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31. 发明授权

US4506039A Process for the production of polymer-containing aromatic polyether polyamines 失效
标题翻译：用于生产含聚合物的芳族聚醚多胺的方法
公开(公告)号：US4506039A
公开(公告)日：1985-03-19
申请号：US450813
申请日：1982-12-20
申请人： Gerhard Balle , Werner Rasshofer , Winfried Schoberth
发明人： Gerhard Balle , Werner Rasshofer , Winfried Schoberth
IPC分类号： C08F283/00 , C08F283/06 , C08G18/00 , C08G18/10 , C08G18/63 , C08G18/14 , C08G67/02
CPC分类号： C08G18/632 , C08F283/06 , C08G18/10
摘要： Polymer-containing polyether polyamines containing terminal aromatically-bound amino groups are produced by in situ polymerization of a polyether polyamine with an olefinically unsaturated monomer. The polyether polyamine starting material must have terminal aromatic amino groups, a molecular weight of from 800 to 10,000 and an aromatic amino group content of from 0.3 to 16 wt. %. Suitable olefinically unsaturated monomers include .alpha.,.beta.-unsaturated nitriles, aromatic vinyl compounds, .alpha.,.beta.-unsaturated carboxylic acids and esters thereof, vinyl esters, vinyl halides, vinylidene halides, .alpha.,.beta.-unsaturated carboxylic acid amides and aminoalkyl esters of unsaturated carboxylic acids. Acrylonitrile/styrene mixtures are preferred monomers. The starting materials are employed in quantities such that the product modified polyether polyamine contains from 1 to 60 wt. % polymer or graft-polymer. The product polyamines are particularly useful in the production of polyurethanes.
摘要翻译：通过聚醚多胺与烯属不饱和单体的原位聚合制备含末端芳香结合氨基的含聚合物聚醚多胺。聚醚多胺原料必须具有末端芳族氨基，分子量为800至10,000，芳族氨基含量为0.3至16重量％。％。合适的烯属不饱和单体包括α，β-不饱和腈，芳族乙烯基化合物，α，β-不饱和羧酸及其酯，乙烯基酯，乙烯基卤化物，亚乙烯基卤化物，α，β-不饱和羧酸酰胺和不饱和羧酸的氨基烷基酯酸。丙烯腈/苯乙烯混合物是优选的单体。原料的使用量使得产物改性的聚醚多胺含有1至60wt。％聚合物或接枝聚合物。产物多胺在聚氨酯的生产中特别有用。

32. 发明授权

US4472568A Process for the preparation of polyamines from N-monoaryl-N',N'-dialkyl urea compounds and their use for the synthesis of polyurethanes 失效
标题翻译：由N-单芳基-N'，N'-二烷基脲化合物制备多胺的方法及其在聚氨酯合成中的应用
公开(公告)号：US4472568A
公开(公告)日：1984-09-18
申请号：US437398
申请日：1982-10-28
申请人： Werner Rasshofer , Gerhard Grogler
发明人： Werner Rasshofer , Gerhard Grogler
IPC分类号： C08G18/00 , C07C67/00 , C07C239/00 , C07C273/18 , C07C275/28 , C08G18/10 , C08G18/38 , C08G18/50 , C08G18/83 , C07C127/15 , C07C127/24
CPC分类号： C08G18/83 , C07C273/1854 , C08G18/10 , C08G18/3819 , C08G18/5036
摘要： This invention relates to an improved process for the preparation of aromatic polyamines containing urethane and/or biuret and/or urea and/or isocyanurate groups and preferably also ether groups by the hydrolysis of poly-N-monoaryl-N',N'-dialkyl urea compounds (1-aryl-3,3-dialkyl ureas). The ureas are obtained by the reaction of secondary aliphatic, cycloaliphatic or saturated heterocyclic amines with divalent to tetravalent isocyanate compounds containing isocyanate end groups attached to aromatic residues. The ureas correspond to the general formula: ##STR1## wherein R.sup.1, R.sup.2 denote alkyl or cycloalkyl groups, or together form a ring andA denotes a divalent to tetravalent residue attached to the ureas by aromatic groups.Hydrolysis is carried out in the presence of water and up to two equivalents of a base containing hydroxide ions and/or up to two equivalents of a compound containing tertiary amino groups, optionally in the presence of solvents. The use of the polyamines obtained by this process for the synthesis of polyurethanes is also described.
摘要翻译：本发明涉及一种改进的制备含氨基甲酸酯和/或缩二脲和/或脲和/或异氰脲酸酯基团的芳族多胺的方法，优选通过水解聚-N-单芳基-N'，N'-二烷基脲化合物（1-芳基-3,3-二烷基脲）。脲通过仲脂族，脂环族或饱和杂环胺与含有连接到芳族残基的异氰酸酯端基的二价至四价异氰酸酯化合物的反应获得。脲对应于以下通式：其中R 1，R 2表示烷基或环烷基，或一起形成环，A表示通过芳族基团连接到脲上的二价至四价残基。任选在溶剂存在下，在水的存在下和至多两当量的含氢氧根离子的碱和/或至多两当量的含有叔氨基的化合物进行水解。还描述了通过该方法获得的用于合成聚氨酯的多胺的用途。

