a solid based on titanium trichloride complexed with an electron-donating compound.
摘要翻译：通过使有机卤化铝（A）与选自酯，酰胺和酮的给电子有机化合物（ED）接触而产生的催化组合物，具有原子比卤素（X）/铝（Al）的有机卤化铝（A）大于1且小于1.3，卤化物（A）和化合物（ED）以卤化物（A）/化合物（ED）的摩尔比大于20使用。可用于聚合α的催化体系 α-烯烃，其包含这样的助催化组合物和基于与给电子化合物络合的三氯化钛的固体。

38. 发明授权

US5763349A Solid precursor of a catalytic system for the polymerization of olefins, process for its preparation, catalytic system comprising this solid precursor and process for the polymerization of olefins in the presence of this catalytic system 失效
标题翻译：用于烯烃聚合的催化体系的固体前体，其制备方法，包含该固体前体的催化体系和在该催化体系存在下烯烃聚合的方法
公开(公告)号：US5763349A
公开(公告)日：1998-06-09
申请号：US606686
申请日：1996-02-15
申请人： Nicola Zandona
发明人： Nicola Zandona
IPC分类号： C08F4/62 , B01J31/38 , C08F4/02 , C08F4/60 , C08F4/606 , C08F4/619 , C08F4/6192 , C08F4/639 , C08F4/6392 , C08F4/646 , C08F4/654 , C08F4/658 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/634 , C08F4/631
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/63904 , C08F4/63908 , C08F4/63912 , C08F4/63916 , C08F4/6392 , Y10S526/904 , Y10S526/906 , Y10S526/907 , Y10S526/943
摘要： Solid precursor of a catalytic system for the polymerization of olefins, containing at least one neutral halogenated metallocene derived from a transition metal, the latter being linked to at least one halogen atom, and at least one ionizing agent. Process for the preparation of this solid precursor, according to which a compound based on the neutral halogenated metallocene is mixed with a compound based on the ionizing agent in a heterogeneous medium. Catalytic system comprising an organometallic compound derived from a metal chosen from groups IA, IIA, IIB, IIIA and IVA of the Periodic Table, and a solid precursor described above. Process for the polymerization of olefins, in which this catalytic system is used.
摘要翻译：用于烯烃聚合的催化体系的固体前体，其含有至少一种衍生自过渡金属的中性卤代茂金属，后者与至少一个卤素原子连接，和至少一种电离剂。制备该固体前体的方法，根据该固体前体，将基于中性卤代金属茂的化合物与基于离子化剂的化合物在异质介质中混合。包含衍生自选自元素周期表IA，IIA，IIB，IIIA和IVA族的金属的有机金属化合物的催化体系和上述固体前体。烯烃聚合方法，其中使用该催化体系。

39. 发明授权

US5756587A Propylene polymers and process for the production thereof 失效
标题翻译：丙烯聚合物及其制备方法
公开(公告)号：US5756587A
公开(公告)日：1998-05-26
申请号：US704509
申请日：1996-09-12
申请人： Serge Bettonville , Philippe De Rop , Claude Franquinet
发明人： Serge Bettonville , Philippe De Rop , Claude Franquinet
IPC分类号： C08F297/08 , C08F297/06 , C08L53/00
CPC分类号： C08F297/06 , C08L53/00
摘要： Propylene block copolymer containing per: 100 parts by weight of a polymer (a) of propylene chosen from homopolymers and copolymers of propylene not containing more than 6% by weight of ethylene and/or of an alpha-olefin having from 4 to 6 carbon atoms, from 1 to 100 parts by weight of a polymer (b) of ethylene chosen from homopolymers and copolymers of ethylene not containing more than 90% by weight of propylene and/or of another alpha-olefin having from 4 to 6 carbon atoms, the said block copolymer additionally containing from approximately 0.001 to approximately 20% by weight of .alpha.,.omega.-diene-derived monomer units with respect to the total weight of the block copolymer.
摘要翻译： PCT No.PCT / EP95 / 00851 Sec。 371日期1996年9月12日 102（e）日期1996年9月12日PCT 1995年3月7日PCT公布。公开号WO95 / 25137 日期1995年9月21日含有丙烯嵌段共聚物：100重量份丙烯聚合物（a），其选自丙烯的均聚物和共聚物，其不包含大于6重量％的乙烯和/或α-烯烃， 4至6个碳原子，1至100重量份的选自乙烯的均聚物和共聚物的乙烯聚合物（b），所述乙烯不包含大于90重量％的丙烯和/或另外的具有4至6个碳原子的α-烯烃 6个碳原子，所述嵌段共聚物相对于嵌段共聚物的总重量另外含有约0.001至约20重量％的α，ω-二烯衍生的单体单元。

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