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31. 发明授权

US06878791B2 Aminoplast crosslinkers derived from tall oil rosin powder coating compositions containing such crosslinkers 失效
标题翻译：衍生自含有这种交联剂的妥尔油松香粉末涂料组合物的氨基塑料交联剂
公开(公告)号：US06878791B2
公开(公告)日：2005-04-12
申请号：US10434681
申请日：2003-05-09
申请人： Jonathan T. Martz , Shengkui Hu
发明人： Jonathan T. Martz , Shengkui Hu
IPC分类号： C08G12/40 , C08L61/32 , C09D161/32 , C09F1/00
CPC分类号： C09D161/32 , C08G12/40 , C08L61/32
摘要： A crosslinking agent that is an ungelled reaction product of (a) at least one aminoplast resin and (b) at least one tall oil rosin wherein the crosslinking agent is essentially free of active hydrogen functional groups and has a glass transition temperature of at least 10° C. is disclosed. Methods for preparing crosslinking agents are also disclosed. Further provided is a curable powder coating composition including a polymer having a glass transition temperature of at least 30° C. containing reactive functional groups and the present crosslinking agent; a multilayer composite coating composition and substrates coated therewith are also disclosed.
摘要翻译：一种交联剂，其是（a）至少一种氨基塑料树脂和（b）至少一种妥尔油松香的未凝胶化反应产物，其中所述交联剂基本上不含活性氢官能团并且玻璃化转变温度为至少10 °C。还公开了制备交联剂的方法。进一步提供一种可固化粉末涂料组合物，其包含玻璃化转变温度为至少含有反应性官能团的30℃的聚合物和本交联剂; 还公开了一种多层复合涂料组合物和其上涂覆的基材。

32. 发明授权

US5684083A Thermally curable coating composition 失效
标题翻译：热固化涂料组合物
公开(公告)号：US5684083A
公开(公告)日：1997-11-04
申请号：US445835
申请日：1995-05-22
申请人： Rodger G. Temple , Henry H. Crum, III , Jonathan T. Martz
发明人： Rodger G. Temple , Henry H. Crum, III , Jonathan T. Martz
IPC分类号： C08F290/14 , C08G18/81 , C09D4/06 , C09D175/16 , C08L75/04
CPC分类号： C09D4/06 , C08F290/147 , C08G18/8158 , C09D175/16
摘要： A composition is disclosed which includes a urethane resin containing reactive ethylenically unsaturated groups and hydroxyl groups, which is preferably derived by reacting a polyisocyanate and an isocyanate reactive group-containing unsaturated monomer selected from the group consisting of hydroxyalkyl acrylates, hydroxyalkyl methacrylates, hydroxyalkyl acrylamides, hydroxy functional allylic compounds, and mixtures thereof to form an isocyanate group-containing reaction product which is then reacted with an organic polyol wherein the equivalent number of hydroxyl groups is in excess compared with the equivalent number of isocyanate groups. The composition also includes an aminoplast resin for reaction with hydroxyl groups on the urethane resin in an amount of less than about 10% by weight based on solids of the composition which is effective in thin film curing of the composition. The composition can also optionally include a thermally activated free radical initiator and a cure-promoting catalyst different from the free radical initiator; such as a metal soap. A method is also disclosed of applying a layer of the composition in which a portion of the layer is a thin film. The method is particularly useful in applying the composition to a substrate which is coated with a cationically electrodeposited primer. The composition and method of the invention are particularly useful for making a chip resistant coating and obtaining good cure at thin film layers of the composition.
摘要翻译：公开了一种组合物，其包含含有反应性烯键式不饱和基团和羟基的聚氨酯树脂，其优选通过使多异氰酸酯和选自异氰酸酯反应性基团的不饱和单体反应而得到，所述不饱和单体选自丙烯酸羟烷基酯，甲基丙烯酸羟烷基酯，羟烷基丙烯酰胺，羟基官能的烯丙基化合物及其混合物，以形成含异氰酸酯基团的反应产物，然后与有机多元醇反应，其中相当数量的羟基与异氰酸酯基团的当量相比是过量的。所述组合物还包括用于与氨基甲酸酯树脂上的羟基反应的氨基塑料树脂，其用量小于约10重量％，基于对组合物的薄膜固化有效的组合物的固体。组合物还可以任选地包括热活化的自由基引发剂和不同于自由基引发剂的固化促进催化剂; 如金属皂。还公开了施加一层该组合物的方法，其中该层的一部分是薄膜。该方法在将组合物施加到用阳离子电沉积引物涂覆的基底上特别有用。本发明的组合物和方法特别可用于制备耐芯片涂层并在组合物的薄膜层获得良好的固化。