33. 发明授权

US4436841A Single-phase, storage-stable polyol compositions containing salts and the use thereof in the production of polyurethanes 失效
标题翻译：含有盐的单相，储存稳定的多元醇组合物及其在生产聚氨酯中的用途
公开(公告)号：US4436841A
公开(公告)日：1984-03-13
申请号：US497640
申请日：1983-05-24
申请人： Werner Rasshofer , Wolfgang Reichmann , Adolf Richartz , Manfred Dietrich
发明人： Werner Rasshofer , Wolfgang Reichmann , Adolf Richartz , Manfred Dietrich
IPC分类号： C08G18/66 , C08K5/053 , C09K3/00 , C08G18/14 , C08G18/65
CPC分类号： C08G18/6674 , C08K5/053 , C08G2120/00 , C08G2130/00 , Y10S521/914
摘要： A single-phase, storage-stable, emulsifier-free polyol mixture comprising 100 parts of a relatively high molecular weight polyoxyalkylene polyol of OH number from 20 to 120, which has at least 5% and less than 80% by weight, of terminal oxyethylene blocks; from 1 to 100 parts of a low molecular weight diol mixture which is a reaction product of ethylene glycol, butane diol-1,4, or a mixture of ethylene glycol and butane diol-1,4, with from 0.05 to 0.50 mols of alkyl oxiranes; from 0.1 to 5 parts of solubilizing additives comprising one or more salts, the cations of which are from Groups I, II and III of the Periodic Table, ammonium or mono- to tetra-alkyl ammonium ions, and the anions of which are produced by removing at least one proton from an acid having a K.sub.s value of at least 10.sup.-7 ; and, optionally, other compounds having isocyanate-reactive hydrogen atoms and other auxiliaries and additives for polyurethane production. Also polyurethanes produced using these polyol mixtures.
摘要翻译：一种单相，储存稳定，不含乳化剂的多元醇混合物，其包含100份具有20-120的OH数量的相对高分子量的聚氧化烯多元醇，其具有至少5重量％且小于80重量％的末端氧化乙烯块 1至100份低分子量二醇混合物，其是乙二醇，丁二醇-1,4-或乙二醇和丁二醇-1,4-的混合物与0.05至0.50摩尔烷基的反应产物环氧乙烷 0.1至5份包含一种或多种盐的增溶添加剂，其阳离子来自周期表第I，II和III族，铵或一至四烷基铵离子，其阴离子由从Ks值至少为10-7的酸中除去至少一个质子; 和任选的具有异氰酸酯反应性氢原子的其它化合物和用于聚氨酯生产的其它助剂和添加剂。还使用这些多元醇混合物制备聚氨酯。

