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31. 发明授权

US5874605A Process for preparing aromatic carbonic ester 失效
标题翻译：制备芳香族碳酸酯的方法
公开(公告)号：US5874605A
公开(公告)日：1999-02-23
申请号：US465
申请日：1998-02-03
申请人： Hiroshi Yoshida , Hideaki Tsuneki , Atusi Moriya , Hiroki Wakayama , Kenichi Watanabe , Yoshiyuki Onda
发明人： Hiroshi Yoshida , Hideaki Tsuneki , Atusi Moriya , Hiroki Wakayama , Kenichi Watanabe , Yoshiyuki Onda
IPC分类号： B01J31/12 , C07B61/00 , C07C68/06 , C07C68/08 , C07C69/96
CPC分类号： C07C68/06 , Y02P20/127
摘要： An aromatic carbonate ester is continuously and efficiently prepared by the transesterification of an aromatic carboxylate with an aliphatic carbonate ester and/or aromatic.aliphatic carbonate ester. A raw material including an aromatic carboxylate, aliphatic carbonate ester and/or aromatic.aliphatic carbonate ester, and a catalyst are continuously fed to a first stage of a reactive distillation column (1) through a raw material feeding pipe (5). Meanwhile, an aliphatic carbonate ester (a) whose boiling point is lower than that of a reactant liquid that is present in a second stage lower than the first stage is continuously fed to the second stage through an aliphatic carbonate ester (a) feeding pipe (6). The second stage is preferably a column bottom section of the reactive distillation column (1). The amount of aliphatic carbonate ester (a) fed is preferably 0.001 to 5 times, by weight, more than the amount of the raw material fed.
摘要翻译： PCT No.PCT / JP97 / 02000 Sec。 371日期1998年2月3日 102（e）1998年2月3日PCT 1997年6月10日PCT公布。 WO97 / 47586 PCT公开号日期1997年12月18日芳族羧酸酯与脂族碳酸酯和/或芳族脂族碳酸酯的酯交换连续有效地制备芳族碳酸酯酯。包含芳族羧酸酯，脂族碳酸酯和/或芳香族脂肪族碳酸酯的催化剂和催化剂通过原料输送管（5）连续供给至反应蒸馏塔（1）的第一阶段。同时，通过脂肪族碳酸酯（a）进料管（a）向第二阶段连续供给沸点低于第一阶段的第二阶段的反应液的沸点的脂肪族碳酸酯（a） 6）。第二阶段优选为反应蒸馏塔（1）的塔底部分。进料的脂肪族碳酸酯（a）的量优选为进料原料量的0.001〜5倍。

32. 发明授权

US5663480A Synthesis of aromatic carbonates by transesterification using a catalyst comprising a microporous material and a group IV metal 失效
标题翻译：通过使用包含微孔材料和IV族金属的催化剂的酯交换合成芳族碳酸酯
公开(公告)号：US5663480A
公开(公告)日：1997-09-02
申请号：US680223
申请日：1996-07-11
申请人： Hideaki Tsuneki , Masaru Kirishiki , Kenichi Watanabe , Yoshiyuki Onda
发明人： Hideaki Tsuneki , Masaru Kirishiki , Kenichi Watanabe , Yoshiyuki Onda
IPC分类号： C07C67/03 , C07C68/06
CPC分类号： C07C68/06 , B01J29/0308 , B01J29/84 , B01J29/89
摘要： A catalyst for producing an aryl ester of a carbonic or carboxylic acid is disclosed, which includes a microporous material containing a metal element belonging to group IV. This catalyst can be used as a heterogeneous catalyst to produce the aryl ester in high yield with industrial advantages. In order to produce the aryl ester using the catalyst, a carbonate or an aliphatic carboxylate is transesterified with an aromatic hydroxy compound, or an aryl carboxylate is transesterified with a carbonate, or an alkyl aryl carbonate is disproportionated by transesterification.
摘要翻译：公开了一种用于生产碳酸或羧酸的芳基酯的催化剂，其包括含有属于IV族的金属元素的微孔材料。该催化剂可以用作非均相催化剂，以高产率生产芳基酯，具有工业优点。为了使用该催化剂生产芳基酯，碳酸酯或脂族羧酸酯与芳族羟基化合物进行酯交换，或羧酸芳基酯与碳酸酯进行酯交换反应，或者碳酸烷基芳基酯通过酯交换进行歧化。

33. 发明授权

US5543546A Process for preparing carbonate esters 失效
标题翻译：制备碳酸酯的方法
公开(公告)号：US5543546A
公开(公告)日：1996-08-06
申请号：US443753
申请日：1995-05-18
申请人： Hideaki Tsuneki , Yoshiyuki Onda , Atusi Moriya , Hiroshi Yoshida
发明人： Hideaki Tsuneki , Yoshiyuki Onda , Atusi Moriya , Hiroshi Yoshida
IPC分类号： B01D3/00 , B01J19/18 , C07C68/06
CPC分类号： C07C67/03 , B01D3/009 , B01J19/1862 , C07C68/06 , B01J2219/00029 , B01J2219/00094 , Y02P20/127
摘要： Carboxylate (1) of the formula R.sup.1 COOR.sup.2 (where each of R.sup.1 and R.sup.2 independently represents an alkyl group, an alicyclic hydrocarbon group or an aryl alkyl group), an aromatic hydroxy compound of the formula R.sup.3 OH (where R.sup.3 represents an aromatic group with or without a substituent), and a catalyst are supplied to a batch reactor 1, and a transesterification between the carboxylate (1) and the aromatic hydroxy compound is performed to produce carboxylate (3) of the formula R.sup.1 COOR.sup.3 (where R.sup.1 and R.sup.3 are as defined above). After distilling off the by-produced alcohol and unreacted compounds using a distillation column 2, carbonate ester (4) of the formula R.sup.4 O--COOR.sup.5 (where each of R.sup.4 and R.sup.5 independently represents an alkyl group, an alicyclic hydrocarbon group or an aryl alkyl group) is supplied to the batch reactor 1. Then, a transesterification between the carboxylate (3) and the carbonate ester (4) is performed to produce carbonate ester (5) of the formula R.sup.3 O--COOR.sup.6 (where R.sup.3 is as defined above, and R.sup.6 is a substituent selected from the group consisting of R.sup.3, R.sup.4 and R.sup.5). This process enables efficient preparation of carbonate esters.
摘要翻译：式R1COOR2的羧酸酯（1）（其中R 1和R 2各自独立地表示烷基，脂环族烃基或芳基烷基），式R 3 OH的芳族羟基化合物（其中R 3表示具有或不具有取代基），将催化剂供给到间歇式反应器1中，并进行羧酸酯（1）与芳族羟基化合物之间的酯交换反应，生成式R 1 COOR 3的羧酸酯（3）（其中R 1和R 3如上所定义））。使用蒸馏塔2蒸馏出副产物醇和未反应化合物后，式R4O-COOR5（其中R4和R5各自独立地表示烷基，脂环族烃基或芳基烷基）的式（4））供给到间歇反应器1.然后，进行羧酸酯（3）和碳酸酯（4）之间的酯交换以制备式R3O-COOR6的碳酸酯（5）（其中R3如上定义，和 R6是选自R3，R4和R5的取代基）。该方法可有效制备碳酸酯。

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