33. 发明授权

US5182355A Polyurethane polyanhydride oligomers and method of preparation 失效
标题翻译：聚氨酯聚酐低聚物及其制备方法
公开(公告)号：US5182355A
公开(公告)日：1993-01-26
申请号：US829706
申请日：1991-09-30
申请人： Jonathan T. Martz , Karl F. Schimmel , Padmanabhan Sundararaman , David N. Walters
发明人： Jonathan T. Martz , Karl F. Schimmel , Padmanabhan Sundararaman , David N. Walters
IPC分类号： C08G18/67 , C08G18/83
CPC分类号： C08G18/831 , C08G18/671 , Y10S525/939
摘要： A polyurethane polyanhydride oligomer is disclosed as well as a process for its preparation. The process involves the following steps:(a) reacting a hydroxyl functional 2,4-dienoate ester with a polyisocyanate under conditions sufficient to react essentially all of the isocyanate groups to form a polyurethane polyene; and(b) reacting by Diels Alder addition the unsaturated double bonds of the polyurethane polyene with an unsaturated polycarboxylic acid anhydride containing material. Also disclosed is a curable composition containing hydroxyl functional material and the aforedescribed polyurethane polyanhydride oligomer.
摘要翻译：公开了聚氨酯聚酐低聚物及其制备方法。该方法包括以下步骤：（a）使羟基官能的2,4-二烯酸酯与多异氰酸酯在足以使基本上所有异氰酸酯基团反应形成聚氨酯多烯的条件下反应; 和（b）由Diels Alder反应，加入聚氨酯多烯的不饱和双键与含不饱和多元羧酸酐的材料。还公开了含有羟基官能材料和上述聚氨酯聚酐低聚物的可固化组合物。

34. 发明授权

US4772695A Process for the preparation of vinyl carbamates 失效
标题翻译：制备乙烯基氨基甲酸酯的方法
公开(公告)号：US4772695A
公开(公告)日：1988-09-20
申请号：US533630
申请日：1983-09-19
申请人： Roy A. Olofson , Gary P. Wooden , Jonathan T. Martz
发明人： Roy A. Olofson , Gary P. Wooden , Jonathan T. Martz
IPC分类号： C07D211/78 , C07D249/18 , C07D273/00 , C07D273/08 , C07D295/205 , C07D323/00 , C07D451/06 , C07D489/06
CPC分类号： C07D273/00 , C07D211/78 , C07D249/18 , C07D295/205 , C07D323/00 , C07D451/06 , C07D489/06
摘要： A process for the preparation of vinyl carbamates of formula I ##STR1## is described which comprises heating an .alpha.-halogeno-carbamate of formula II ##STR2## in which X is a halogen atom at a temperature between 70.degree. and 250.degree. C. for a period of time between several minutes up to several hours. R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are the same or different. The process is applicable to a great variety of products in which R.sub.1, R.sub.2, R.sub.3, and R.sub.4 have different meanings. The process permits to prepare in a simple and economical fashion, vinyl carbamates, which have industrial value and novel vinyl carbamates.
摘要翻译：描述了制备式I的乙烯基氨基甲酸酯的方法（I），其包括在70℃的温度下加热其中X为卤素原子的式II的α-卤代 - 氨基甲酸酯和250℃下进行数分钟至数小时之间的时间。 R1，R2，R3和R4相同或不同。该方法适用于各种产品，其中R1，R2，R3和R4具有不同的含义。该方法允许以简单和经济的方式制备具有工业价值的乙烯基氨基甲酸酯和新的乙烯基氨基甲酸乙烯酯。