34. 发明授权

US4386218A Polyamines and processes for the production of such polyamines and of polyurethane plastics therefrom 失效
标题翻译：用于生产这种多胺和聚氨酯塑料的多胺和方法
公开(公告)号：US4386218A
公开(公告)日：1983-05-31
申请号：US308326
申请日：1981-10-05
申请人： Werner Rasshofer , Dieter Dieterich , Holger Meyborg
发明人： Werner Rasshofer , Dieter Dieterich , Holger Meyborg
IPC分类号： C07C275/62 , B01J23/02 , B01J31/08 , C07B61/00 , C07C271/20 , C07C271/26 , C07C273/18 , C07C275/00 , C07C275/14 , C08G18/00 , C08G18/10 , C08G18/32 , C08G18/50 , C08G18/65 , C08G18/83 , C07C127/15 , C07C127/24
CPC分类号： C08G18/83 , C07C273/1809 , C08G18/10 , C08G18/5048
摘要： A compound having a terminal isocyanate group is hydrolyzed to produce a polyamine having a urethane and/or a urea and/or a biuret group. More particularly, a carbamate is made by mixing an isocyanate prepolymer having urethane and/or urea and/or biuret groups present with aqueous base solutions at a temperature of from 0.degree. to 0.degree. C. and in quantities such that the equivalent ratio of hydroxyl to isocyanate groups is between from 0.3:1 to .gtoreq.1.01 to 1. The carbamate is then treated with an acid ion exchanger to form an amine. The amine is then removed from any other material which may be present. A preferred polyamine thus-produced corresponds to the general formula: ##STR1## in which each R radical may represent a divalent straight or branched-chain aliphatic radical; a divalent cycloaliphatic radical; a 4,4'- and/or a 2,4'-dicyclohexylmethane radical; or a 2,4- and/or 2,6-methyl cyclohexane radical. Such an amine may be reacted with a polyisocyanate and optionally with other known additives to form a polyurethane plastic or foam.
摘要翻译：将具有末端异氰酸酯基的化合物水解以制备具有氨基甲酸酯和/或脲和/或缩二脲基的多胺。更具体地，氨基甲酸酯是通过在0℃至0℃的温度下混合存在有氨基甲酸酯和/或脲和/或缩二脲基的异氰酸酯预聚物和/或缩二脲基与碱水溶液形成的，其量使得羟基的当量比到异氰酸酯基团之间的比例为0.3:1至> / = 1.01:1。然后用酸式离子交换剂处理氨基甲酸酯以形成胺。然后将胺从可能存在的任何其它材料中除去。如此制备的优选的多胺对应于通式：其中每个R基团可以表示二价直链或支链脂族基团; 二价脂环族基团; 4,4'-和/或2,4'-二环己基甲基基团; 或2,4-和/或2,6-甲基环己烷基。这样的胺可以与多异氰酸酯和任选地与其它已知的添加剂反应以形成聚氨酯塑料或泡沫。

35. 发明授权

US4384102A Process for the preparation of compounds having s-triazine units and epoxide groups 失效
标题翻译：制备具有三嗪单元和环氧基团的化合物的方法
公开(公告)号：US4384102A
公开(公告)日：1983-05-17
申请号：US336659
申请日：1982-01-04
申请人： Werner Rasshofer , Gerhard Grogler , Richard Kopp
发明人： Werner Rasshofer , Gerhard Grogler , Richard Kopp
IPC分类号： C07D405/14 , C07D405/12 , C08G18/00 , C08G18/79 , C08G18/80 , C08G18/77
CPC分类号： C07D405/12 , C08G18/003 , C08G18/8058
摘要： Compounds having both s-triazine units and epoxide groups present are prepared by reacting an epoxide containing an isocyanate-reactive group with a triisocyanate corresponding to the formula: ##STR1## in which X is as defined herein. These reactants are used in quantities such that the equivalent ratio of isocyanate groups to isocyanate-reactive groups is maintained at less than or equal to 1 to 1. The compounds thus produced are particularly useful as reactive cross-linkers in the production of polyurethanes and polyepoxides.
摘要翻译：通过使含有异氰酸酯反应性基团的环氧化物与对应于下式的其中X如本文所定义的下式的三异氰酸酯反应来制备具有均三嗪单元和环氧基团的化合物。这些反应物的用量使得异氰酸酯基团与异氰酸酯反应性基团的当量比保持在小于或等于1比1。由此制备的化合物特别可用作聚氨酯和聚环氧化物生产中的反应性交联剂。

