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    • 37. 发明授权
    • Composition for resist underlayer film and method for producing the same
    • 抗蚀剂下层膜用组合物及其制造方法
    • US06576393B1
    • 2003-06-10
    • US09545453
    • 2000-04-07
    • Hikaru SugitaAkio SaitoKinji YamadaMichinori NishikawaYoshihisa OhtaYoshiji Yuumoto
    • Hikaru SugitaAkio SaitoKinji YamadaMichinori NishikawaYoshihisa OhtaYoshiji Yuumoto
    • G03C173
    • G03F7/0751G03F7/09Y10S430/106Y10S430/115Y10S430/12Y10S430/122Y10S430/124Y10S430/126
    • Disclosed are a composition for a resist underlayer film excellent in reproducibility of a resist pattern, excellent in adhesion to a resist, excellent in resistance to a developing solution used after exposure of the resist and decreased in film loss in oxygen ashing of the resist; and a method for producing the same, the composition comprising: both or either of a hydrolysate and a condensate of (A) at least one compound selected from the group consisting of (A-1) a compound represented by the following general formula (1): R1aSi(OR2)4−a  (1) wherein R1 represents a hydrogen atom, a fluorine atom or a univalent organic group, R2 represents a univalent organic group, and a represents an integer of 0 to 2, and (A-2) a compound represented by the following general formula (2): R3b(R4O)3−bSi—(R7)d—Si(OR5)3−cR6c  (2) wherein R3, R4, R5 and R6, which may be the same or different, each represent univalent organic groups, b and c, which may be the same or different, each represent integers of 0 to 2, R7 represents an oxygen atom or —(CH2)n—, d represents 0 or 1, and n represents an integer of 1 to 6; and (B) a compound generating an acid by ultraviolet irradiation and/or heating.
    • 公开了抗蚀剂图案的再现性优异的抗蚀剂下层膜的组合物,对抗蚀剂的附着性优异,对抗蚀剂曝光后使用的显影液的耐受性优异,抗蚀剂的氧气灰化的膜损失降低; 及其制备方法,该组合物包含:(A)至少一种选自(A-1)由下列通式(1)表示的化合物的化合物的水解产物和缩合物: ):其中R1表示氢原子,氟原子或一价有机基团,R2表示一价有机基团,a表示0〜2的整数,(A-2)由以下通式( 2):其中可以相同或不同的R 3,R 4,R 5和R 6各自表示一价有机基团,b和c可以相同或不同,各自表示0-2的整数,R7表示氧 原子或 - (CH 2)n - ,d表示0或1,n表示1〜6的整数。 和(B)通过紫外线照射和/或加热产生酸的化合物。
    • 39. 发明授权
    • Curable resin composition cured products
    • 固化树脂组合物固化产物
    • US06313233B1
    • 2001-11-06
    • US09447952
    • 1999-11-29
    • Takahiko KurosawaKinji YamadaMinoru MatsubaraYasutake InoueTomotaka ShinodaKouhei Gotou
    • Takahiko KurosawaKinji YamadaMinoru MatsubaraYasutake InoueTomotaka ShinodaKouhei Gotou
    • C08G6548
    • H01L21/02126C08G77/455C08K5/5415C08L79/08C09D183/10H01L21/312C08L2666/52
    • A curable resin composition comprising (A) a hydrolyzate or a partial condensate of an organosilane compound, or both; (B) at least one compound selected from the group consisting of polyamic acids having a hydrolyzable silyl group or carboxylic acid anhydride group, or both, and polyimides having a hydrolyzable silyl group or carboxylic acid anhydride group, or both; and (C) a chelate compound or an alkoxide compound with a metal selected from the group consisting of zirconium, titanium, and aluminum, or both the chelate compound and the alkoxide compound. The resin composition can be cured and fabricated without producing no cracks into a cured product such as a semiconductor device having a low dielectric constant, high heat resistance and moisture resistance, superior adhesion to various substrate materials, superb electrical insulation properties, and low moisture absorption. Semiconductor devices using this curable resin composition as an insulating film exhibit a low electricity consumption, work at a high speed, and have excellent reliability.
    • 一种可固化树脂组合物,其包含(A)有机硅烷化合物的水解产物或部分缩合物,或两者; (B)至少一种选自具有水解性甲硅烷基或羧酸酐基团的聚酰胺酸或二者的化合物和具有可水解甲硅烷基或羧酸酐基团的聚酰亚胺或两者; 和(C)螯合化合物或选自锆,钛和铝的金属的醇盐化合物,或螯合化合物和醇盐化合物两者。 可以固化和制造树脂组合物,而不会在诸如具有低介电常数,高耐热性和耐湿性,优异的各种基材的粘合性,优异的电绝缘性能和低吸湿性的半导体装置等固化产物中不产生裂纹 。 使用该固化性树脂组合物作为绝缘膜的半导体装置的电耗低,高速工作,可靠性优异。