35. 发明授权

US08193293B2 Low temperature curable coating compositions and related methods 有权
标题翻译：低温可固化涂料组合物及相关方法
公开(公告)号：US08193293B2
公开(公告)日：2012-06-05
申请号：US12049521
申请日：2008-03-17
申请人： Jonathan T. Martz , Erick B. Iezzi
发明人： Jonathan T. Martz , Erick B. Iezzi
IPC分类号： C08G77/26
CPC分类号： C08G77/46 , C08G77/18 , C08G77/26 , C08G77/54 , C08G77/80 , C08K5/544 , C09D183/08 , C09D183/12 , C08L83/00 , C08L63/00
摘要： Disclosed are low temperature curable coating compositions, related coated substrates, methods for depositing a coating on a substrate and methods for refinishing the surface of an article, such as an automobile. The coating compositions include: (1) an aminofunctional silicon compound; (2) a polyether; and (3) a compound comprising functional groups reactive with the amino functionality of the aminofunctional silicon compound.
摘要翻译：公开了低温可固化涂料组合物，相关的涂布基材，在基材上沉积涂料的方法以及用于修补诸如汽车的制品表面的方法。涂料组合物包括：（1）氨基官能化硅化合物; （2）聚醚; 和（3）包含与氨基官能硅化合物的氨基官能团反应的官能团的化合物。

36. 发明授权

US08137813B2 Triamine/aspartate curative and coatings comprising the same 有权
标题翻译：三胺/天冬氨酸治疗剂和包含其的涂层
公开(公告)号：US08137813B2
公开(公告)日：2012-03-20
申请号：US13087741
申请日：2011-04-15
申请人： Howard Senkfor , Thomas R Hockswender , Steven V. Barancyk , Jonathan T. Martz , Steven R. Zawacky
发明人： Howard Senkfor , Thomas R Hockswender , Steven V. Barancyk , Jonathan T. Martz , Steven R. Zawacky
IPC分类号： B32B27/40
CPC分类号： C09D175/02 , C08G18/12 , C08G18/3234 , C08G18/3821 , C08G18/4854 , C08G18/5024 , C08G18/667 , Y10T428/12 , Y10T428/12993 , Y10T428/24355 , Y10T428/31551 , Y10T428/31605 , Y10T428/31678 , Y10T428/31725 , C08G18/38 , C08G18/6685
摘要： A coating composition is disclosed comprising polyurea formed from a reaction mixture comprising isocyanate and a triamine/aspartate reaction product resulting from a Michael addition reaction of a triamine with a dialkyl maleate and/or a dialkyl fumarate. The reaction product has a viscosity of less than 2000 cPs, and the triamine has the structure: wherein each n is the same or different and is any integer. Substrates coated with these polyurea coatings comprising this reaction product are also disclosed.
摘要翻译：公开了一种涂料组合物，其包含由包含异氰酸酯和三胺与马来酸二烷基酯和/或富马酸二烷基酯的迈克尔加成反应产生的三胺/天冬氨酸反应产物的反应混合物形成的聚脲。反应产物的粘度小于2000cPs，三胺具有以下结构：其中每个n相同或不同，为任何整数。还公开了涂覆有包含该反应产物的这些聚脲涂层的底物。

