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31. 发明授权

US5455140A Methine-dye releasing couplers for heat image separation systems 失效
标题翻译：用于热图像分离系统的甲基染料释放成色剂
公开(公告)号：US5455140A
公开(公告)日：1995-10-03
申请号：US250145
申请日：1994-05-27
申请人： John Texter , Thomas R. Welter , David T. Southby , Jared B. Mooberry
发明人： John Texter , Thomas R. Welter , David T. Southby , Jared B. Mooberry
IPC分类号： G03C8/10 , G03C8/40 , G03C8/12
CPC分类号： G03C8/10 , G03C8/4013
摘要： An aqueous-developable photographic color diffusion transfer element is disclosed where this element comprises one and only one dimensionally stable support and one or more layers comprising radiation sensitive silver halide, thermal solvent for facilitating the thermal diffusion of dyes through a hydrophilic binder, a methine-dye releasing coupler, and hydrophilic binder, wherein said dye is heat diffusible in said binder and thermal solvent, and wherein said methine-dye releasing coupler is of the structure (I)Cp--L--M (I)whereCp is a coupler radical substituted in the coupling position with a divalent linking group, L;M is a methine-dye radical exhibiting selective absorption in the visible spectrum; and where the --L--M group couples off upon reaction of said coupler radical with the oxidation product of a primary amine developing agent, and where said methine-dye radical M is released from said --L--M group subsequent to the coupling off of said --L--M group.Also disclosed in this invention is a diffusion transfer process for forming a color photographic image comprising the steps of:exposing said element to actinic radiation; processing said element by immersing said element in an external aqueous bath containing color developer of the primary amine type;washing said element;drying said element to remove the imbibed water; andheating said element to effect dye diffusion transfer to an image receiving layer.
摘要翻译：公开了一种含水显影照相色彩扩散转移元件，其中该元件包括一个且仅一维稳定的载体，以及包含辐射敏感卤化银的一层或多层，用于促进染料通过亲水性粘合剂的热扩散的热溶剂，染料释放成色剂和亲水性粘合剂，其中所述染料在所述粘合剂和热溶剂中是热扩散的，并且其中所述次甲基染料释放成色剂具有结构式（I）Cp-LM（I），其中Cp是取代基与二价连接基团的偶联位置L; M是在可见光谱中表现出选择性吸收的次甲基染料基团; 并且其中-LM基团在所述成色剂基团与伯胺显影剂的氧化产物反应时脱离，并且其中所述次甲基染料基团M在所述-LM基团的偶联之后从所述-LM基团释放出来。本发明还公开了用于形成彩色照相图像的扩散转移方法，包括以下步骤：将所述元件暴露于光化辐射; 通过将所述元件浸入含有伯胺型彩色显影剂的外部水浴中来处理所述元件; 洗涤元素; 干燥所述元件以除去吸收的水; 并加热所述元件以进行染料扩散转移到图像接收层。

32. 发明授权

US5356750A Dye releasing couplers for heat image separation systems 失效
标题翻译：用于热图像分离系统的脱色成色剂
公开(公告)号：US5356750A
公开(公告)日：1994-10-18
申请号：US993580
申请日：1992-12-21
申请人： John Texter , Thomas R. Welter , David T. Southby , Jared B. Mooberry
发明人： John Texter , Thomas R. Welter , David T. Southby , Jared B. Mooberry
IPC分类号： G03C8/10 , G03C8/40 , G03C5/54
CPC分类号： G03C8/4033 , G03C8/10 , G03C8/4066
摘要： An aqueous-developable photographic color diffusion transfer element comprising a single dimensionally stable support and one or more layers comprising radiation sensitive silver halide, thermal solvent for facilitating the thermal diffusion of dyes through a hydrophilic binder, a dye-releasing coupler, and hydrophilic binder, wherein said dye is heat diffusible in said binder and thermal solvent, and wherein said dye-releasing coupler is of the structureCp--L-DyewhereCp is a cyan dye forming radical, magenta dye forming radical, yellow dye forming radical, black dye forming radical, or colorless product forming radical, said Cp being substituted in the coupling position with a divalent linking group, L;Dye is a dye radical exhibiting selective absorption in the visible spectrum; and where said --L-Dye group couples off upon reaction of said coupler radical with the oxidation product of a primary amine developing agent is disclosed.
摘要翻译：含水显影照相色彩扩散转移元件包括单尺寸稳定的载体和一层或多层包含辐射敏感的卤化银，用于促进染料通过亲水性粘合剂的热扩散的热溶剂，染料释放成色剂和亲水性粘合剂，其中所述染料在所述粘合剂和热溶剂中是热扩散的，并且其中所述染料释放成色剂具有结构Cp-L-Dye，其中Cp是形成自由基的青色染料，形成自由基的品红色染料，形成自由基的黄色染料，黑色染料形成自由基或无色产物形成基团，所述Cp在偶联位置被二价连接基团L取代; 染料是在可见光谱中显示出选择性吸收的染料基团; 并且其中所述-L-染料基团在所述成色剂基团与伯胺显影剂的氧化产物反应时偶联。