36. 发明授权

US4360603A Process for the preparation of compounds containing s-triazine units and isocyanate groups or isocyanate-reactive groups and the production of polyurethanes containing these fillers 失效
标题翻译：用于制备含有三嗪单元和异氰酸酯基团或异氰酸酯反应性基团的化合物的方法以及含有这些填料的聚氨酯的生产方法
公开(公告)号：US4360603A
公开(公告)日：1982-11-23
申请号：US323331
申请日：1981-11-20
申请人： Gerhard Grogler , Werner Rasshofer , Richard Kopp
发明人： Gerhard Grogler , Werner Rasshofer , Richard Kopp
IPC分类号： C08G18/00 , C07D251/70 , C08G18/38 , C08G18/79 , C08G18/80 , C08L75/00 , C08L75/04 , C08G18/14
CPC分类号： C08G18/8003 , C07D251/70 , C08G18/3851 , C08G18/8058
摘要： This invention relates to a process for the preparation of compounds which contain s-triazine units and isocyanate groups or isocyanate-reactive groups and which melt without decomposition, by the reaction of triisocyanates containing s-triazine units with compounds containing isocyanate-reactive groups, and the use of these products as fillers which can be chemically fixed in the production of polyurethanes by the isocyanate polyaddition process.
摘要翻译：本发明涉及一种制备含有三嗪单元和异氰酸酯基团或异氰酸酯反应性基团并通过含有三嗪单元的三异氰酸酯与含有异氰酸酯反应性基团的化合物反应熔融而不分解的化合物的方法，以及这些产品的使用可以通过异氰酸酯加聚方法在化学上固定在聚氨酯的生产中。

37. 发明授权

US06428895B1 Stable adhesive composite material made of polyurethane and of another thermoplastic material, a process for its production and a method for its use in motor vehicles 失效
标题翻译：由聚氨酯和另一种热塑性材料制成的稳定的粘合剂复合材料，其生产方法及其用于机动车辆的方法
公开(公告)号：US06428895B1
公开(公告)日：2002-08-06
申请号：US09919384
申请日：2001-07-31
申请人： Karsten Reihs , Werner Rasshofer , Holger Warth , Dirk Wegener , Manfred Schmidt , Peter Heitkämper
发明人： Karsten Reihs , Werner Rasshofer , Holger Warth , Dirk Wegener , Manfred Schmidt , Peter Heitkämper
IPC分类号： B32B710
CPC分类号： B32B27/40 , B32B5/18 , B32B27/32 , B32B27/34 , B32B27/365 , B32B2266/0278 , B32B2323/04 , B32B2323/10 , B32B2367/00 , B32B2369/00 , B32B2375/00 , C08J5/12 , C08J2375/04 , C09J175/08 , Y10T428/31507 , Y10T428/31551 , Y10T428/31562 , Y10T428/31565 , Y10T428/31587 , Y10T428/31598 , Y10T428/31739
摘要： The present invention relates to composite materials made of at least one composite layer of a polyurethane and of a second composite layer which is directly bonded to the first layer and which consists of a thermoplastic material that is different from the polyurethane of layer A). The polyurethane material of layer A) is characterized by a residual content of free reaction components containing ether groups of no more than 400 ppm, and preferably of no more than 100 ppm. The invention also relates to a process for the production of these composite materials and to a method of their use as materials in motor vehicles.
摘要翻译：本发明涉及由聚氨酯和第二复合层的至少一个复合层制成的复合材料，所述复合层直接结合到第一层，并且由不同于层A）的聚氨酯的热塑性材料组成。层A）的聚氨酯材料的特征在于含有不超过400ppm，优选不超过100ppm的醚基的游离反应组分的残留含量。本发明还涉及一种生产这些复合材料的方法及其作为机动车辆材料的方法。

38. 发明授权

US6020386A Process for the production of hydroxyfunctional compounds from (polyurethane) polyurea waste 失效
标题翻译：从（聚氨酯）聚脲废料生产羟基官能化合物的方法
公开(公告)号：US6020386A
公开(公告)日：2000-02-01
申请号：US189861
申请日：1994-02-01
申请人： Thomas Munzmay , Walter Meckel , Ulrich Liman , Hartmut Nefzger , Werner Rasshofer , Karl-Heinz Dorner , Andreas Ruckes
发明人： Thomas Munzmay , Walter Meckel , Ulrich Liman , Hartmut Nefzger , Werner Rasshofer , Karl-Heinz Dorner , Andreas Ruckes
IPC分类号： C08G18/83 , C08G18/32 , C08J11/22 , C08L75/00 , C08J11/04
CPC分类号： C08J11/22 , C08J2375/00 , Y02P20/582 , Y02W30/706
摘要： Hydroxyfunctional compounds suitable for use in the polyisocyanate polyaddition process are obtained from polyurethane and/or polyurethane polyurea waste by decomposition with an alcohol and subsequent reaction of the alcoholysis products to reduce their content of low molecular weight, sterically unhindered aromatic amines. In this process, polyurethane and/or polyurethane polyurea waste is first treated with a low molecular weight diol or polyol at a temperature of from about 160 to 260.degree. C. The resultant alcoholysis product may then either be further heated at a temperature lower than that used in the first step within the ranger of from about 50 to 180.degree. C. or reacted with a dialkyl carbonate and/or 1,3-dicarbonyl compound.
摘要翻译：适用于多异氰酸酯加聚方法的羟基官能化合物通过用醇分解从聚氨酯和/或聚氨酯聚脲废物中获得，随后醇解产物的反应降低其低分子量空间不受阻碍的芳族胺的含量。在该方法中，聚氨酯和/或聚氨酯聚脲废物首先在约160至260℃的温度下用低分子量二醇或多元醇进行处理。然后可以在低于该温度的温度下进一步加热得到的醇解产物。在第一步中用于约50至180℃的游C.，或与碳酸二烷基酯和/或1,3-二羰基化合物反应。