37. 发明申请

US20110217471A1 ONE-COMPONENT, AMBIENT CURABLE WATERBORNE COATING COMPOSITIONS, RELATED METHODS AND COATED SUBSTRATES 审中-公开
标题翻译：单组分，环氧固化水性涂料组合物，相关方法和涂层基材
公开(公告)号：US20110217471A1
公开(公告)日：2011-09-08
申请号：US13037460
申请日：2011-03-01
申请人： Irina G. Schwendeman , Venkateshwarlu Kalsani , Ronald R. Ambrose , Mary Ann Fuhry , Shanti Swarup , Anthony M. Chasser , Jonathan T. Martz , Carol L. Boggs
发明人： Irina G. Schwendeman , Venkateshwarlu Kalsani , Ronald R. Ambrose , Mary Ann Fuhry , Shanti Swarup , Anthony M. Chasser , Jonathan T. Martz , Carol L. Boggs
IPC分类号： B05D3/02 , C09D175/04
CPC分类号： C08G18/0866 , C08G18/095 , C08G18/5024 , C08G18/706 , C08G18/765 , C09D175/04
摘要： Disclosed are coating compositions that can be one-component, ambient curable, and waterborne. The coating compositions include a polycarbodiimide, a carboxylic acid functional polymer, and a base. The polycarbodiimide is modified for hydrophilicity and is derived from a tetramethylxylylene diisocyanate. The base is present in the composition in an amount sufficient to provide the composition with a pH of at least 9.0.
摘要翻译：公开了可以是单组分，环境可固化和水性的涂料组合物。涂料组合物包括聚碳二亚胺，羧酸官能聚合物和碱。聚碳化二亚胺被改性为亲水性，并衍生自四甲基亚二甲苯基二异氰酸酯。基料以足以提供组合物的pH至少为9.0的量存在于组合物中。

38. 发明申请

US20110206935A1 (METH)ACRYLATE/ASPARTATE AMINE CURATIVES AND COATINGS AND ARTICLES COMPRISING THE SAME 有权
标题翻译：（METH）丙烯酸酯/丙烯酸酯酰胺和涂料和包含它们的物品
公开(公告)号：US20110206935A1
公开(公告)日：2011-08-25
申请号：US13094298
申请日：2011-04-26
申请人： Steve Barancyk , John Furar , Howard Senkfor , Jonathan T. Martz , Thomas R. Hockswender , Anthony M. Chasser
发明人： Steve Barancyk , John Furar , Howard Senkfor , Jonathan T. Martz , Thomas R. Hockswender , Anthony M. Chasser
IPC分类号： B32B27/40 , C08G71/02 , C09D175/02
CPC分类号： C08G18/5024 , C08G18/12 , C08G18/3234 , C08G18/3821 , C08G18/4854 , C08G18/6674 , C09D175/02 , Y10T428/12 , Y10T428/12993 , Y10T428/31551 , C08G18/6685 , C08G18/38
摘要： (Meth)acrylate/aspartate amine curatives comprising the reaction product of a polyamine, a dialkyl maleate and/or dialkyl fumarate, and a (meth)acrylate are disclosed, as are methods for making the same. A polyurea comprising the reaction product of the acrylate/aspartate amine curative and isocyanate is also disclosed, as are coatings comprising such a polyurea and substrates coated with the same.
摘要翻译：公开了包含多胺，马来酸二烷基酯和/或富马酸二烷基酯与（甲基）丙烯酸酯的反应产物的（甲基）丙烯酸酯/天冬氨酸胺固化剂，以及制备它们的方法。还公开了包含丙烯酸酯/天冬氨酸胺固化剂和异氰酸酯的反应产物的聚脲，以及包含这种聚脲和涂覆有聚脲的基材的涂层。