33. 发明授权

US5108902A Reducible compounds which provide aniline dyes for analytical compositions and methods of using same 失效
标题翻译：为分析组合物提供苯胺衍生物的可降解化合物及其使用方法
公开(公告)号：US5108902A
公开(公告)日：1992-04-28
申请号：US215127
申请日：1988-07-05
申请人： Jared B. Mooberry
发明人： Jared B. Mooberry
IPC分类号： G01N31/22 , C09B23/00 , C09B23/14 , C09B29/00 , C09B29/06 , C09B53/00 , C09B55/00 , C09B62/78 , C09B62/825 , C12Q1/00 , C12Q1/04 , G01N21/77 , G01N33/493 , G01N33/52
CPC分类号： C09B29/06 , C12Q1/04 , G01N33/52 , C12Q2304/20
摘要： Certain reducible compounds are useful in analytical compositions, elements and methods, for example for the detection of bacterial cells. These compounds comprise a moiety which provides an aniline dye upon reduction. Structurally, the reducible compounds are quinones having suitable substituents which promote varying amounts of aniline dye release at physiological pH.

34. 发明授权

US5019492A Photographic element and process comprising a blocked photographically useful compound 失效
标题翻译：摄影元件和包含封闭的照相用化合物的方法
公开(公告)号：US5019492A
公开(公告)日：1991-05-28
申请号：US343981
申请日：1989-04-26
申请人： John M. Buchanan , Ewell R. Cook , Jared B. Mooberry , Gary S. Proehl , Stephen P. Singer , William N. Washburn
发明人： John M. Buchanan , Ewell R. Cook , Jared B. Mooberry , Gary S. Proehl , Stephen P. Singer , William N. Washburn
IPC分类号： G03C1/06 , G03C1/43 , G03C7/305 , G03C7/392
CPC分类号： G03C7/30511 , Y10S430/156 , Y10S430/157 , Y10S430/158 , Y10S430/159 , Y10S430/16 , Y10S430/161
摘要： A novel blocked photographically useful compound comprises a new blocking group that (a) comprises two electrophilic groups, the least electrophilic of which is bonded directly or through a timing group to the photographically useful group (PUG) of the compound, (b) is capable of reacting with a dinucleophile reagent, and (c) has the two electrophilic groups separated from each other by a bond or unsubstituted or substituted atom that enables nucleophilic displacement to occur with release of PUG when the compound is reacted with a dinucleophile reagent. Such a blocked photographically useful compound is useful in a photographic material and process to provide increased stability and enable more rapid release of the photographically useful group upon reaction with a dinucleophile reagent.

35. 发明授权

US4283472A Silver halide elements containing blocked pyrazolone magenta dye-forming couplers 失效
标题翻译：含有封闭的吡唑啉酮品红色染料形成成色剂的卤化银元素
公开(公告)号：US4283472A
公开(公告)日：1981-08-11
申请号：US124872
申请日：1980-02-26
申请人： Thomas E. Gompf , Howell A. Hammond , Jared B. Mooberry
发明人： Thomas E. Gompf , Howell A. Hammond , Jared B. Mooberry
IPC分类号： G03C7/38 , C07D231/52 , C09B26/02 , G03C7/384 , G03C7/00
CPC分类号： C07D231/52 , G03C7/384
摘要： Novel 5-pyrazolone magenta dye-forming couplers are blocked with a coupler moiety which yields an alkali-soluble or colorless reaction product. The coupler moiety is joined via its coupling position to the enol oxygen of the 5-pyrazolone and is displaced therefrom during processing as a result of reaction by means of oxidized color developing agent to thereby activate the 5-pyrazolone coupler. These couplers have good reactivity and good resistance to aerial contaminants, such a formaldehyde, and can be incorporated in photographic emulsions and elements.
摘要翻译：新的5-吡唑啉酮品红色染料形成成色剂用产生碱溶性或无色反应产物的成色剂部分封闭。成色剂部分通过其耦合位置连接到5-吡唑啉酮的烯醇氧，并且在加工过程中由于通过氧化的彩色显影剂反应的结果而被取代，从而活化5-吡唑啉酮成色剂。这些成色剂具有良好的反应性和对空气污染物（如甲醛）的良好抗性，并且可以并入摄影乳剂和元素中。

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