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    • 32. 发明申请
    • LUBRICATING OIL COMPOSITIONS
    • 润滑油组合物
    • US20130123157A1
    • 2013-05-16
    • US13293387
    • 2011-11-10
    • Gilles SinquinCurt CampbellHélène LecroqEugene E. Spala
    • Gilles SinquinCurt CampbellHélène LecroqEugene E. Spala
    • C10M135/02C07C381/00
    • C07C381/00C10M135/02C10M159/22C10M2219/088C10M2219/089C10N2240/10C10N2270/00C10N2210/02
    • Disclosed herein is a neutral or overbased salt of a sulfurized alkylhydroxyaromatic compound obtained by the process comprising the steps of (a) sulfurizing an alkylhydroxyaromatic compound derived from alkylation of a hydroxyaromatic compound with one or more olefins comprising C9 to C18 oligomers of monomers selected from propylene, butylene or mixtures thereof to provide a sulfurized alkylhydroxyaromatic reaction product; (b) removing any unsulfurized alkylhydroxyaromatic compound from the sulfurized alkylhydroxyaromatic reaction product of step (a) to obtain a sulfurized alkylhydroxyaromatic compound substantially free of the unsulfurized alkylhydroxyaromatic compound; and (c) neutralizing the sulfurized alkylhydroxyaromatic compound of step (b) to provide a salt of the sulfurized alkylhydroxyaromatic compound, wherein the overbased salt of the sulfurized alkylhydroxyaromatic compound contains less than about 2% by combined mass of the unsulfurized alkylhydroxyaromatic compound and its unsulfurized metal salt.
    • 本文公开了一种中和或高碱性的硫化烷基羟基芳族化合物的盐,该方法包括以下步骤:(a)将衍生自羟基芳族化合物的烷基羟基芳族化合物硫化为一种或多种烯烃,所述烯烃包含选自丙烯的单体的C 9至C 18低聚物 ,丁烯或其混合物以提供硫化的烷基羟基芳族化合物反应产物; (b)从步骤(a)的硫化烷基羟基芳族化合物反应产物中除去任何未硫化的烷基羟基芳族化合物,得到基本上不含未硫化烷基羟基芳族化合物的硫化烷基羟基芳族化合物; 和(c)中和步骤(b)的硫化烷基羟基芳族化合物以提供硫化烷基羟基芳族化合物的盐,其中硫化烷基羟基芳族化合物的高碱性盐含有少于约2%的未硫化烷基羟基芳族化合物及其未硫化的 金属盐。
    • 34. 发明申请
    • RHEOLOGICAL METHODS TO DETERMINE THE PREDISPOSITION OF A POLYMER TO FORM NETWORK OR GEL
    • 测定聚合物形成网络或凝胶的流变学方法
    • US20130085092A1
    • 2013-04-04
    • US13605677
    • 2012-09-06
    • Rainer KolbSudhin DattaPritesh A. PatelKirk A. Nass
    • Rainer KolbSudhin DattaPritesh A. PatelKirk A. Nass
    • G01N19/00G06F19/00C10M143/02
    • C10M143/08C10M2205/0285C10N2230/02G01N11/16G01N2011/0033
    • A method is provided to determine the predisposition of a polymer to form network or gel in a lubricating oil which comprises obtaining a composition of a polymer in a diluent, measuring the shear stress as a function of shear rate, determining the yield stress using the Herschel-Bulkley equation and assessing the yield stress. A method is also provided to determine the predisposition of a polymer to form network or gel in a lubricating oil which comprises obtaining a composition of a polymer in a diluent, determining at least one of (i) the storage modulus G′ and loss modulus G″ of the composition by subjecting the composition to sinusoidal (oscillating) stress or strain of certain amplitude and frequency, (ii) the phase lag (angle) of the response strain or stress δ, or (iii) the tangent (tan) δ, and (c) assessing at least one of the G′, G″, δ, or tan(δ) determined.
    • 提供了一种确定聚合物在润滑油中形成网络或凝胶的倾向的方法,其包括在稀释剂中获得聚合物的组成,测量作为剪切速率的函数的剪切应力,使用赫歇尔测定屈服应力 -Bulkley方程并评估屈服应力。 还提供了一种确定聚合物在润滑油中形成网络或凝胶的倾向的方法,其包括获得稀释剂中聚合物的组成,确定以下中的至少一个:(i)储能模量G'和损耗模量G 通过使组合物经受一定幅度和频率的正弦(振荡)应力或应变,(ii)响应应变或应力δ的相位滞后(角度),或(iii)正切(tanδ)δ, 和(c)评估确定的G',G“,δ或tan(δ)中的至少一个。