39. 发明授权

US07972701B2 Substrates coated with a polyurea comprising a (meth)acrylated amine reaction product 有权
标题翻译：用包含（甲基）丙烯酸酯化的胺反应产物的聚脲涂覆的基材
公开(公告)号：US07972701B2
公开(公告)日：2011-07-05
申请号：US11611984
申请日：2006-12-18
申请人： Jonathan T. Martz , Thomas R. Hockswender , Steven V. Barancyk , Howard Senkfor
发明人： Jonathan T. Martz , Thomas R. Hockswender , Steven V. Barancyk , Howard Senkfor
IPC分类号： B32B27/00 , C08G18/32 , C08G18/60
CPC分类号： C09D175/02 , B60R13/02 , B60R13/08 , C08G18/289 , C08G18/3234 , C08G18/3821 , C08G18/6685 , C08G18/672 , C08G18/722 , C08G18/758 , C08G18/8175 , C08G2150/90 , Y10T428/31551 , Y10T428/31605
摘要： A metallic substrate coated at least in part with a multilayer coating composite, comprising at least one of an electrocoat layer, a base coat layer, and a clearcoat layer; and a polyurea formed from a reaction mixture comprising isocyanate and a (meth)acrylated amine reaction product of a monoamine and a poly(meth)acrylate is disclosed. The ratio of equivalents of isocyanate groups to equivalents of amine groups in the polyurea is greater than 1 and the isocyanate functional component and the (meth)acrylated amine functional component can be applied to the substrate at a volume mixing ratio of 1:1. A building comprising a building component coated at least in part with such a polyurea is also disclosed, as is a substrate coated at least in part with such a polyurea, wherein the ratio of equivalents or isocyanate to equivalents of amine groups is greater than 1.3:1.
摘要翻译：至少部分涂覆有多层涂层复合材料的金属基材，其包含电泳涂层，底涂层和透明涂层中的至少一种; 并且公开了由包含异氰酸酯和单胺和聚（甲基）丙烯酸酯的（甲基）丙烯酸酯化胺反应产物的反应混合物形成的聚脲。异氰酸酯基当量与聚脲中胺基当量的比值大于1，异氰酸酯官能组分和（甲基）丙烯酸酯化胺官能组分可以以1：1的体积混合比施加到基材上。还公开了包括至少部分涂覆有这种聚脲的建筑构件的建筑物，以及至少部分地涂覆有这种聚脲的基材，其中等同物或异氰酸酯与胺基当量的比例大于1.3： 1。

40. 发明申请

US20100136345A1 POLYUREA COATING COMPRISING A POLYAMINE/MONO(METH)ACRYLATE REACTION PRODUCT 有权
标题翻译：聚氨酯/单（甲基）丙烯酸酯反应产物的聚氨酯涂料
公开(公告)号：US20100136345A1
公开(公告)日：2010-06-03
申请号：US11611982
申请日：2006-12-18
申请人： Steven V. Barancyk , Thomas R. Hockswender , John Furar , Jonathan T. Martz , Howard Senkfor
发明人： Steven V. Barancyk , Thomas R. Hockswender , John Furar , Jonathan T. Martz , Howard Senkfor
IPC分类号： C09D175/02 , B05D1/02 , C08G18/67 , C08G18/32 , C08K5/17 , B32B27/28
CPC分类号： C08G18/3821 , C08G18/12 , C08G18/3262 , C08G18/5024 , C08G18/6674 , C09D175/04 , Y10T428/31551 , C08G18/50 , C08G18/798
摘要： Coating compositions comprising a polyurea formed from a reaction mixture comprising isocyanate and a (meth)acrylated amine are disclosed. The (meth)acrylated amine is the reaction product of a polyamine and a mono(meth)acrylate; the ratio of equivalents of isocyanate groups to equivalents of amine groups is greater than 1 and the isocyanate and the (meth)acrylated amine reaction product can be applied to a substrate at a volume mixing ratio of 1:1. Methods for using the coatings, and substrates coated therewith are also disclosed.
摘要翻译：公开了包含由包含异氰酸酯和（甲基）丙烯酸酯化的胺的反应混合物形成的聚脲的涂料组合物。（甲基）丙烯酸酯化胺是多胺和单（甲基）丙烯酸酯的反应产物; 异氰酸酯基的当量与胺基的当量的比率大于1，并且异氰酸酯和（甲基）丙烯酸酯化的胺反应产物可以以1：1的体积混合比施加到基材上。还公开了使用涂层的方法和涂覆的基材。

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