39. 发明授权

US5879608A Molded polyurethane articles prepared from recycled polyols and processes for their production and use 失效
标题翻译：由回收多元醇制备的模制聚氨酯制品及其生产和使用方法
公开(公告)号：US5879608A
公开(公告)日：1999-03-09
申请号：US740551
申请日：1996-10-30
申请人： Adolf Lammeck , Werner Rasshofer
发明人： Adolf Lammeck , Werner Rasshofer
IPC分类号： C08G18/40 , C08G18/83 , C08G101/00 , C08J11/24 , B27N3/08 , B28B19/00 , B29C51/00 , B29C53/00
CPC分类号： C08J11/24 , C08J2375/04 , Y02W30/706
摘要： Molded polyurethane articles are made by reacting polyisocyanates with polyol compositions obtained by chemical decomposition of polyurethane and/or polyurea waste in a mold. The polyol compositions employed in this invention have an OH value of from about 100 to about 500 mg KOH/g, a water content of from 0 to about 5 wt. % and a viscosity at 20.degree. C. of more than 2,000 mPa.multidot.s. These molded polyurethane articles preferably have a sandwich structure in which the core is a polyurethane and there is at least one outer layer made from an optionally fiber-reinforced plastic material. These molded polyurethane articles are useful in the motor vehicle, furniture, machine and equipment manufacturing industries.
摘要翻译：聚氨酯制品是通过使多异氰酸酯与通过在模具中化学分解聚氨酯和/或聚脲废物获得的多元醇组合物而制成的。用于本发明的多元醇组合物的OH值为约100至约500mg KOH / g，水含量为0至约5wt。％，在20℃下的粘度超过2,000mPax。这些模制的聚氨酯制品优选具有夹心结构，其中芯是聚氨酯，并且存在由任选的纤维增强塑料材料制成的至少一个外层。这些模塑聚氨酯制品可用于机动车辆，家具，机器和设备制造业。

40. 发明授权

US5210127A Free-flowing, thermoplastically processible and post-crosslinkable polyurethane powders 失效
标题翻译：自由流动，热塑性可交联聚氨酯粉末
公开(公告)号：US5210127A
公开(公告)日：1993-05-11
申请号：US964592
申请日：1992-10-21
申请人： Joachim Werner , Walter Meckel , Ulrich Liman , Dirk Wegener , Werner Rasshofer , James W. Rosthauser
发明人： Joachim Werner , Walter Meckel , Ulrich Liman , Dirk Wegener , Werner Rasshofer , James W. Rosthauser
IPC分类号： C08G18/00 , C08G18/08 , C08G18/10 , C08G18/79 , C08G18/80 , C08J3/12 , C08J3/24 , C08J5/18 , C08J9/10 , C08J9/16 , C08L75/00 , C08L75/04
CPC分类号： C08J3/24 , C08G18/0871 , C08G18/10 , C08G18/8064 , C08G2101/00 , C08G2140/00 , C08G2350/00 , C08G2410/00 , C08J2375/04
摘要： Novel powders useful in the slush molding process are produced by reacting an emulsion of either an isocyanate or an isocyanate reactive material with either an isocyanate reactive material or an isocyanate, depending upon the nature of the component used to make the emulsion in the presence of an at least partially blocked isocyanate and an organic carrier. The final reaction product is subsequently removed from the carrier.
摘要翻译：通过将异氰酸酯或异氰酸酯反应性材料的乳液与异氰酸酯反应性材料或异氰酸酯反应来制备可用于搪塑成型方法的新型粉末，这取决于在存在下制备乳液的组分的性质至少部分封端的异氰酸酯和有机载体。随后从载体中除去最终的反应产物。

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